Composition comprising hf and e-3,3,3-trifluoro-1-chloropropene

ABSTRACT

An azeotropic or quasi-azeotropic composition including hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene and optionally one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene, and optionally one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.

CROSS REFERENCE TO RELATED APPLICATIONS

The present application is a continuation of U.S. application Ser. No.14/774,161, filed on Sep. 10, 2015, which is a U.S. national stage ofInternational Application No. PCT/FR2014/05034, filed on Feb. 21, 2014,which claims the benefit of French Application No. 13-52483, filed onMar. 20, 2013. The entire contents of each of U.S. application Ser. No.14/774,161, International Application No. PCT/FR2014/05034, and FrenchApplication No. 13-52483 are hereby incorporated herein by reference intheir entirety.

TECHNICAL FIELD

The present invention relates to azeotropic or quasi-azeotropiccompositions comprising E-3,3,3-trifluoro-1-chloropropene and hydrogenfluoride. These compositions may originate from intermediatecompositions in the production of E-3,3,3-trifluoro-1-chloropropene andare generally useful in processes for recycling hydrogen fluoride.

BACKGROUND

The manufacture of E-3,3,3-trifluoro-1-chloropropene accompanied by amultitude of by-products, having a boiling point close to HCFO-1233zdE,leads to relatively complex and expensive purification steps. Thedifficulty encountered during the purification of

HCFO-1233zdE generally implies an appreciable loss of desired product.Furthermore, these by-products may form azeotropic compositions withE-3,3,3-trifluoro-1-chloropropene, making separation by distillationsimple, very difficult, or even impossible.

Fluids based on E-3,3,3-trifluoro-1-chloropropene have found numerousapplications in varied industrial fields, especially as heat-transferfluid, propellants, foaming agents, swelling agents, gaseousdielectrics, polymerization medium or monomer, support fluids, abrasiveagents, drying agents and fluids for power production units.

Particular importance is given to fluids that have a low impact on theenvironment.

DETAILED DESCRIPTION

Following various experiments and trials, the Applicant has discoveredthat the compound E-3,3,3-trifluoro-1-chloropropene formed aheteroazeotropic or quasi-heteroazeotropic compound with hydrogenfluoride. It is difficult to identify novel fluids corresponding tothese characteristics since azeotropes are not predictable.

The subject of the present invention is an azeotropic orquasi-azeotropic composition comprising hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene and optionally one or more(hydro)halocarbon compounds comprising between 1 and 3 carbon atoms.

According to one embodiment of the invention, the composition isheteroazeotropic or quasi-heteroazeotropic.

A heteroazeotropic or quasi-heteroazeotropic mixture is an azeotropic orquasi-azeotropic mixture in which the condensed liquid forms twoimmiscible solutions that can be readily separated, for example bydecantation. This property is a considerable advantage for the recoveryof HF.

The term “quasi-azeotropic” or “quasi-heteroazeotropic” has a broadmeaning and is intended to include compositions that are strictlyazeotropic or strictly heteroazeotropic and those that behave like anazeotropic or heteroazeotropic mixture.

A mixture is azeotropic when the pressure at the dew point is equal tothat at the bubble formation point, which means that the vaporcomposition is equal to that of the condensed liquid.

A mixture is considered as quasi-azeotropic when the pressure at the dewpoint is substantially equal to that at the bubble formation point,which means that the vapor composition is substantially equal to that ofthe condensed liquid.

Another way of characterizing a mixture as quasi-azeotropic when thepressure difference between the pressure at the dew point and thepressure at the bubble formation point is low, preferentially less thanor equal to 5%, on the basis of the pressure at the bubble formationpoint.

Compositions according to the invention especially concern the followingcompounds, the acronyms of which represent:

HF: hydrogen fluoride

HCC-40: chloromethane, or CH₃Cl

HCFC-115: chloropentafluoroethane, or C₂F₅Cl

HCFC-124: chlorotetrafluoroethane, or C₂HF₄Cl

HFC-125: pentafluoroethane, or C₂HF₅

HCFC-133a: 1-chloro-2,2,2-trifluoroethane, or C₂H₂F₃Cl

HFC-134a: 1,1,1,2-tetrafluoroethane, or C₂H₂F₄

HCFC-142b: 1-chloro-1,1-difluoroethane, or C₂H₃F₂Cl

HFC-143a: 1,1,1-trifluoroethane, or C₂H₃F₃

HFC-152a: 1,1-difluoroethane, or C₂H₄F₂

HFO-1132: 1,2-difluoroethylene, or C₂H₂F₂

HFO-1141: fluoroethylene, or C₂H₃F

HFO-1234yf: 2,3,3,3-tetrafluoropropene or CH₂═CF—CF₃

HFC-245cb: 1,1,1,2,2-pentafluoropropane or CF₃—CF₂—CH₃

HFO-1234zeE: E-1,3,3,3-tetrafluoropropene or E-CF₃—CH═CHF

HFO-1234zeZ: Z-1,3,3,3-tetrafluoropropene or Z—CF₃—CH═CHF

HFO-1243zf: 3,3,3-trifluoropropene or CF₃—CH═CH₂

HCFO-1233xf: 3,3,3-trifluoro-2-chloropropene or CF₃—CCl═CH₂

HCFO-1233zdE: E-3,3,3-trifluoro-1-chloropropene or E-CF₃—CH═CHCl

HCFO-1233zdZ: Z-3,3,3-trifluoro-1-chloropropene or Z—CF₃—CH═CHCl

HFO-1225yeZ: Z-1,1,1,2,3-pentafluoropropene or Z—CHF═CF—CF₃

HFO-1225yeE: E-1,1,1,2,3-pentafluoropropene or E-CHF═CF—CF₃

HFO-1225zc: 1,1,3,3,3-pentafluoropropene or CF₂═CH—CF₃

HFO-1225yc: 1,1,2,3,3-pentafluoropropene or CF₂═CF—CF₂

HCFC-1214: dichlorotetrafluoropropene, or C₃F₄Cl₂

HCFO-1215: chloropentafluoropropene, or C₃F₅Cl

HFO-1216: hexafluoropropene, or C₃F₆

HCFO-1223: dichlorotrifluoropropene, or C₃HF₃Cl₂

HCFO-1224: chlorotetrafluoropropene, or C₃HF₄Cl

HCFO-1232: dichlorodifluoropropene, or C₃H₂F₂Cl₂

HCFO-1233xc: 1,1,3-trifluoro-2-chloropropene or CH₂F—CCl═CF₂

HCFO-1233xe: 1,3,3-trifluoro-2-chloropropene or CHF₂—CCl═CHF

HCFO-1233yb: 1,2,3-trifluoro-1-chloropropene or CH₂F—CF═CFCl

HCFO-1233yc: 1,1,2-trifluoro-3-chloropropene or CH₂Cl—CF═CF₂

HCFO-1233yd: 2,3,3-trifluoro-1-chloropropene or CHF₂—CF═CHCl

HCFO-1233ye: 1,2,3-trifluoro-3-chloropropene or CHClF—CF═CHF

HCFO-1233y1: 2,3,3-trifluoro-3-chloropropene or CClF₂—CF═CH₂

HCFO-1233zb: 1,3,3-trifluoro-1-chloropropene or CHF₂—CH═CFCl

HCFO-1233zc: 1,1,3-trifluoro-3-chloropropene or CHClF—CH═CF₂

HCFO-1233ze: 1,3,3-trifluoro-3-chloropropene or CClF₂—CH═CHF

HFO-1234yc: 1,1,2,3-tetrafluoropropene or CF₂═CF—CH₂F

HFO-1234ye: 1,2,3,3-tetrafluoropropene or CHF═CF—CHF₂

HFO-1234zc: 1,1,3,3-tetrafluoropropene or CF₂═CH—CHF₂

HCFO-1242: chlorodifluoropropene, or C₃H₃F₂Cl

HFO-1243yc: 1,1,2-trifluoropropene or CH₃—CF═CF₂

HFO-1243ye: 1,2,3-trifluoropropene or CH₂F—CF═CHF

HFO-1243y1: 2,3,3-trifluoropropene or CHF₂—CF═CH₂

HFO-1243zc: 1,1,3-trifluoropropene or CH₂F—CH═CF₂

HFO-1243ze: 1,3,3-trifluoropropene or CHF₂—CH═CHF

HCFO-1251: chlorofluoropropene, or C₃H₄FCl

HFO-1252: difluoropropene, or C₃H₄F₂

HFO-216: hexafluoropropene, or C₃F₆Cl₂

HCFO-217: chloroheptafluoropropane, or C₃F₇Cl

HFC-218: octafluoropropane, or C₃F₈

HCFC-225: dichloropentafluoropropane, or C₃HF₅Cl₂

HCFC-226: chlorohexafluoropropane, or C₃HF₆Cl

HFC-227: heptafluoropropane, or C₃HF₇

HCFC-234: dichlorotetrafluoropropane, or C₃H₂F₄Cl₂

HCFC-235: chloropentafluoropropane, or C₃H₂F₅Cl

HFC-236: hexafluoropropane, or C₃H₂F₆

HCFC-243: dichlorotrifluoropropane, or C₃H₃F₃Cl₂

HCFC-244: chlorotetrafluoropropane, or C₃H₃F₄Cl

HCFC-244bb: 2-chloro,1,1,1,2-tetrafluoropropane or CF₃—CFCl—CH₃

HFC-245fa: 1,1,1,3,3-pentafluoropropane or CF₃—CH₂—CHF₂

HFC-245ea: 1,1,2,3,3-pentafluoropropane or CHF₂—CHF—CHF₂

HFC-245eb: 1,1,1,2,3-pentafluoropropane or CF₃—CHF—CH₂F

HFC-245ca: 1,1,2,2,3-pentafluoropropane or CHF₂—CF₂—CH₂F

HCFC-253: chlorotrifluoropropane, or C₃H₄F₃Cl

HFC-254: tetrafluoropropane, or C₃H₄F₄

HCFC-262: Chlorodifluoropropane, or C₃H₅F₂Cl

HFC-263: trifluoropropane, or C₃H₅F₃

Trifluoropropyne: CF₃—C≡CH

The composition according to the invention may optionally be a mixtureof one or more azeotropes and/or heteroazeotropes of ternary,quaternary, penternary systems, systems with six compounds, systems withseven compounds, systems with eight or more compounds.

The compound(s) containing 1 and/or 2 carbon atoms may be chosenespecially from chloromethane, chloropentafluoroethane,1-chloro-1,2,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane,pentafluoroethane, 1-chloro-1,2,2-trifluoroethane,1-chloro-2,2,2-trifluoroethane, 1,1,2,2-tetrafluoroethane,1,1,1,2-tetrafluoroethane, 1-chloro-1,2-difluoroethane,1-chloro-1,1-difluoroethane, 1,1,2-trifluoroethane,1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1-difluoroethane,1,2-difluoroethylene and fluoroethylene.

The compound(s) containing 3 carbon atoms may be chosen especially from1,2-dichloro-1,1,2,3,3,3-hexafluoropropane,1,3-dichloro-1,1,2,2,3,3-hexafluoropropane,1,1-dichloro-1,2,2,3,3,3-hexafluoropropane,2,2-dichloro-1,1,1,3,3,3-hexafluoropropane,1-chloro-1,1,2,2,3,3,3-heptafluoropropane,2-chloro-1,1,1,2,3,3,3-heptafluoropropane, octafluoropropane,dichloropentafluoropropane, 2,2-dichloro-1,1,1,3,3-pentafluoropropane,2,3-dichloro-1,1,1,2,3-pentafluoropropane,1,2-dichloro-1,1,2,3,3-pentafluoropropane,3,3-dichloro-1,1,1,2,2-pentafluoropropane,1,3-dichloro-1,1,2,2,3-pentafluoropropane,1,1-dichloro-1,2,2,3,3-pentafluoropropane,1,2-dichloro-1,1,3,3,3-pentafluoropropane,1,3-dichloro-1,1,2,3,3-pentafluoropropane,1,1-dichloro-1,2,3,3,3-pentafluoropropane, chlorohexafluoropropane,2-chloro-1,1,1,2,3,3-hexafluoropropane,3-chloro-1,1,1,2,2,3-hexafluoropropane,1-chloro-1,1,2,2,3,3-hexafluoropropane,2-chloro-1,1,1,3,3,3-hexafluoropropane,1-chloro-1,1,2,3,3,3-hexafluoropropane,1,1,2,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3,3-Heptafluoropropane,dichlorotetrafluoropropane, 2,2-dichloro-1,1,3,3-tetrafluoropropane,2,2-dichloro-1,1,1,3-tetrafluoropropane,1,2-dichloro-1,2,3,3-tetrafluoropropane,2,3-dichloro-1,1,1,2-tetrafluoropropane,1,2-dichloro-1,1,2,3-tetrafluoropropane,1,3-dichloro-1,2,2,3-tetrafluoropropane,1,1-dichloro-2,2,3,3-tetrafluoropropane,1,3-dichloro-1,1,2,2-tetrafluoropropane,1,1-dichloro-1,2,2,3-tetrafluoropropane,2,3-dichloro-1,1,1,3-tetrafluoropropane,1,3-dichloro-1,1,3,3-tetrafluoropropane,1,3-dichloro-1,1,3,3-tetrafluoropropane,1,1-dichloro-1,3,3,3-tetrafluoropropane,1,1-dichloro-2,3,3,3-tetrafluoropropane,1,3-dichloro-1,1,2,3-tetrafluoropropane,1,1-dichloro-1,2,3,3-tetrafluoropropane, chloropentafluoropropane,1-chloro-1,2,2,3,3-pentafluoropropane,3-chloro-1,1,1,2,3-pentafluoropropane,1-chloro-1,1,2,2,3-pentafluoropropane,2-chloro-1,1,1,3,3-pentafluoropropane,1-chloro-1,1,3,3,3-pentafluoropropane,1-chloro-1,1,2,3,3-pentafluoropropane,3-chloro-1,1,1,2,2-pentafluoropropane,2-chloro-1,1,2,3,3-pentafluoropropane,2-chloro-1,1,1,2,3-pentafluoropropane, 1,1,1,2,2,3-hexafluoropropane,1,1,1,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoropropane,1,1,2,2,3,3-hexafluoropropane, dichlorotrifluoropropane,1,1-dichloro-3,3,3-trifluoropropane,1,3-dichloro-1,1,3-trifluoropropane,1,1-dichloro-1,3,3-trifluoropropane,1,3-dichloro-1,2,3-trifluoropropane,1,1-dichloro-2,3,3-trifluoropropane,1,3-dichloro-1,1,2-trifluoropropane,1,1-dichloro-1,2,3-trifluoropropane,1,2-dichloro-1,3,3-trifluoropropane,2,3-dichloro-1,1,1-trifluoropropane,1,2-dichloro-1,1,3-trifluoropropane,1,3-dichloro-1,2,2-trifluoropropane,1,1-dichloro-2,2,3-trifluoropropane,1,1-dichloro-1,2,2-trifluoropropane,2,3-dichloro-1,1,2-trifluoropropane,1,2-dichloro-1,2,3-trifluoropropane,1,2-dichloro-1,1,2-trifluoropropane,2,2-dichloro-1,1,3-trifluoropropane,2,2-dichloro-3,3,3-trifluoropropane, chlorotetrafluoropropane,2-chloro-1,2,3,3-tetrafluoropropane,2-chloro-1,1,1,2-tetrafluoropropane,3-chloro-1,1,2,2-tetrafluoropropane,1-chloro-1,2,2,3-tetrafluoropropane,1-chloro-1,1,2,2-tetrafluoropropane,2-chloro-1,1,3,3-tetrafluoropropane,2-chloro-1,1,1,3-tetrafluoropropane,3-chloro-1,1,2,3-tetrafluoropropane,3-chloro-1,1,1,2-tetrafluoropropane,1-chloro-1,1,2,3-tetrafluoropropane,3-chloro-1,1,1,3-tetrafluoropropane,1-chloro-1,1,3,3-tetrafluoropropane, pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1,2,3,3-pentafluoropropane,1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane,chlorotrifluoropropane, 2-chloro-1,2,3-trifluoropropane,2-chloro-1,1,2-trifluoropropane, 1-chloro-2,2,3-trifluoropropane,1-chloro-1,2,2-trifluoropropane, 3-chloro-1,1,2-trifluoropropane,1-chloro-1,2,3-trifluoropropane, 1-chloro-1,1,2-trifluoropropane,3-chloro-1,3,3-trifluoropropane, 3-chloro-1,1,1-trifluoropropane,1-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,3-trifluoropropane,2-chloro-1,1,1-trifluoropropane, 1,1,2,2-tetrafluoropropane,1,1,1,3-tetrafluoropropane, 1,1,2,3-tetrafluoropropane,1,1,1,2-tetrafluoropropane, 1,2,2,3-tetrafluoropropane,1,1,3,3-tetrafluoropropane, chlorodifluoropropane,1-chloro-2,2-difluoropropane, 3-chloro-1,1-difluoropropane,1-chloro-1,3-difluoropropane, 1-chloro-1,1-difluoropropane,1-chloro-2,3-difluoropropane, 1-chloro-1,2-difluoropropane,2-chloro-1,3-difluoropropane, 2-chloro-1,1-difluoropropane,2-chloro-1,2-difluoropropane, trifluoropropane, 1,1,1-trifluoropropane,1,1,3-trifluoropropane, 1,2,3-trifluoropropane, 1,1,2-trifluoropropane,1,2,2-trifluoropropane, dichlorotetrafluoropropene,1,2-dichloro-1,3,3,3-tetrafluoropropene,1,1-dichloro-2,3,3,3-tetrafluoropropene,1,3-dichloro-1,2,3,3-tetrafluoropropene,2,3-dichloro-1,1,3,3-tetrafluoropropene,3,3-dichloro-1,1,2,3-tetrafluoropropene, chloropentafluoropropene,1-chloropentafluoropropene, 2-chloropentafluoropropene,3-chloropentafluoropropene, hexafluoropropene, dichlorotrifluoropropene,1,1-dichloro-3,3,3-trifluoropropene,1,2-dichloro-3,3,3-trifluoropropene,2,3-dichloro-1,3,3-trifluoropropene,1,3-dichloro-2,3,3-trifluoropropene,1,2-dichloro-1,3,3-trifluoropropene,2,3-dichloro-1,1,3-trifluoropropene,1,1-dichloro-2,3,3-trifluoropropene,1,3-dichloro-1,2,3-trifluoropropene,3,3-dichloro-1,1,2-trifluoropropene,3,3-dichloro-1,2,3-trifluoropropene,1,3-dichloro-1,3,3-trifluoropropene,3,3-dichloro-1,1,3-trifluoropropene,1-chloro-2,3,3,3-tetrafluoropropene,1-chloro-1,3,3,3-tetrafluoropropene,2-chloro-1,3,3,3-tetrafluoropropene,3-chloro-1,2,3,3-tetrafluoropropene,3-chloro-1,1,3,3-tetrafluoropropene,2-chloro-1,1,3,3-tetrafluoropropene,1-chloro-1,2,3,3-tetrafluoropropene,3-chloro-1,1,2,3-tetrafluoropropene, 1,2,3,3,3-pentafluoropropene,1,1,3,3,3-pentafluoropropene, 1,1,2,3,3-pentafluoropropene,dichlorodifluoropropene, 2,3-dichloro-3,3-difluoropropene,1,2-dichloro-1,3-difluoropropene, 2,3-dichloro-1,1-difluoropropene,1,2-dichloro-3,3-difluoropropene, 2,3-dichloro-1,3-difluoropropene,1,1-dichloro-2,3-difluoropropene, 1,3-dichloro-1,2-difluoropropene,1,3-dichloro-2,3-difluoropropene, 3,3-dichloro-1,2-difluoropropene,3,3-dichloro-2,3-difluoropropene, 1,1-dichloro-3,3-difluoropropene,1,3-dichloro-1,3-difluoropropene, 3,3-dichloro-1,1-difluoropropene,1,3-dichloro-3,3-difluoropropene, 3,3-dichloro-1,3-difluoropropene,chlorotrifluoropropene, 2-chloro-1,1,3-trifluoropropene,2-chloro-1,3,3-trifluoropropene, 1-chloro-1,2,3-trifluoropropene,3-chloro-1,1,2-trifluoropropene, 1-chloro-2,3,3-trifluoropropene,3-chloro-1,2,3-trifluoropropene, 3-chloro-2,3,3-trifluoropropene,1-chloro-1,3,3-trifluoropropene, 3-chloro-1,1,3-trifluoropropene,3-chloro-1,3,3-trifluoropropene, 1,1,2,3-tetrafluoropropene,2,3,3,3-tetrafluoropropene, 1,2,3,3-tetrafluoropropene,1,1,3,3-tetrafluoropropene, chlorodifluoropropene,3-chloro-3,3-difluoropropene, 3-chloro-1,3-difluoropropene,2-chloro-1,1-difluoropropene, 2-chloro-1,3-difluoropropene,2-chloro-3,3-difluoropropene, 1-chloro-1,2-difluoropropene,1-chloro-2,3-difluoropropene, 3-chloro-1,2-difluoropropene,3-chloro-2,3-difluoropropene, 1-chloro-1,3-difluoropropene,3-chloro-1,1-difluoropropene, 1-chloro-3,3-difluoropropene,trifluoropropene, 1,1,2-trifluoropropene, 1,2,3-trifluoropropene,2,3,3-trifluoropropene, 1,1,3-trifluoropropene, 1,3,3-trifluoropropene,chlorofluoropropene, 1-chloro-3-fluoropropene, 1-chloro-1-fluoropropene,1-chloro-2-fluoropropene, 2-chloro-1-fluoropropene,2-chloro-3-fluoropropene, 3-chloro-2-fluoropropene,3-chloro-1-fluoropropene, 3-chloro-3-fluoropropene, difluoropropene,1,2-difluoropropene, 2,3-difluoropropene, 1,1-difluoropropene,1,3-difluoropropene, 3,3-difluoropropene, 1,1,1,2,2-pentafluoropropane,E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene,3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene,E-3,3,3-trifluoro-1-chloropropene, Z-3,3,3-trifluoro-1-chloropropene andtrifluoropropyne.

Preferably, the ternary compositions consisting essentially ofHF-HFCO-1233zdE-HFC-245fa are excluded from the present invention.

A subject of the present invention is also an azeotropic orquasi-azeotropic composition comprising hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, and optionally one or more compoundschosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene,1,3,3,3-tetrafluoropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

A subject of the present invention is also an azeotropic orquasi-azeotropic composition comprising hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene and optionally at least one or moreorganic compounds chosen from 1,1,1,2,2-pentafluoropropane,2,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene,Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane and optionally one or more compounds chosenfrom 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, 2,3,3,3-tetrafluoropropene andoptionally one or more compounds chosen from 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,3,3,3-trifluoropropene and optionally one or more compounds chosen from3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene andoptionally one or more compounds chosen from 1,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,1,3,3,3-tetrafluoropropene and optionally one or more compounds chosenfrom trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne and optionally oneor more compounds chosen from 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro,1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,1,1,1,3,3-pentafluoropropane and optionally one or more compounds chosenfrom 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro,1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, 1,1,1,3,3-pentafluoropropene andoptionally one or more compounds chosen from1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,1,1,1,3,3-pentafluoropropene and optionally2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropeneand 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane and optionally one or more compounds chosenfrom 2,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene,Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,2,3,3,3-tetrafluoropropene and optionally one or more compounds chosenfrom E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene,3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane. According to one embodiment, thecomposition according to the invention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, E-1,3,3,3-tetrafluoropropene andoptionally one or more compounds chosen fromZ-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, Z-1,3,3,3-tetrafluoropropene andoptionally one or more compounds chosen from 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride,E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoropropene and optionallyone or more compounds chosen from 3,3,3-trifluoro-2-chloropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrachloropropane.

According to one embodiment according to the invention, the compositioncomprises hydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene,3,3,3-trifluoro-2-chloropropene and optionally one or more compoundschosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

Irrespective of the embodiment, the composition preferably comprisesfrom 1% to 85% and advantageously from 5% to 80% by weight of hydrogenfluoride and from 99% to 15% and advantageously from 20% to 95% byweight of the sum of the organic compounds; more particularly, thecomposition comprises from 1% to 85% by weight of hydrogen fluoride andfrom 99% to 15% by weight of the sum of the organic compounds(HFO-1233zdE and the (hydro)halocarbon compounds).

Irrespective of the embodiment, the boiling point of the compositionaccording to the invention is between -20° C. and 80° C. and at apressure between 0.1 and 44 bar absolute, preferentially between 0° C.and 40° C. and preferentially at a pressure of between 0.7 and 18 barabsolute, advantageously between 0.9 and 12.5 bar absolute.

The Applicant has discovered that the compositions according to theinvention have advantageous properties in particular for the recyclingof HF in the reaction step. Thus, the condensed phase of thesecompositions, optionally when they are subjected to a distillation stepand/or a liquid/liquid separation step, such as by decantation, form twoimmiscible liquid phases.

By way of example, for the ternary compounds containing hydrogenfluoride, E-3,3,3-trifluoro-1-chloropropene and a compound chosen from1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,3,3,3-trifluoropropene, 1,3,3,3-tetrafluoropropene,3,3,3-trifluoro-2-chloropropene, the appearance of a heteroazeotropecharacterized by two liquid phases, one rich in HF and the otherdepleted in HF, depends on the amount of HF in the composition. Thesedecantation ranges as a function of the HF content in the compositionswere characterized for at least isotherms at 0° C., 25° C. and 40° C.

Similarly, the decantation ranges for the ternary compounds containinghydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene and a compoundchosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, Z-1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane are characterized by a phasedepleted in HF and a phase enriched in HF for at least isotherms at 0°C., 25° C. and 40° C.

The Applicant has observed the same phenomenon for compositions ofhydrogen fluoride, E-3,3,3-trifluoro-1-chloropropene comprising severalcompounds chosen from 1,1,1,2,2-pentafluoropropane,2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene,1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention comprises from 5% to 70% by weight ofhydrogen fluoride and from 95% to 30% by weight of HCFO-1233zdE, theboiling point of this preferred composition is between 0 and 40° C. at apressure of between 0.9 and 4 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 10% to 65% byweight of hydrogen fluoride and from 90% to 35% by weight ofHCFO-1233zdE, the boiling point of this preferred composition is between0 and 40° C. at a pressure of between 0.9 and 4 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention comprises from 1% to 85% by weight ofhydrogen fluoride and from 99% to 15% by weight of the sum ofHCFO-1233zdE and of HFC-245cb, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.9 and10.5 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 10% to 80% byweight of hydrogen fluoride and from 90% to 20% by weight of the sum ofHCFO-1233zdE and of HFO-245b, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.9 and10.5 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention comprises from 1% to 80% by weight ofhydrogen fluoride and from 99% to 20% by weight of the sum ofHCFO-1233zdE and of HFO-1243zf, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.9 and10.5 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 5% to 75% by weightof hydrogen fluoride and from 95% to 25% by weight of the sum ofHCFO-1233zdE and of HFO-1243zf, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.9 and10.5 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention comprises from 1% to 85% by weight ofhydrogen fluoride and from 99% to 15% by weight of the sum ofHCFO-1233zdE, of HFC-245cb and of HFO-1243zf, the boiling point of thispreferred composition is between 0 and 40° C. at a pressure of between0.9 and 10.5 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 5% to 80% by weightof hydrogen fluoride and from 95% to 20% by weight of the sum ofHCFO-1233zdE, of HFC-245cb and of HFO-1243zf, the boiling point of thispreferred composition is between 0 and 40° C. at a pressure of between0.9 and 10.5 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention comprises from 1% to 80% by weight ofhydrogen fluoride and from 99% to 20% by weight of the sum ofHCFO-1233zd, of HCFC-244bb, of HFC-245a, of trifluoropropyne, ofHFO-1225yeZ and of HFO-1225zc, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.7 and 18bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 5% to 75% by weightof hydrogen fluoride and from 95% to 25% by weight of the sum ofHCFO-1233zd, of HCFC-244bb, of HFC-245a, of trifluoropropyne, ofHFO-1225yeZ and of HFO-1225zc, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.7 and 18bar absolute.

The pressure characteristics of the mixtures in Examples 1, 4, 7, 10,13, 16, 19 and 22 have been calculated for an isotherm at 25° C.

Examples 2, 5, 8, 11, 14, 17, 20 and 23 represent the boiling points andpressure ranges of the mixtures and Examples 3, 6, 9, 12, 15, 18, 21 and23 represent the decantation ranges of the mixtures of Examples 1, 4, 7,10, 13, 16, 19 and 22 as a function of the mass percentage of HFcharacterized for isotherms at 0° C., 25° C. and 40° C. The decantationranges of Examples 3, 6, 9, 12, 15, 18, 21 and 23 are calculated formixtures of organic compounds having equal-mass contents. By way ofexample, for a ternary mixture, a mixture containing 50% by weight ofeach of the two organic compounds is considered; for a penternarymixture, a mixture containing 25% by weight of each of the four organiccompounds is considered, the mass fraction of HF ranging from 0 to 1.These calculations are performed at the liquid-vapor equilibrium, underazeotropic conditions.

EXAMPLE 1 Binary Mixture

HF-HCFO-1233zdE Binary HF-F1233zdE Isotherm 0° C. Isotherm 25° C.Isotherm 40° C. Pressure Pressure Pressure HF massfrac bar bar bar 0 0.51.3 2.2 0.05 0.9 2.4 4.0 0.1 0.9 2.4 4.0 0.15 0.9 2.4 4.0 0.2 0.9 2.44.0 0.25 0.9 2.4 4.0 0.3 0.9 2.4 4.0 0.35 0.9 2.4 4.0 0.4 0.9 2.4 4.00.45 0.9 2.4 4.0 0.5 0.9 2.4 4.0 0.55 0.9 2.4 4.0 0.6 0.9 2.4 4.0 0.650.9 2.4 4.0 0.7 0.9 2.4 4.0 0.75 0.9 2.4 3.9 0.8 0.9 2.3 3.8 0.85 0.92.2 3.5 0.9 0.8 1.9 3.2 0.95 0.6 1.6 2.7 1 0.5 1.2 1.9

EXAMPLE 2 Temperature and Pressure Range of the Binary Mixture

Boiling point range Temperature Pressure Binary ° C. bar absHF-HCFO-1233zdE-HFC-245cb 0 to 40 ~0.9 to ~4.0

EXAMPLE 3 Decantation Range of the Binary Mixture

Decantation ranges Mass percentage of HF Temperature Binary system 0° C.25° C. 40° C. HF-HCFO-1233zdE 5-80% 5-75% 5-70%

EXAMPLE 4 Ternary Mixtures, Isotherm at 25° C.

HF-HCFO-1233zdE-HFC-245cb HF-HCFO-1233xf-HCFO-1233zdE Organics OrganicsOrganics Organics Organics Organics 0.95 F1233zdE + 0.5 F1233zdE + 0.05F1233zdE + 0.95 F1233zdE + 0.5 F1233zdE + 0.05 F1233zdE + 0.05 F245cb0.5 F245cb 0.95 F245cb 0.05 F1233xf 0.5 F1233xf 0.95 F1233xf TOTAL TOTALTOTAL TOTAL TOTAL TOTAL PRES- PRES- PRES- PRES- PRES- PRES- MASSFRACSURE MASSFRAC SURE MASSFRAC SURE MASSFRAC SURE MASSFRAC SURE MASSFRACSURE HF bar HF bar HF bar HF bar HF bar HF bar 0 1.5 0 3.0 0 4.5 0 1.3 01.4 0 1.5 0.05 2.6 0.05 4.2 0.05 5.7 0.05 2.4 0.05 2.5 0.05 2.6 0.1 2.60.1 4.2 0.1 5.7 0.1 2.4 0.1 2.5 0.1 2.6 0.15 2.6 0.15 4.2 0.15 5.7 0.152.4 0.15 2.5 0.15 2.6 0.2 2.6 0.2 4.2 0.2 5.7 0.2 2.4 0.2 2.5 0.2 2.60.25 2.6 0.25 4.2 0.25 5.7 0.25 2.4 0.25 2.5 0.25 2.6 0.3 2.6 0.3 4.20.3 5.7 0.3 2.4 0.3 2.5 0.3 2.6 0.35 2.6 0.35 4.2 0.35 5.7 0.35 2.4 0.352.5 0.35 2.6 0.4 2.6 0.4 4.2 0.4 5.7 0.4 2.4 0.4 2.5 0.4 2.6 0.45 2.60.45 4.2 0.45 5.7 0.45 2.4 0.45 2.5 0.45 2.6 0.5 2.6 0.5 4.2 0.5 5.7 0.52.4 0.5 2.5 0.5 2.6 0.55 2.6 0.55 4.2 0.55 5.7 0.55 2.4 0.55 2.5 0.552.6 0.6 2.6 0.6 4.3 0.6 5.7 0.6 2.4 0.6 2.5 0.6 2.6 0.65 2.6 0.65 4.30.65 5.7 0.65 2.4 0.65 2.5 0.65 2.6 0.7 2.6 0.7 4.3 0.7 5.7 0.7 2.4 0.72.5 0.7 2.6 0.75 2.6 0.75 4.4 0.75 5.7 0.75 2.4 0.75 2.5 0.75 2.6 0.82.5 0.8 4.4 0.8 5.7 0.8 2.3 0.8 2.4 0.8 2.5 0.85 2.4 0.85 4.1 0.85 5.70.85 2.2 0.85 2.3 0.85 2.3 0.9 2.1 0.9 3.5 0.9 4.9 0.9 1.9 0.9 2.0 0.92.1 0.95 1.7 0.95 2.6 0.95 3.5 0.95 1.6 0.95 1.7 0.95 1.7 1 1.2 1 1.2 11.2 1 1.2 1 1.2 1 1.2 HF-HFO-1234zeE-HCFO-1233zdEHF-HFO-1234zeZ-HCFO-1233zdE Organics Organics Organics Organics OrganicsOrganics 0.95 F1233zdE + 0.5 F1233zdE + 0.05 F1233zdE + 0.95 F1233zdE +0.5 F1233zdE + 0.05 F1233zdE + 0.05 F1234zeZ 0.5 F1234zeZ 0.95 F1234zeZ0.05 F1234zeE 0.5 F1234zeE 0.95 F1234zeE TOTAL TOTAL TOTAL TOTAL TOTALTOTAL PRES- PRES- PRES- MASSFRAC PRES MASSFRAC PRES MASSFRAC PRESMASSFRAC SURE MASSFRAC SURE MASSFRAC SURE HF bar HF bar HF bar HF bar HFbar HF bar 0 1.5 0 3.2 0 4.7 0 1.3 0 1.6 0 1.8 0.05 2.6 0.05 4.2 0.055.7 0.05 2.4 0.05 2.7 0.05 2.9 0.1 2.6 0.1 4.2 0.1 5.7 0.1 2.4 0.1 2.70.1 2.9 0.15 2.6 0.15 4.2 0.15 5.7 0.15 2.4 0.15 2.7 0.15 2.9 0.2 2.60.2 4.2 0.2 5.7 0.2 2.4 0.2 2.7 0.2 2.9 0.25 2.6 0.25 4.2 0.25 5.7 0.252.4 0.25 2.7 0.25 2.9 0.3 2.6 0.3 4.2 0.3 5.7 0.3 2.4 0.3 2.7 0.3 2.90.35 2.6 0.35 4.2 0.35 5.7 0.35 2.4 0.35 2.7 0.35 2.9 0.4 2.6 0.4 4.20.4 5.7 0.4 2.4 0.4 2.7 0.4 2.9 0.45 2.6 0.45 4.2 0.45 5.7 0.45 2.4 0.452.7 0.45 2.9 0.5 2.6 0.5 4.1 0.5 5.6 0.5 2.4 0.5 2.7 0.5 2.9 0.55 2.60.55 4.1 0.55 5.6 0.55 2.4 0.55 2.7 0.55 2.9 0.6 2.6 0.6 4.1 0.6 5.5 0.62.4 0.6 2.7 0.6 2.9 0.65 2.6 0.65 4.1 0.65 5.4 0.65 2.4 0.65 2.7 0.652.9 0.7 2.6 0.7 4.0 0.7 5.2 0.7 2.4 0.7 2.7 0.7 2.9 0.75 2.6 0.75 3.80.75 5.0 0.75 2.4 0.75 2.7 0.75 2.9 0.8 2.4 0.8 3.6 0.8 4.7 0.8 2.3 0.82.6 0.8 2.8 0.85 2.3 0.85 3.2 0.85 4.2 0.85 2.2 0.85 2.4 0.85 2.6 0.92.0 0.9 2.8 0.9 3.5 0.9 2.0 0.9 2.1 0.9 2.3 0.95 1.7 0.95 2.1 0.95 2.50.95 1.6 0.95 1.7 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HFO-1234yf-HCFO-1233zdE HF-HCFO-1233zdE-HFO-1243zf Organics OrganicsOrganics Organics Organics Organics 0.95 F1233zdE + 0.5 F1233zdE + 0.05F1233zdE + 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf + 0.05 F1234yf 0.5F1234yf 0.95 F1234yf 0.05 F1233zdE 0.5 F1233zdE 0.95 F1233zdE TOTALTOTAL TOTAL TOTAL TOTAL TOTAL PRES- PRES- PRES- PRES- PRES- PRES-MASSFRAC SURE MASSFRAC SURE MASSFRAC SURE MASSFRAC SURE MASSFRAC SUREMASSFRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 1.6 0 4.2 06.5 0 5.7 0 3.9 0 1.6 0.05 2.7 0.5 5.3 0.5 7.5 0.05 6.6 0.05 5.0 0.052.7 0.1 2.7 0.1 5.3 0.1 7.5 0.1 6.6 0.1 4.9 0.1 2.7 0.15 2.7 0.15 5.30.15 7.5 0.15 6.6 0.15 4.9 0.15 2.7 0.2 2.7 0.2 5.3 0.2 7.5 0.2 6.6 0.24.9 0.2 2.7 0.25 2.7 0.25 5.3 0.25 7.5 0.25 6.6 0.25 4.9 0.25 2.7 0.32.7 0.3 5.3 0.3 7.5 0.3 6.6 0.3 4.9 0.3 2.7 0.35 2.7 0.35 5.3 0.35 7.50.35 6.6 0.35 4.9 0.35 2.7 0.4 2.7 0.4 5.3 0.4 7.5 0.4 6.6 0.4 4.9 0.42.7 0.45 2.7 0.45 5.3 0.45 7.5 0.45 6.6 0.45 4.9 0.45 2.7 0.5 2.7 0.55.3 0.5 7.5 0.5 6.6 0.5 4.9 0.5 2.7 0.55 2.7 0.55 5.3 0.55 7.5 0.55 6.60.55 4.9 0.55 2.7 0.6 2.7 0.6 5.3 0.6 7.5 0.6 6.6 0.6 4.9 0.6 2.7 0.652.7 0.65 5.3 0.65 7.5 0.65 6.5 0.65 4.8 0.65 2.7 0.7 2.7 0.7 5.3 0.7 7.50.7 6.4 0.7 4.8 0.7 2.7 0.75 2.7 0.75 5.2 0.75 7.4 0.75 6.3 0.75 4.60.75 2.7 0.8 2.6 0.8 4.9 0.8 7.0 0.8 6.0 0.8 4.4 0.8 2.5 0.85 2.4 0.854.5 0.85 6.5 0.85 5.5 0.85 4.0 0.85 2.4 0.9 2.1 0.9 3.8 0.9 5.4 0.9 4.60.9 3.4 0.9 2.1 0.95 1.7 0.95 2.8 0.95 3.8 0.95 3.3 0.95 2.5 0.95 1.7 11.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 5 Temperature and Pressure Range of Ternary Mixtures

Boiling point range Temperature Pressure bar Ternary ° C. absHF-HCFO-1233zdE-HFC-245cb 0 to 40 ~1.0 to~8.9HF-HCFO-1233xf-HCFO-1233zdE 0 to 40 ~0.9 to~4.0HF-HFO-1234zeE-HCFO-1233zdE 0 to 40 ~1.0 to~8.8HF-HFO-1234zeZ-HCFO-1233zdE 0 to 40 ~0.9 to~4.8HF-HCFO-1233zdE-HFO-1243zf 0 to 40  ~1.1 to~10.2HF-HFO-1234yf-HCFO-1233zdE 0 to 40  ~1.0 to~11.4

EXAMPLE 6 Decantation Range of Ternary Mixtures

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermTernary 0° C. 25° C. 40° C. HF-HCFO-1233zdE-HFC- 5-80 5-75  5-75

HF-HCFO-1233xf- 5-80 5-75  5-65 HCFO-1233zdE HF-HFO-1234zeE- 5-70 5-6510-50 HCFO-1233zdE HF-HFO-1234zeZ- 5-80 5-75  5-65 HCFO-1233zdEHF-HCFO-1233zdE-HFO- 5-75 5-65 15-45

HF-HFO-1234yf-HCFO- 5-75 5-70 15-55

indicates data missing or illegible when filed

EXAMPLE 7 Quaternary Mixtures, Isotherm at 25° C.

HF-HCFO-1233xf-HCFO-1233zdE-HFC-245cb Organics Organics OrganicsOrganics 0.9 F1233xf + 0.05 0.4 F1233xf + 0.3 0.05 F1233xf + 0.9 0.05F1233xf + 0.05 F1233zdE + 0.05 F245cb F1233zdE + 0.3 F245cb F1233zdE +0.05 F245cb F1233zdE + 0.9 F245cb TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 1.7 0 2.4 0 1.5 0 4.3 0.05 2.8 0.05 3.6 0.05 2.60.05 5.5 0.1 2.8 0.1 3.6 0.1 2.6 0.1 5.5 0.15 2.8 0.15 3.6 0.15 2.6 0.155.5 0.2 2.8 0.2 3.6 0.2 2.6 0.2 5.5 0.25 2.8 0.25 3.6 0.25 2.6 0.25 5.50.3 2.8 0.3 3.6 0.3 2.6 0.3 5.5 0.35 2.8 0.35 3.6 0.35 2.6 0.35 5.5 0.42.8 0.4 3.6 0.4 2.6 0.4 5.5 0.45 2.8 0.45 3.6 0.45 2.6 0.45 5.5 0.5 2.80.5 3.6 0.5 2.6 0.5 5.5 0.55 2.8 0.55 3.6 0.55 2.6 0.55 5.5 0.6 2.8 0.63.7 0.6 2.6 0.6 5.5 0.65 2.8 0.65 3.7 0.65 2.6 0.65 5.5 0.7 2.8 0.7 3.70.7 2.6 0.7 5.6 0.75 2.8 0.75 3.7 0.75 2.6 0.75 5.6 0.8 2.7 0.8 3.7 0.82.5 0.8 5.6 0.85 2.5 0.85 3.4 0.85 2.4 0.85 5.5 0.9 2.2 0.9 2.9 0.9 2.10.9 4.8 0.95 1.8 0.95 2.2 0.95 1.7 0.95 3.4 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE Organics Organics OrganicsOrganics 0.9 F1233xf + 0.05 0.05 F1233xf + 0.9 0.05 F1233xf + 0.05 0.4F1233xf + 0.3 F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.05 F1234zeE0.05 F1234zeE 0.9 F1234zeE 0.3 F1234zeE TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 1.7 0 1.5 0 4.6 0 2.5 0.05 2.8 0.05 2.6 0.05 5.50.05 3.6 0.1 2.8 0.1 2.6 0.1 5.5 0.1 3.6 0.15 2.8 0.15 2.6 0.15 5.5 0.153.6 0.2 2.8 0.2 2.6 0.2 5.5 0.2 3.6 0.25 2.8 0.25 2.6 0.25 5.5 0.25 3.60.3 2.8 0.3 2.6 0.3 5.5 0.3 3.6 0.35 2.8 0.35 2.6 0.35 5.5 0.35 3.6 0.42.8 0.4 2.6 0.4 5.5 0.4 3.6 0.45 2.8 0.45 2.6 0.45 5.5 0.45 3.6 0.5 2.80.5 2.6 0.5 5.5 0.5 3.6 0.55 2.8 0.55 2.6 0.55 5.4 0.55 3.5 0.6 2.8 0.62.6 0.6 5.4 0.6 3.5 0.65 2.8 0.65 2.6 0.65 5.3 0.65 3.5 0.7 2.8 0.7 2.60.7 5.1 0.7 3.5 0.75 2.8 0.75 2.6 0.75 4.9 0.75 3.3 0.8 2.6 0.8 2.5 0.84.6 0.8 3.2 0.85 2.4 0.85 2.3 0.85 4.1 0.85 2.9 0.9 2.2 0.9 2.0 0.9 3.40.9 2.5 0.95 1.7 0.95 1.7 0.95 2.5 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ Organics Organics OrganicsOrganics 0.9 F1233xf + 0.05 0.05 F1233xf + 0.9 0.05 F1233xf + 0.05 0.4F1233xf + 0.3 F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.05 F1234zeZ0.05 F1234zeZ 0.9 F1234zeZ 0.3 F1234zeZ TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 1.5 0 1.4 0 1.8 0 1.6 0.05 2.7 0.05 2.5 0.05 2.90.05 2.7 0.1 2.7 0.1 2.5 0.1 2.9 0.1 2.7 0.15 2.7 0.15 2.5 0.15 2.9 0.152.7 0.2 2.7 0.2 2.5 0.2 2.9 0.2 2.7 0.25 2.7 0.25 2.5 0.25 2.9 0.25 2.70.3 2.7 0.3 2.5 0.3 2.9 0.3 2.7 0.35 2.7 0.35 2.5 0.35 2.9 0.35 2.7 0.42.7 0.4 2.5 0.4 2.9 0.4 2.7 0.45 2.7 0.45 2.5 0.45 2.9 0.45 2.7 0.5 2.70.5 2.5 0.5 2.9 0.5 2.7 0.55 2.7 0.55 2.5 0.55 2.9 0.55 2.7 0.6 2.7 0.62.5 0.6 2.9 0.6 2.7 0.65 2.7 0.65 2.5 0.65 2.9 0.65 2.7 0.7 2.7 0.7 2.50.7 2.9 0.7 2.7 0.75 2.7 0.75 2.5 0.75 2.9 0.75 2.7 0.8 2.5 0.8 2.4 0.82.8 0.8 2.6 0.85 2.4 0.85 2.2 0.85 2.6 0.85 2.4 0.9 2.1 0.9 2.0 0.9 2.30.9 2.1 0.95 1.7 0.95 1.6 0.95 1.8 0.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HCFO-1233zdE-HFO-1243zf Organics Organics OrganicsOrganics 0.9 F1233xf + 0.05 0.05 F1233xf + 0.9 0.05 F1233xf + 0.05 0.4F1233xf + 0.3 F1233zdE + 0.05 F1243zf F1233zdE + 0.05 F1243zf F1233zdE +0.9 F1243zf F1233zdE + 0.3 F1243zf TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 1.8 0 1.6 0 5.5 0 3.0 0.05 2.9 0.05 2.7 0.05 6.40.05 4.1 0.1 2.9 0.1 2.7 0.1 6.5 0.1 4.1 0.15 2.9 0.15 2.7 0.15 6.5 0.154.1 0.2 2.9 0.2 2.7 0.2 6.5 0.2 4.1 0.25 2.9 0.25 2.7 0.25 6.5 0.25 4.10.3 2.9 0.3 2.7 0.3 6.5 0.3 4.1 0.35 2.9 0.35 2.7 0.35 6.5 0.35 4.1 0.42.9 0.4 2.7 0.4 6.5 0.4 4.1 0.45 2.9 0.45 2.7 0.45 6.5 0.45 4.1 0.5 2.90.5 2.7 0.5 6.4 0.5 4.1 0.55 2.9 0.55 2.7 0.55 6.4 0.55 4.1 0.6 2.9 0.62.7 0.6 6.4 0.6 4.0 0.65 2.9 0.65 2.7 0.65 6.4 0.65 4.0 0.7 2.9 0.7 2.70.7 6.3 0.7 4.0 0.75 2.9 0.75 2.7 0.75 6.1 0.75 3.9 0.8 2.7 0.8 2.6 0.85.8 0.8 3.7 0.85 2.5 0.85 2.4 0.85 5.3 0.85 3.4 0.9 2.2 0.9 2.1 0.9 4.50.9 2.9 0.95 1.8 0.95 1.7 0.95 3.2 0.95 2.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE Organics Organics OrganicsOrganics 0.9 F245cb + 0.05 0.05 F245cb + 0.9 0.05 F245cb + 0.05 0.4F245cb + 0.3 F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.05 F1234zeE0.05 F1234zeE 0.9 F1234zeE 0.3 F1234zeE TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 4.5 0 1.7 0 4.7 0 3.8 0.05 5.7 0.05 2.8 0.05 5.70.05 4.9 0.1 5.7 0.1 2.8 0.1 5.7 0.1 4.9 0.15 5.7 0.15 2.8 0.15 5.7 0.154.9 0.2 5.7 0.2 2.8 0.2 5.7 0.2 4.9 0.25 5.7 0.25 2.8 0.25 5.7 0.25 4.90.3 5.7 0.3 2.8 0.3 5.7 0.3 4.9 0.35 5.7 0.35 2.8 0.35 5.7 0.35 4.9 0.45.7 0.4 2.8 0.4 5.7 0.4 4.9 0.45 5.7 0.45 2.8 0.45 5.7 0.45 4.9 0.5 5.70.5 2.8 0.5 5.7 0.5 4.9 0.55 5.7 0.55 2.8 0.55 5.6 0.55 4.9 0.6 5.7 0.62.8 0.6 5.5 0.6 4.9 0.65 5.7 0.65 2.8 0.65 5.5 0.65 4.9 0.7 5.7 0.7 2.80.7 5.3 0.7 4.9 0.75 5.7 0.75 2.8 0.75 5.1 0.75 4.9 0.8 5.7 0.8 2.7 0.84.8 0.8 4.7 0.85 5.6 0.85 2.5 0.85 4.3 0.85 4.3 0.9 4.8 0.9 2.2 0.9 3.60.9 3.7 0.95 3.4 0.95 1.8 0.95 2.6 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ Organics Organics OrganicsOrganics 0.9 F245cb + 0.05 0.05 F245cb + 0.9 0.05 F245cb + 0.05 0.4F245cb + 0.3 F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.05 F1234zeZ0.05 F1234zeZ 0.9 F1234zeZ 0.3 F1234zeZ TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 4.3 0 1.5 0 1.9 0 2.8 0.05 5.5 0.05 2.6 0.05 3.00.05 3.9 0.1 5.5 0.1 2.6 0.1 3.0 0.1 3.9 0.15 5.5 0.15 2.6 0.15 3.0 0.153.9 0.2 5.5 0.2 2.6 0.2 3.0 0.2 3.9 0.25 5.5 0.25 2.6 0.25 3.0 0.25 3.90.3 5.5 0.3 2.6 0.3 3.0 0.3 4.0 0.35 5.5 0.35 2.6 0.35 3.0 0.35 4.0 0.45.5 0.4 2.6 0.4 3.0 0.4 4.0 0.45 5.5 0.45 2.6 0.45 3.0 0.45 4.0 0.5 5.50.5 2.6 0.5 3.0 0.5 4.0 0.55 5.5 0.55 2.6 0.55 3.0 0.55 4.0 0.6 5.5 0.62.6 0.6 3.0 0.6 4.0 0.65 5.5 0.65 2.7 0.65 3.1 0.65 4.0 0.7 5.6 0.7 2.70.7 3.1 0.7 4.1 0.75 5.6 0.75 2.7 0.75 3.1 0.75 4.1 0.8 5.6 0.8 2.6 0.82.9 0.8 4.1 0.85 5.5 0.85 2.4 0.85 2.7 0.85 3.8 0.9 4.8 0.9 2.1 0.9 2.40.9 3.3 0.95 3.4 0.95 1.7 0.95 1.9 0.95 2.5 1 1.2 1 1.2 1 1.2 1 1.2HF-HFC-245cb-HCFO-1233zdE-HFO-1243zf Organics Organics Organics Organics0.9 F245cb + 0.05 0.05 F245cb + 0.9 0.05 F245cb + 0.05 0.4 F245cb + 0.3F1233zdE + 0.05 F1243zf F1233zdE + 0.05 F1243zf F1233zdE + 0.9 F1243zfF1233zdE + 0.3 F1243zf TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HFbar HF bar 0 4.6 0 1.8 0 5.6 0 4.2 0.05 5.7 0.05 2.9 0.05 6.6 0.05 5.30.1 5.7 0.1 2.9 0.1 6.6 0.1 5.3 0.15 5.7 0.15 2.9 0.15 6.6 0.15 5.3 0.25.7 0.2 2.9 0.2 6.6 0.2 5.3 0.25 5.7 0.25 2.9 0.25 6.6 0.25 5.3 0.3 5.70.3 2.9 0.3 6.6 0.3 5.3 0.35 5.7 0.35 2.9 0.35 6.6 0.35 5.3 0.4 5.7 0.42.9 0.4 6.6 0.4 5.3 0.45 5.7 0.45 2.9 0.45 6.6 0.45 5.3 0.5 5.7 0.5 2.90.5 6.6 0.5 5.3 0.55 5.7 0.55 2.9 0.55 6.6 0.55 5.3 0.6 5.7 0.6 2.9 0.66.5 0.6 5.3 0.65 5.7 0.65 2.9 0.65 6.5 0.65 5.3 0.7 5.8 0.7 2.9 0.7 6.40.7 5.3 0 5.8 0.75 2.9 0.75 6.2 0.75 5.3 0.8 5.8 0.8 2.8 0.8 6.0 0.8 5.10.85 5.7 0.85 2.6 0.85 5.5 0.85 4.7 0.9 4.9 0.9 2.3 0.9 4.7 0.9 4.1 0.953.5 0.95 1.8 0.95 3.3 0.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ Organics 0.9 Organics0.051233zdE + Organics 0.05 Organics 1233zdE + 0.05 1234zeE + 0.91234zeE + 1233zdE + 0.05 0.4 1233zdE + 0.3 0.05 1234zeZ 0.05 1234zeZ1234zeE + 0.9 1234zeZ 1234zeE + 0.3 1234zeZ TOTAL TOTAL TOTAL TOTALMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar 0 1.5 0 4.5 0 1.9 0 2.6 0.05 2.6 0.05 5.50.05 3.0 0.05 3.7 0.1 2.6 0.1 5.5 0.1 3.0 0.1 3.6 0.15 2.6 0.15 5.5 0.153.0 0.15 3.6 0.2 2.6 0.2 5.5 0.2 3.0 0.2 3.6 0.25 2.6 0.25 5.5 0.25 3.00.25 3.6 0.3 2.6 0.3 5.5 0.3 3.0 0.3 3.6 0.35 2.6 0.35 5.5 0.35 3.0 0.353.6 0.4 2.6 0.4 5.5 0.4 3.0 0.4 3.6 0.45 2.6 0.45 5.5 0.45 3.0 0.45 3.60.5 2.6 0.5 5.5 0.5 3.0 0.5 3.6 0.55 2.6 0.55 5.4 0.55 3.0 0.55 3.6 0.62.6 0.6 5.4 0.6 3.0 0.6 3.6 0.65 2.6 0.65 5.3 0.65 3.0 0.65 3.5 0.7 2.60.7 5.1 0.7 3.0 0.7 3.5 0.75 2.6 0.75 4.9 0.75 3.0 0.75 3.4 0.8 2.5 0.84.6 0.8 2.9 0.8 3.2 0.85 2.3 0.85 4.1 0.85 2.7 0.85 2.9 0.9 2.0 0.9 3.40.9 2.3 0.9 2.5 0.95 1.7 0.95 2.5 0.95 1.9 0.95 2.0 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf Organics Organics OrganicsOrganics 0.9 F1233zdE + 0.05 0.05 F1233zdE + 0.9 0.05 F1233zdE + 0.050.4 F1233zdE + 0.3 F1234zeE + 0.05 F1243zf F1234zeE + 0.05 F1243zfF1234zeE + 0.9 F1243zf F1234zeE + 0.3 F1243zf TOTAL TOTAL TOTAL TOTALMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar 0 1.8 0 4.8 0 5.6 0 3.9 0.05 2.9 0.05 5.70.05 6.6 0.05 5.0 0.1 2.9 0.1 5.7 0.1 6.6 0.1 5.0 0.15 2.9 0.15 5.7 0.156.6 0.15 5.0 0.2 2.9 0.2 5.7 0.2 6.6 0.2 5.0 0.25 2.9 0.25 5.7 0.25 6.60.25 5.0 0.3 2.9 0.3 5.7 0.3 6.6 0.3 5.0 0.35 2.9 0.35 5.7 0.35 6.6 0.355.0 0.4 2.9 0.4 5.7 0.4 6.6 0.4 4.9 0.45 2.9 0.45 5.7 0.45 6.6 0.45 4.90.5 2.9 0.5 5.7 0.5 6.6 0.5 4.9 0.55 2.9 0.55 5.6 0.55 6.5 0.55 4.9 0.62.9 0.6 5.6 0.6 6.5 0.6 4.9 0.65 2.9 0.65 5.5 0.65 6.5 0.65 4.9 0.7 2.80.7 5.3 0.7 6.4 0.7 4.8 0.75 2.8 0.75 5.1 0.75 6.2 0.75 4.6 0.8 2.7 0.84.8 0.8 5.9 0.8 4.3 0.85 2.5 0.85 4.3 0.85 5.4 0.85 3.9 0.9 2.2 0.9 3.60.9 4.6 0.9 3.3 0.95 1.8 0.95 2.6 0.95 3.3 0.95 2.5 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf Organics Organics OrganicsOrganics 0.9 F1233zdE + 0.05 0.05 F1233zdE + 0.9 0.05 F1233zdE + 0.050.4 F1233zdE + 0.3 F1234zeZ + 0.05 F1243zf F1234zeZ + 0.05 F1243zfF1234zeZ + 0.9 F1243zf F1234zeZ + 0.3 F1243zf TOTAL TOTAL TOTAL TOTALMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar 0 1.6 0 2.0 0 5.5 0 3.0 0.05 2.7 0.05 3.10.05 6.4 0.05 4.1 0.1 2.7 0.1 3.1 0.1 6.5 0.1 4.1 0.15 2.7 0.15 3.1 0.156.5 0.15 4.1 0.2 2.7 0.2 3.1 0.2 6.5 0.2 4.1 0.25 2.7 0.25 3.1 0.25 6.50.25 4.1 0.3 2.7 0.3 3.1 0.3 6.4 0.3 4.1 0.35 2.7 0.35 3.1 0.35 6.4 0.354.1 0.4 2.7 0.4 3.1 0.4 6.4 0.4 4.1 0.45 2.7 0.45 3.1 0.45 6.4 0.45 4.10.5 2.7 0.5 3.1 0.5 6.4 0.5 4.1 0.55 2.7 0.55 3.1 0.55 6.4 0.55 4.1 0.62.7 0.6 3.1 0.6 6.4 0.6 4.1 0.65 2.7 0.65 3.1 0.65 6.3 0.65 4.0 0.7 2.70.7 3.1 0.7 6.3 0.7 4.0 0.75 2.7 0.75 3.1 0.75 6.1 0.75 3.9 0.8 2.6 0.83.0 0.8 5.8 0.8 3.7 0.85 2.4 0.85 2.7 0.85 5.3 0.85 3.4 0.9 2.1 0.9 2.40.9 4.5 0.9 2.9 0.95 1.7 0.95 1.9 0.95 3.2 0.95 2.2 1 1.2 1 1.2 1 1.2 11.2 HF-HFO-1234yf-HCFO-1233zdE-HFC-245cb Organics Organics OrganicsOrganics 0.9 F1234yf + 0.05 0.4 F1234yf + 0.3 0.05 F1234yf + 0.9 0.05F1234yf + 0.05 F1233zdE + 0.05 F245cb F1233zdE + 0.3 F245cb F1233zdE +0.05 F245cb F1233zdE + 0.9 F245cb TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 6.4 0 4.6 0 1.8 0 4.6 0.05 7.4 0.05 5.7 0.05 2.90.05 5.8 0.1 7.4 0.1 5.7 0.1 2.9 0.1 5.8 0.15 7.4 0.15 5.7 0.15 2.9 0.155.8 0.2 7.4 0.2 5.7 0.2 2.9 0.2 5.8 0.25 7.4 0.25 5.7 0.25 2.9 0.25 5.80.3 7.4 0.3 5.7 0.3 2.9 0.3 5.8 0.35 7.4 0.35 5.7 0.35 2.9 0.35 5.8 0.47.4 0.4 5.7 0.4 2.9 0.4 5.8 0.45 7.4 0.45 5.7 0.45 2.9 0.45 5.8 0.5 7.40.5 5.7 0.5 2.9 0.5 5.8 0.55 7.4 0.55 5.7 0.55 2.9 0.55 5.8 0.6 7.4 0.65.7 0.6 2.9 0.6 5.8 0.65 7.4 0.65 5.8 0.65 2.9 0.65 5.8 0.7 7.4 0.7 5.80.7 2.9 0.7 5.8 0.75 7.3 0.75 5.8 0.75 2.9 0.75 5.8 0.8 7.0 0.8 5.6 0.82.8 0.8 5.8 0.85 6.4 0.85 5.1 0.85 2.6 0.85 5.7 0.9 5.4 0.9 4.4 0.9 2.30.9 4.9 0.95 3.7 0.95 3.1 0.95 1.8 0.95 3.5 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE Organics Organics OrganicsOrganics 0.9 F1233xf + 0.05 0.05 F1233xf + 0.9 0.05 F1233xf + 0.05 0.4F1233xf + 0.3 F1234yf + F1234yf + F1234yf + F1234yf + 0.05 F1233zdE 0.05F1233zdE 0.9 F1233zdE 0.3 F1233zdE TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 1.8 0 6.3 0 1.7 0 3.2 0.05 3.0 0.05 7.3 0.05 2.80.05 4.3 0.1 3.0 0.1 7.3 0.1 2.8 0.1 4.3 0.15 3.0 0.15 7.3 0.15 2.8 0.154.3 0.2 2.9 0.2 7.3 0.2 2.8 0.2 4.3 0.25 2.9 0.25 7.3 0.25 2.8 0.25 4.30.3 2.9 0.3 7.3 0.3 2.8 0.3 4.3 0.35 2.9 0.35 7.3 0.35 2.8 0.35 4.3 0.42.9 0.4 7.3 0.4 2.8 0.4 4.3 0.45 2.9 0.45 7.3 0.45 2.7 0.45 4.3 0.5 2.90.5 7.3 0.5 2.7 0.5 4.3 0.55 2.9 0.55 7.3 0.55 2.7 0.55 4.3 0.6 2.9 0.67.3 0.6 2.7 0.6 4.3 0.65 2.9 0.65 7.3 0.65 2.7 0.65 4.3 0.7 2.9 0.7 7.30.7 2.7 0.7 4.3 0.75 2.9 0.75 7.1 0.75 2.7 0.75 4.2 0.8 2.8 0.8 6.8 0.82.6 0.8 4.0 0.85 2.6 0.85 6.2 0.85 2.4 0.85 3.7 0.9 2.3 0.9 5.3 0.9 2.10.9 3.1 0.95 1.8 0.95 3.7 0.95 1.7 0.95 2.3 1 1.2 1 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE Organics Organics OrganicsOrganics 0.9 F1234yf + 0.05 0.05 F1234yf + 0.9 0.05 F1234yf + 0.05 0.4F1234yf + 0.3 F1234zeE + F1234zeE + F1234zeE + F1234zeE + 0.05 F1233zdE0.05 F1233zdE 0.9 F1233zdE 0.3 F1233zdE TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 6.4 0 4.8 0 1.8 0 4.7 0.05 7.4 0.05 5.8 0.05 2.90.05 5.7 0.1 7.4 0.1 5.8 0.1 2.9 0.1 5.7 0.15 7.4 0.15 5.8 0.15 2.9 0.155.7 0.2 7.4 0.2 5.8 0.2 2.9 0.2 5.7 0.25 7.4 0.25 5.8 0.25 2.9 0.25 5.70.3 7.4 0.3 5.8 0.3 2.9 0.3 5.7 0.35 7.4 0.35 5.8 0.35 2.9 0.35 5.7 0.47.4 0.4 5.8 0.4 2.9 0.4 5.7 0.45 7.4 0.45 5.8 0.45 2.9 0.45 5.7 0.5 7.40.5 5.7 0.5 2.9 0.5 5.7 0.55 7.4 0.55 5.7 0.55 2.9 0.55 5.7 0.6 7.4 0.65.6 0.6 2.9 0.6 5.7 0.65 7.4 0.65 5.5 0.65 2.9 0.65 5.7 0.7 7.4 0.7 5.40.7 2.9 0.7 5.6 0.75 7.2 0.75 5.1 0.75 2.9 0.75 5.4 0.8 6.9 0.8 4.8 0.82.7 0.8 5.1 0.85 6.3 0.85 4.3 0.85 2.5 0.85 4.7 0.9 5.3 0.9 3.6 0.9 2.20.9 3.9 0.95 3.7 0.95 2.6 0.95 1.8 0.95 2.8 1 1.2 1 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE Organics Organics OrganicsOrganics 0.9 F1234yf + 0.05 0.05 F1234yf + 0.9 0.05 F1234yf + 0.05 0.4F1234yf + 0.3 F1234zeZ + F1234zeZ + F1234zeZ + F1234zeZ + 0.05 F1233zdE0.05 F1233zdE 0.9 F1233zdE 0.3 F1233zdE TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 6.3 0 2.0 0 1.7 0 3.8 0.05 7.3 0.05 3.2 0.05 2.80.05 4.8 0.1 7.3 0.1 3.2 0.1 2.8 0.1 4.8 0.15 7.3 0.15 3.2 0.15 2.8 0.154.8 0.2 7.3 0.2 3.2 0.2 2.8 0.2 4.8 0.25 7.3 0.25 3.2 0.25 2.8 0.25 4.80.3 7.3 0.3 3.2 0.3 2.8 0.3 4.8 0.35 7.3 0.35 3.1 0.35 2.8 0.35 4.8 0.47.3 0.4 3.1 0.4 2.8 0.4 4.8 0.45 7.3 0.45 3.1 0.45 2.8 0.45 4.8 0.5 7.30.5 3.1 0.5 2.8 0.5 4.8 0.55 7.3 0.55 3.1 0.55 2.8 0.55 4.8 0.6 7.3 0.63.1 0.6 2.8 0.6 4.8 0.65 7.3 0.65 3.1 0.65 2.8 0.65 4.8 0.7 7.3 0.7 3.10.7 2.7 0.7 4.8 0.75 7.1 0.75 3.1 0.75 2.7 0.75 4.7 0.8 6.8 0.8 3.0 0.82.6 0.8 4.5 0.85 6.2 0.85 2.8 0.85 2.4 0.85 4.1 0.9 5.3 0.9 2.4 0.9 2.20.9 3.5 0.95 3.7 0.95 1.9 0.95 1.7 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2HF-HFO-1234yf-HCFO-1233zdE-HFO-1243zf Organics Organics OrganicsOrganics 0.9 F1234yf + 0.05 0.05 F1234yf + 0.9 0.05 F1234yf + 0.05 0.4F1234yf + 0.3 F1233zdE + 0.05 F1243zf F1233zdE + 0.05 F1243zf F1233zdE +0.9 F1243zf F1233zdE + 0.3 F1243zf TOTAL TOTAL TOTAL TOTAL MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar 0 6.5 0 1.9 0 5.7 0 5.0 0.05 7.5 0.05 3.0 0.05 6.70.05 6.0 0.1 7.5 0.1 3.0 0.1 6.7 0.1 6.0 0.15 7.5 0.15 3.0 0.15 6.7 0.156.0 0.2 7.4 0.2 3.0 0.2 6.7 0.2 6.0 0.25 7.4 0.25 3.0 0.25 6.7 0.25 6.00.3 7.5 0.3 3.0 0.3 6.7 0.3 6.0 0.35 7.5 0.35 3.0 0.35 6.7 0.35 6.0 0.47.5 0.4 3.0 0.4 6.7 0.4 6.0 0.45 7.5 0.45 3.0 0.45 6.7 0.45 6.0 0.5 7.50.5 3.0 0.5 6.6 0.5 6.0 0.55 7.5 0.55 3.0 0.55 6.6 0.55 6.0 0.6 7.5 0.63.0 0.6 6.6 0.6 6.0 0.65 7.5 0.65 3.0 0.65 6.6 0.65 6.0 0.7 7.4 0.7 3.00.7 6.5 0.7 6.0 0.75 7.3 0.75 3.0 0.75 6.3 0.75 5.8 0.8 7.0 0.8 2.8 0.86.0 0.8 5.5 0.85 6.4 0.85 2.6 0.85 5.5 0.85 5.1 0.9 5.4 0.9 2.3 0.9 4.70.9 4.3 0.95 3.7 0.95 1.8 0.95 3.3 0.95 3.1 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 8 Temperature and Pressure Range of Quaternary Mixtures

Boiling point range Temperature Pressure bar Quaternary ° C. absHF-HCFO-1233xf-HFC-245cb-HCFO- 0 to 40 ~1.0 to ~8.7  1233zdEHF-HCFO-1233xf-HCFO-1233zdE- 0 to 40 ~1.0 to ~8.6 HFO-1234zeEHF-HCFO-1233xf-HCFO-1233zdE- 0 to 40 ~0.9 to ~4.8 HFO-1234zeZHF-HCFO-1233xf-HCFO-1233zdE- 0 to 40 ~1.0 to ~9.9 HFO-1243zfHF-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40 ~1.0 to ~8.9 1234zeEHF-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40 ~1.0 to ~8.9 1234zeZHF-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40  ~1.1 to ~10.1 1243zfHF-HCFO-1233zdE-HFO-1234zeE- 0 to 40 ~1.0 to ~8.6 HFO-1234zeZHF-HCFO-1233zdE-HFO-1234zeE- 0 to 40  ~1.1 to ~10.1 HFO-1243zfHF-HCFO-1233zdE-HFO-1234zeZ- 0 to 40 ~1.0 to ~9.9 HFO-1243zfHF-HFO-1234yf-HFC-245cb-HCFO- 0 to 40  ~1.1 to ~11.3 1233zdEHF-HCFO-1233xf-HFO-1234yf-HCFO- 0 to 40  ~1.0 to ~11.1 1233zdEHF-HFO-1234yf-HFO-1234zeE-HCFO- 0 to 40  ~1.1 to ~11.3 1233zdEHF-HFO-1234yf-HFO-1234zeZ-HCFO- 0 to 40  ~1.0 to ~11.0 1233zdEHF-HFO-1234yf-HCFO-1233zdE- 0 to 40  ~1.2 to ~11.3 HFO-1243zf

EXAMPLE 9 Decantation Range of Auaternary Mixtures

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermQuaternary 0° C. 25° C. 40° C. HF-HCFO-1233xf-HFC-245cb- 5-80 5-75  5-70HCFO-1233zdE HF-HCFO-1233xf-HCFO-1233zdE- 5-75 5-65  5-55 HFO-1234zeEHF-HCFO-1233xf-HCFO-1233zdE- 5-80 5-75  5-65 HFO-1234zeZHF-HCFO-1233xf-HCFO-1233zdE- 5-75 5-70 10-60 HFO-1243zfHF-HFC-245cb-HCFO-1233zdE- 5-75 5-70 10-65 HFO-1234zeEHF-HFC-245cb-HCFO-1233zdE- 5-80 5-75  5-70 HFO-1234zeZHF-HFC-245cb-HCFO-1233zdE- 5-75 5-70 15-65 HFO-1243zfHF-HCFO-1233zdE-HFO-1234zeE- 5-75 5-65 10-55 HFO-1234zeZHF-HCFO-1233zdE-HFO-1234zeE- 5-70 10-60  * HFO-1243zfHF-HCFO-1233zdE-HFO-1234zeZ- 5-75 5-70 10-55 HFO-1243zfHF-HFO-1234yf-HFC-245cb- 5-75 5-75 15-70 HCFO-1233zdEHF-HCFO-1233xf-HFO-1234yf- 5-75 5-70 10-60 HCFO-1233zdEHF-HFO-1234yf-HFO-1234zeE- 5-70 10-60  * HCFO-1233zdEHF-HFO-1234yf-HFO-1234zeZ- 5-75 5-70 10-60 HCFO-1233zdEHF-HFO-1234yf-HCFO-1233zdE- 5-75 10-65  * HFO-1243zf

EXAMPLE 10 Penternary Mixtures, Isotherm at 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE Organics OrganicsOrganics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 F1233zdE +F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.033 F245cb + 0.033F245cb + 0.9 245cb + 0.033 F245cb + 0.25 F245cb + 0.034 F1234zeE 0.034F1234zeE 0.034 F1234zeE 0.9 F1234zeE 0.25 F1234zeE TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 01.8 0 1.6 0 4.4 0 4.7 0 3.2 0.05 2.9 0.05 2.7 0.05 5.6 0.05 5.6 0.05 4.30.1 2.9 0.1 2.7 0.1 5.6 0.1 5.6 0.1 4.3 0.15 2.9 0.15 2.7 0.15 5.6 0.155.6 0.15 4.3 0.2 2.9 0.2 2.7 0.2 5.6 0.2 5.6 0.2 4.3 0.25 2.9 0.25 2.70.25 5.6 0.25 5.6 0.25 4.3 0.3 2.9 0.3 2.7 0.3 5.6 0.3 5.6 0.3 4.3 0.352.9 0.35 2.7 0.35 5.6 0.35 5.6 0.35 4.3 0.4 2.9 0.4 2.7 0.4 5.6 0.4 5.60.4 4.3 0.45 2.9 0.45 2.7 0.45 5.6 0.45 5.6 0.45 4.3 0.5 2.9 0.5 2.7 0.55.6 0.5 5.6 0.5 4.3 0.55 2.9 0.55 2.7 0.55 5.6 0.55 5.6 0.55 4.3 0.6 2.90.6 2.7 0.6 5.6 0.6 5.5 0.6 4.3 0.65 2.9 0.65 2.7 0.65 5.6 0.65 5.4 0.654.3 0.7 2.9 0.7 2.7 0.7 5.7 0.7 5.2 0.7 4.3 0.75 2.9 0.75 2.7 0.75 5.70.75 5.0 0.75 4.2 0.8 2.7 0.8 2.6 0.8 5.7 0.8 4.7 0.8 4.0 0.85 2.5 0.852.4 0.85 5.6 0.85 4.2 0.85 3.7 0.9 2.2 0.9 2.1 0.9 4.8 0.9 3.5 0.9 3.20.95 1.8 0.95 1.7 0.95 3.4 0.95 2.5 0.95 2.4 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ Organics OrganicsOrganics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 F1233zdE +F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.033 F245cb + 0.033F245cb + 0.9 F245cb + 0.033 F245cb + 0.25 F245cb + 0.034 F1234zeZ 0.034F1234zeZ 0.034 F1234zeZ 0.9 F1234zeZ 0.25 F1234zeZ TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 01.7 0 1.5 0 4.3 0 1.9 0 2.3 0.05 2.8 0.05 2.6 0.05 5.5 0.05 3.0 0.05 3.50.1 2.8 0.1 2.6 0.1 5.5 0.1 3.0 0.1 3.5 0.15 2.8 0.15 2.6 0.15 5.5 0.153.0 0.15 3.5 0.2 2.8 0.2 2.6 0.2 5.5 0.2 3.0 0.2 3.5 0.25 2.8 0.25 2.60.25 5.5 0.25 3.0 0.25 3.5 0.3 2.8 0.3 2.6 0.3 5.5 0.3 3.0 0.3 3.5 0.352.8 0.35 2.6 0.35 5.5 0.35 3.0 0.35 3.5 0.4 2.8 0.4 2.6 0.4 5.5 0.4 3.00.4 3.5 0.45 2.8 0.45 2.6 0.45 5.5 0.45 3.0 0.45 3.5 0.5 2.8 0.5 2.6 0.55.5 0.5 3.0 0.5 3.5 0.55 2.8 0.55 2.6 0.55 5.5 0.55 3.0 0.55 3.5 0.6 2.80.6 2.6 0.6 5.5 0.6 3.0 0.6 3.5 0.65 2.8 0.65 2.6 0.65 5.5 0.65 3.0 0.653.6 0.7 2.8 0.7 2.6 0.7 5.6 0.7 3.0 0.7 3.6 0.75 2.8 0.75 2.6 0.75 5.60.75 3.0 0.75 3.6 0.8 2.7 0.8 2.5 0.8 5.6 0.8 2.9 0.8 3.5 0.85 2.5 0.852.3 0.85 5.5 0.85 2.7 0.85 3.3 0.9 2.2 0.9 2.1 0.9 4.8 0.9 2.4 0.9 2.80.95 1.8 0.95 1.7 0.95 3.4 0.95 1.9 0.95 2.2 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1243zf Organics OrganicsOrganics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 F1233zdE +F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.033 F245cb + 0.033F245cb + 0.9 F245cb + 0.033 F245cb + 0.25 F245cb + 0.034 F1243zf 0.034F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 0 1.8 01.6 0 4.5 0 5.6 0 3.5 0.05 3.0 0.05 2.8 0.05 5.7 0.05 6.5 0.05 4.6 0.13.0 0.1 2.8 0.1 5.7 0.1 6.6 0.1 4.6 0.15 3.0 0.15 2.8 0.15 5.7 0.15 6.60.15 4.6 0.2 3.0 0.2 2.8 0.2 5.7 0.2 6.5 0.2 4.6 0.25 3.0 0.25 2.8 0.255.7 0.25 6.5 0.25 4.6 0.3 3.0 0.3 2.8 0.3 5.7 0.3 6.5 0.3 4.6 0.35 2.90.35 2.8 0.35 5.7 0.35 6.5 0.35 4.6 0.4 2.9 0.4 2.8 0.4 5.7 0.4 6.5 0.44.6 0.45 2.9 0.45 2.7 0.45 5.7 0.45 6.5 0.45 4.6 0.5 2.9 0.5 2.7 0.5 5.70.5 6.5 0.5 4.6 0.55 2.9 0.55 2.7 0.55 5.7 0.55 6.5 0.55 4.6 0.6 2.9 0.62.7 0.6 5.7 0.6 6.5 0.6 4.6 0.65 2.9 0.65 2.7 0.65 5.7 0.65 6.4 0.65 4.60.7 2.9 0.7 2.7 0.7 5.7 0.7 6.4 0.7 4.7 0.75 2.9 0.75 2.7 0.75 5.7 0.756.2 0.75 4.6 0.8 2.8 0.8 2.6 0.8 5.7 0.8 5.9 0.8 4.4 0.85 2.6 0.85 2.40.85 5.6 0.85 5.4 0.85 4.1 0.9 2.3 0.9 2.2 0.9 4.8 0.9 4.6 0.9 3.5 0.951.8 0.95 1.8 0.95 3.4 0.95 3.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ Organics OrganicsOrganics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033 F1233xf + 0.033Organics Organics F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.034F1233xf + 0.033 0.25 F1233xf + 0.25 F1233zdE + 0.034 F1233zdE + 0.0340.9 F1233zdE + F1234zeE + 0.033 F1234zeE + 0.25 F1233zdE F1234zeZF1234zeZ 0.034 F1234zeZ F1233zdE + 0.9 F1234zeZ 0.25 F1234zeZ TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF barHF bar 0 1.7 0 4.6 0 1.5 0 1.9 0 2.4 0.05 2.8 0.05 5.5 0.05 2.6 0.05 3.00.05 3.5 0.1 2.8 0.1 5.5 0.1 2.6 0.1 3.0 0.1 3.5 0.15 2.8 0.15 5.5 0.152.6 0.15 3.0 0.15 3.5 0.2 2.8 0.2 5.5 0.2 2.6 0.2 3.0 0.2 3.5 0.25 2.80.25 5.5 0.25 2.6 0.25 3.0 0.25 3.5 0.3 2.8 0.3 5.5 0.3 2.6 0.3 3.0 0.33.5 0.35 2.8 0.35 5.5 0.35 2.6 0.35 3.0 0.35 3.5 0.4 2.8 0.4 5.5 0.4 2.60.4 3.0 0.4 3.5 0.45 2.8 0.45 5.5 0.45 2.6 0.45 3.0 0.45 3.5 0.5 2.8 0.55.5 0.5 2.6 0.5 3.0 0.5 3.5 0.55 2.8 0.55 5.4 0.55 2.6 0.55 3.0 0.55 3.40.6 2.8 0.6 5.4 0.6 2.6 0.6 3.0 0.6 3.4 0.65 2.8 0.65 5.3 0.65 2.6 0.653.0 0.65 3.4 0.7 2.8 0.7 5.1 0.7 2.5 0.7 3.0 0.7 3.4 0.75 2.7 0.75 4.90.75 2.5 0.75 3.0 0.75 3.3 0.8 2.6 0.8 4.6 0.8 2.4 0.8 2.8 0.8 3.1 0.852.4 0.85 4.1 0.85 2.3 0.85 2.6 0.85 2.9 0.9 2.1 0.9 3.4 0.9 2.0 0.9 2.30.9 2.5 0.95 1.7 0.95 2.5 0.95 1.7 0.95 1.9 0.95 1.9 1 1.2 1 1.2 1 1.2 11.2 1 1.2 HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf OrganicsOrganics Organics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf +0.9 0.033 F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.9 F1234zeE + 1234zeE +0.25 F1233zdE + F1233zdE + F1233zdE + 0.033 F1233zdE + 0.034 F1243zf0.034 F1243zf 0.034 F1243zf F1233zdE + 0.9 F1243zf 0.25 F1243zf TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF barHF bar 0 1.9 0 4.7 0 1.7 0 5.6 0 3.6 0.05 3.0 0.05 5.7 0.05 2.8 0.05 6.50.05 4.7 0.1 3.0 0.1 5.7 0.1 2.8 0.1 6.6 0.1 4.7 0.15 3.0 0.15 5.7 0.152.8 0.15 6.6 0.15 4.7 0.2 3.0 0.2 5.7 0.2 2.8 0.2 6.5 0.2 4.7 0.25 3.00.25 5.7 0.25 2.8 0.25 6.5 0.25 4.6 0.3 2.9 0.3 5.7 0.3 2.7 0.3 6.5 0.34.6 0.35 2.9 0.35 5.7 0.35 2.7 0.35 6.5 0.35 4.6 0.4 2.9 0.4 5.7 0.4 2.70.4 6.5 0.4 4.6 0.45 2.9 0.45 5.7 0.45 2.7 0.45 6.5 0.45 4.6 0.5 2.9 0.55.6 0.5 2.7 0.5 6.5 0.5 4.6 0.55 2.9 0.55 5.6 0.55 2.7 0.55 6.5 0.55 4.60.6 2.9 0.6 5.5 0.6 2.7 0.6 6.5 0.6 4.6 0.65 2.9 0.65 5.4 0.65 2.7 0.656.4 0.65 4.5 0.7 2.9 0.7 5.3 0.7 2.7 0.7 6.3 0.7 4.5 0.75 2.9 0.75 5.00.75 2.7 0.75 6.2 0.75 4.3 0.8 2.7 0.8 4.7 0.8 2.6 0.8 5.9 0.8 4.1 0.852.5 0.85 4.2 0.85 2.4 0.85 5.4 0.85 3.7 0.9 2.2 0.9 3.5 0.9 2.1 0.9 4.60.9 3.1 0.95 1.8 0.95 2.5 0.95 1.7 0.95 3.3 0.95 2.3 1 1.2 1 1.2 1 1.2 11.2 1 1.2 HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf OrganicsOrganics Organics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf +0.9 0.033 F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + F1234zeZ + F1234zeZ +F1233zdE + F1233zdE + 0.9 F1233zdE + 0.033 0.25 F1233zdE + 0.034 F1243zf0.034 F1243zf 0.034 F1243zf F1233zdE + 0.9 F1243zf 0.25 F1243zf TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF barHF bar 0 1.7 0 1.9 0 1.5 0 5.5 0 2.8 0.05 2.8 0.05 3.0 0.05 2.6 0.05 6.40.05 3.9 0.1 2.8 0.1 3.0 0.1 2.6 0.1 6.5 0.1 3.9 0.15 2.8 0.15 3.0 0.152.6 0.15 6.5 0.15 3.9 0.2 2.8 0.2 3.0 0.2 2.6 0.2 6.5 0.2 3.9 0.25 2.80.25 3.0 0.25 2.6 0.25 6.5 0.25 3.9 0.3 2.8 0.3 3.0 0.3 2.6 0.3 6.5 0.33.9 0.35 2.8 0.35 3.0 0.35 2.6 0.35 6.5 0.35 3.9 0.4 2.8 0.4 3.0 0.4 2.60.4 6.5 0.4 3.9 0.45 2.8 0.45 3.0 0.45 2.6 0.45 6.4 0.45 3.9 0.5 2.8 0.53.0 0.5 2.6 0.5 6.4 0.5 3.9 0.55 2.8 0.55 3.0 0.55 2.6 0.55 6.4 0.55 3.90.6 2.8 0.6 3.0 0.6 2.6 0.6 6.4 0.6 3.9 0.65 2.8 0.65 3.0 0.65 2.6 0.656.4 0.65 3.8 0.7 2.8 0.7 3.0 0.7 2.6 0.7 6.3 0.7 3.8 0.75 2.8 0.75 3.00.75 2.6 0.75 6.1 0.75 3.7 0.8 2.7 0.8 2.9 0.8 2.5 0.8 5.8 0.8 3.6 0.852.5 0.85 2.7 0.85 2.3 0.85 5.3 0.85 3.3 0.9 2.2 0.9 2.4 0.9 2.1 0.9 4.50.9 2.8 0.95 1.8 0.95 1.9 0.95 1.7 0.95 3.2 0.95 2.2 1 1.2 1 1.2 1 1.2 11.2 1 1.2 HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ OrganicsOrganics Organics 0.9 F245cb + 0.033 0.033 F245cb + 0.9 0.033 F245cb +0.033 Organics Organics F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE +0.034 F245cb + 0.033 0.25 F245cb + 0.25 F1233zdE + 0.034 F1233zdE +0.034 0.9 F1233zdE + F1234zeE + 0.033 F1234zeE + 0.25 F1233zdE F1234zeZF1234zeZ 0.034 F1234zeZ F1233zdE + 0.9 F1234zeZ 0.25 F1234zeZ TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF barHF bar 0 4.4 0 4.7 0 1.6 0 2.0 0 3.2 0.05 5.6 0.05 5.6 0.05 2.7 0.05 3.10.05 4.3 0.1 5.6 0.1 5.6 0.1 2.7 0.1 3.1 0.1 4.3 0.15 5.6 0.15 5.6 0.152.7 0.15 3.1 0.15 4.3 0.2 5.6 0.2 5.6 0.2 2.7 0.2 3.1 0.2 4.3 0.25 5.60.25 5.6 0.25 2.7 0.25 3.1 0.25 4.3 0.3 5.6 0.3 5.6 0.3 2.7 0.3 3.1 0.34.3 0.35 5.6 0.35 5.6 0.35 2.7 0.35 3.1 0.35 4.3 0.4 5.6 0.4 5.6 0.4 2.70.4 3.1 0.4 4.3 0.45 5.6 0.45 5.6 0.45 2.7 0.45 3.1 0.45 4.3 0.5 5.6 0.55.6 0.5 2.7 0.5 3.1 0.5 4.3 0.55 5.6 0.55 5.6 0.55 2.7 0.55 3.1 0.55 4.30.6 5.6 0.6 5.5 0.6 2.7 0.6 3.1 0.6 4.3 0.65 5.6 0.65 5.4 0.65 2.7 0.653.1 0.65 4.3 0.7 5.7 0.7 5.2 0.7 2.7 0.7 3.1 0.7 4.3 0.75 5.7 0.75 5.00.75 2.7 0.75 3.1 0.75 4.3 0.8 5.7 0.8 4.7 0.8 2.6 0.8 3.0 0.8 4.1 0.855.6 0.85 4.2 0.85 2.4 0.85 2.7 0.85 3.7 0.9 4.8 0.9 3.5 0.9 2.1 0.9 2.40.9 3.2 0.95 3.4 0.95 2.5 0.95 1.7 0.95 1.9 0.95 2.4 1 1.2 1 1.2 1 1.2 11.2 1 1.2 HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf OrganicsOrganics Organics Organics Organics 0.9 F245cb + 0.033 0.033 F245cb +0.9 0.033 F245cb + 0.033 0.034 F245cb + 0.033 0.25 F245cb + 0.25F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + F1234zeE + 0.033 F1234zeE +F1233zdE + F1233zdE + 0.9 F1233zdE + F1233zdE + 0.25 F1233zdE + 0.034F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTALTOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 04.6 0 4.8 0 1.8 0 5.7 0 4.3 0.05 5.8 0.05 5.8 0.05 2.9 0.05 6.6 0.05 5.40.1 5.8 0.1 5.8 0.1 2.9 0.1 6.6 0.1 5.4 0.15 5.8 0.15 5.8 0.15 2.9 0.156.6 0.15 5.4 0.2 5.8 0.2 5.8 0.2 2.9 0.2 6.6 0.2 5.4 0.25 5.8 0.25 5.80.25 2.9 0.25 6.6 0.25 5.4 0.3 5.8 0.3 5.8 0.3 2.9 0.3 6.6 0.3 5.4 0.355.8 0.35 5.8 0.35 2.9 0.35 6.6 0.35 5.4 0.4 5.8 0.4 5.8 0.4 2.9 0.4 6.60.4 5.4 0.45 5.8 0.45 5.8 0.45 2.9 0.45 6.6 0.45 5.4 0.5 5.8 0.5 5.7 0.52.9 0.5 6.6 0.5 5.4 0.55 5.8 0.55 5.7 0.55 2.9 0.55 6.6 0.55 5.4 0.6 5.80.6 5.6 0.6 2.9 0.6 6.6 0.6 5.4 0.65 5.8 0.65 5.5 0.65 2.8 0.65 6.5 0.655.4 0.7 5.8 0.7 5.4 0.7 2.8 0.7 6.4 0.7 5.4 0.75 5.8 0.75 5.2 0.75 2.80.75 6.3 0.75 5.2 0.8 5.8 0.8 4.8 0.8 2.7 0.8 6.0 0.8 5.0 0.85 5.7 0.854.3 0.85 2.5 0.85 5.5 0.85 4.5 0.9 4.9 0.9 3.6 0.9 2.2 0.9 4.7 0.9 3.90.95 3.5 0.95 2.6 0.95 1.8 0.95 3.3 0.95 2.8 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf Organics OrganicsOrganics Organics Organics 0.9 F245cb + 0.033 0.033 F245cb + 0.9 0.033F245cb + 0.033 0.034 F245cb + 0.033 0.25 F245cb + 0.25 F1234zeZ + 0.033F1234zeZ + 0.033 F1234zeZ + F1234zeZ + 0.033 F1234zeZ + F1233zdE +F1233zdE + 0.9 F1233zdE + F1233zdE + 0.25 F1233zdE + 0.034 F1243zf 0.034F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 0 4.5 02.0 0 1.7 0 5.6 0 3.5 0.05 5.7 0.05 3.2 0.05 2.8 0.05 6.5 0.05 4.6 0.15.7 0.1 3.2 0.1 2.8 0.1 6.6 0.1 4.6 0.15 5.7 0.15 3.2 0.15 2.8 0.15 6.60.15 4.6 0.2 5.7 0.2 3.2 0.2 2.8 0.2 6.5 0.2 4.6 0.25 5.7 0.25 3.2 0.252.8 0.25 6.5 0.25 4.6 0.3 5.7 0.3 3.2 0.3 2.8 0.3 6.5 0.3 4.6 0.35 5.70.35 3.2 0.35 2.8 0.35 6.5 0.35 4.6 0.4 5.7 0.4 3.2 0.4 2.8 0.4 6.5 0.44.6 0.45 5.7 0.45 3.2 0.45 2.8 0.45 6.5 0.45 4.6 0.5 5.7 0.5 3.2 0.5 2.80.5 6.5 0.5 4.7 0.55 5.7 0.55 3.2 0.55 2.8 0.55 6.5 0.55 4.7 0.6 5.7 0.63.2 0.6 2.8 0.6 6.5 0.6 4.7 0.65 5.7 0.65 3.2 0.65 2.8 0.65 6.4 0.65 4.70.7 5.7 0.7 3.2 0.7 2.8 0.7 6.4 0.7 4.7 0.75 5.7 0.75 3.1 0.75 2.8 0.756.2 0.75 4.7 0.8 5.7 0.8 3.0 0.8 2.6 0.8 5.9 0.8 4.5 0.85 5.6 0.85 2.80.85 2.4 0.85 5.4 0.85 4.1 0.9 4.8 0.9 2.5 0.9 2.2 0.9 4.6 0.9 3.5 0.953.4 0.95 1.9 0.95 1.8 0.95 3.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf Organics OrganicsOrganics Organics Organics 0.9 F1234zeE + 0.033 0.033 F1234zeE + 0.90.033 F1234zeE + 0.033 0.034 F1234zeE + 0.033 0.25 F1234zeE + 0.25F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + F1234zeZ + 0.033 F1234zeZ +F1233zdE + F1233zdE + 0.9 F1233zdE + F1233zdE + 0.25 F1233zdE + 0.034F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTALTOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 04.7 0 2.1 0 1.7 0 5.6 0 3.6 0.05 5.7 0.05 3.2 0.05 2.8 0.05 6.5 0.05 4.70.1 5.7 0.1 3.2 0.1 2.8 0.1 6.6 0.1 4.7 0.15 5.7 0.15 3.2 0.15 2.8 0.156.5 0.15 4.7 0.2 5.7 0.2 3.2 0.2 2.8 0.2 6.5 0.2 4.7 0.25 5.7 0.25 3.20.25 2.8 0.25 6.5 0.25 4.7 0.3 5.7 0.3 3.2 0.3 2.8 0.3 6.5 0.3 4.6 0.355.7 0.35 3.1 0.35 2.8 0.35 6.5 0.35 4.6 0.4 5.7 0.4 3.1 0.4 2.8 0.4 6.50.4 4.6 0.45 5.7 0.45 3.1 0.45 2.7 0.45 6.5 0.45 4.6 0.5 5.6 0.5 3.1 0.52.7 0.5 6.5 0.5 4.6 0.55 5.6 0.55 3.1 0.55 2.7 0.55 6.5 0.55 4.6 0.6 5.50.6 3.1 0.6 2.7 0.6 6.5 0.6 4.6 0.65 5.4 0.65 3.1 0.65 2.7 0.65 6.4 0.654.6 0.7 5.3 0.7 3.1 0.7 2.7 0.7 6.3 0.7 4.5 0.75 5.0 0.75 3.1 0.75 2.70.75 6.2 0.75 4.3 0.8 4.7 0.8 3.0 0.8 2.6 0.8 5.9 0.8 4.1 0.85 4.2 0.852.7 0.85 2.4 0.85 5.4 0.85 3.7 0.9 3.5 0.9 2.4 0.9 2.1 0.9 4.6 0.9 3.20.95 2.5 0.95 1.9 0.95 1.7 0.95 3.3 0.95 2.4 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233xF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE Organics 0.033Organics Organics Organics Organics 0.9 F1233xf + F1233xf + 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 0.033F1234zeE + 0.033 0.9 F1234zeE + 0.033 F1234zeE + F1234zeE + 0.033F1234zeE + F1233zdE + F1233zdE + 0.9 F1233zdE + F1233zdE + 0.25F1233zdE + 0.034 F1234yf 0.034 F1234yf 0.034 F1234yf 0.9 F1234yf 0.25F1234yf TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HFbar HF bar HF bar HF bar 0 1.9 0 4.7 0 1.7 0 6.4 0 3.8 0.05 3.0 0.05 5.70.05 2.8 0.05 7.4 0.05 4.8 0.1 3.0 0.1 5.7 0.1 2.8 0.1 7.4 0.1 4.8 0.153.0 0.15 5.7 0.15 2.8 0.15 7.4 0.15 4.8 0.2 3.0 0.2 5.7 0.2 2.8 0.2 7.40.2 4.8 0.25 3.0 0.25 5.7 0.25 2.8 0.25 7.4 0.25 4.8 0.3 3.0 0.3 5.7 0.32.8 0.3 7.4 0.3 4.8 0.35 3.0 0.35 5.7 0.35 2.8 0.35 7.4 0.35 4.8 0.4 3.00.4 5.7 0.4 2.8 0.4 7.4 0.4 4.8 0.45 3.0 0.45 5.7 0.45 2.8 0.45 7.4 0.454.8 0.5 3.0 0.5 5.7 0.5 2.8 0.5 7.4 0.5 4.8 0.55 3.0 0.55 5.6 0.55 2.80.55 7.4 0.55 4.8 0.6 3.0 0.6 5.5 0.6 2.8 0.6 7.4 0.6 4.8 0.65 2.9 0.655.4 0.65 2.7 0.65 7.4 0.65 4.8 0.7 2.9 0.7 5.3 0.7 2.7 0.7 7.4 0.7 4.70.75 2.9 0.75 5.1 0.75 2.7 0.75 7.2 0.75 4.6 0.8 2.8 0.8 4.7 0.8 2.6 0.86.9 0.8 4.3 0.85 2.6 0.85 4.2 0.85 2.4 0.85 6.3 0.85 3.9 0.9 2.3 0.9 3.60.9 2.1 0.9 5.3 0.9 3.3 0.95 1.8 0.95 2.6 0.95 1.7 0.95 3.7 0.95 2.4 11.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE Organics OrganicsOrganics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 F1234zeZ +0.033 F1234zeZ + 0.033 F1234zeZ + F1234zeZ + 0.033 F1234zeZ + F1233zdE +F1233zdE + 0.9 F1233zdE + F1233zdE + 0.25 F1233zdE + 0.034 F1234yf 0.034F1234zf 0.034 F1234yf 0.9 F1234yf 0.25 F1234yf TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 0 1.8 02.0 0 1.6 0 6.3 0 3.0 0.05 2.9 0.05 3.1 0.05 2.7 0.05 7.3 0.05 4.1 0.12.9 0.1 3.1 0.1 2.7 0.1 7.3 0.1 4.1 0.15 2.9 0.15 3.1 0.15 2.7 0.15 7.30.15 4.1 0.2 2.9 0.2 3.1 0.2 2.7 0.2 7.3 0.2 4.1 0.25 2.9 0.25 3.1 0.252.7 0.25 7.3 0.25 4.1 0.3 2.9 0.3 3.1 0.3 2.7 0.3 7.3 0.3 4.1 0.35 2.90.35 3.1 0.35 2.7 0.35 7.3 0.35 4.1 0.4 2.9 0.4 3.1 0.4 2.7 0.4 7.3 0.44.1 0.45 2.9 0.45 3.1 0.45 2.7 0.45 7.3 0.45 4.1 0.5 2.9 0.5 3.1 0.5 2.70.5 7.3 0.5 4.1 0.55 2.9 0.55 3.1 0.55 2.7 0.55 7.3 0.55 4.1 0.6 2.9 0.63.1 0.6 2.7 0.6 7.3 0.6 4.1 0.65 2.9 0.65 3.1 0.65 2.7 0.65 7.3 0.65 4.10.7 2.9 0.7 3.1 0.7 2.7 0.7 7.3 0.7 4.0 0.75 2.8 0.75 3.1 0.75 2.6 0.757.1 0.75 4.0 0.8 2.7 0.8 2.9 0.8 2.5 0.8 6.8 0.8 3.8 0.85 2.5 0.85 2.70.85 2.4 0.85 6.2 0.85 3.5 0.9 2.2 0.9 2.4 0.9 2.1 0.9 5.3 0.9 3.0 0.951.8 0.95 1.9 0.95 1.7 0.95 3.7 0.95 2.3 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1243zf Organics OrganicsOrganics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 F1243zf +F1243zf + F1243zf + F1243zf + F1243zf + 0.033 F1233zdE + 0.033F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.25 F1233zdE + 0.034 F1234yf0.034 F1234yf 0.034 F1234yf 0.9 F1234yf 0.25 F1234yf TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 01.9 0 5.6 0 1.7 0 6.4 0 4.1 0.05 3.0 0.05 6.6 0.05 2.8 0.05 7.4 0.05 5.20.1 3.0 0.1 6.6 0.1 2.8 0.1 7.4 0.1 5.2 0.15 3.0 0.15 6.6 0.15 2.8 0.157.4 0.15 5.2 0.2 3.0 0.2 6.6 0.2 2.8 0.2 7.4 0.2 5.2 0.25 3.0 0.25 6.60.25 2.8 0.25 7.4 0.25 5.2 0.3 3.0 0.3 6.6 0.3 2.8 0.3 7.4 0.3 5.2 0.353.0 0.35 6.6 0.35 2.8 0.35 7.4 0.35 5.2 0.4 3.0 0.4 6.6 0.4 2.8 0.4 7.40.4 5.2 0.45 3.0 0.45 6.6 0.45 2.8 0.45 7.4 0.45 5.2 0.5 3.0 0.5 6.6 0.52.8 0.5 7.4 0.5 5.1 0.55 3.0 0.55 6.6 0.55 2.8 0.55 7.4 0.55 5.1 0.6 3.00.6 6.5 0.6 2.8 0.6 7.4 0.6 5.1 0.65 3.0 0.65 6.5 0.65 2.8 0.65 7.4 0.655.1 0.7 3.0 0.7 6.4 0.7 2.8 0.7 7.4 0.7 5.1 0.75 3.0 0.75 6.2 0.75 2.80.75 7.2 0.75 4.9 0.8 2.8 0.8 6.0 0.8 2.7 0.8 6.9 0.8 4.7 0.85 2.6 0.855.5 0.85 2.5 0.85 6.3 0.85 4.3 0.9 2.3 0.9 4.6 0.9 2.2 0.9 5.3 0.9 3.70.95 1.8 0.95 3.3 0.95 1.8 0.95 3.7 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE Organics OrganicsOrganics 0.9 F1234yf + 0.033 0.033 F1234yf + 0.9 0.033 F1234yf + 0.033Organics Organics F1233zdE + 0.033 F1233zdE + 0.033 F1233zdE + 0.034F1234yf + 0.033 0.25 F1234yf + 0.25 F1234zeE + 0.034 F1234zeE + 0.0340.9 F1234zeE + F1233zdE + 0.033 F1233zdE + 0.25 F1234zeE + F1234zeZF1234zeZ 0.034 F1234zeZ F1234zeE + 0.9 F1234zeZ 0.25 F1234zeZ TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF barHF bar 0 6.4 0 1.7 0 4.7 0 2.1 0 3.8 0.05 7.4 0.05 2.8 0.05 5.7 0.05 3.20.05 4.8 0.1 7.4 0.1 2.8 0.1 5.7 0.1 3.2 0.1 4.8 0.15 7.4 0.15 2.8 0.155.7 0.15 3.2 0.15 4.8 0.2 7.4 0.2 2.8 0.2 5.7 0.2 3.2 0.2 4.8 0.25 7.40.25 2.8 0.25 5.7 0.25 3.2 0.25 4.8 0.3 7.4 0.3 2.8 0.3 5.7 0.3 3.2 0.34.8 0.35 7.4 0.35 2.8 0.35 5.7 0.35 3.2 0.35 4.8 0.4 7.4 0.4 2.8 0.4 5.70.4 3.2 0.4 4.8 0.45 7.4 0.45 2.8 0.45 5.7 0.45 3.2 0.45 4.8 0.5 7.4 0.52.8 0.5 5.7 0.5 3.2 0.5 4.8 0.55 7.4 0.55 2.8 0.55 5.6 0.55 3.2 0.55 4.80.6 7.4 0.6 2.8 0.6 5.5 0.6 3.2 0.6 4.8 0.65 7.4 0.65 2.7 0.65 5.4 0.653.2 0.65 4.8 0.7 7.4 0.7 2.7 0.7 5.3 0.7 3.2 0.7 4.7 0.75 7.2 0.75 2.70.75 5.1 0.75 3.1 0.75 4.6 0.8 6.9 0.8 2.6 0.8 4.7 0.8 3.0 0.8 4.3 0.856.3 0.85 2.4 0.85 4.2 0.85 2.8 0.85 4.0 0.9 5.3 0.9 2.1 0.9 3.6 0.9 2.40.9 3.4 0.95 3.7 0.95 1.7 0.95 2.6 0.95 1.9 0.95 2.5 1 1.2 1 1.2 1 1.2 11.2 1 1.2 HF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics 0.9 F1234yf + 0.033 0.033 F1234yf +0.9 0.033 F1234yf + 0.033 0.034 F1234yf + 0.033 0.25 F1234yf + 0.25F1233zdE + 0.033 F1233zdE + 0.033 F1233zdE + F1233zdE + 0.033 F1233zdE +F1234zeE + F1234zeE + 0.9 F1234zeE + F1234zeE + 0.25 F1234zeE + 0.034F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTALTOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 06.5 0 1.9 0 4.9 0 5.7 0 4.8 0.05 7.5 0.05 3.0 0.05 5.8 0.05 6.7 0.05 5.80.1 7.5 0.1 3.0 0.1 5.9 0.1 6.7 0.1 5.9 0.15 7.5 0.15 3.0 0.15 5.8 0.156.7 0.15 5.9 0.2 7.5 0.2 3.0 0.2 5.8 0.2 6.7 0.2 5.9 0.25 7.5 0.25 3.00.25 5.8 0.25 6.7 0.25 5.9 0.3 7.5 0.3 3.0 0.3 5.8 0.3 6.7 0.3 5.9 0.357.5 0.35 2.9 0.35 5.8 0.35 6.7 0.35 5.9 0.4 7.5 0.4 2.9 0.4 5.8 0.4 6.70.4 5.9 0.45 7.5 0.45 2.9 0.45 5.8 0.45 6.7 0.45 5.9 0.5 7.5 0.5 2.9 0.55.8 0.5 6.7 0.5 5.8 0.55 7.5 0.55 2.9 0.55 5.8 0.55 6.6 0.55 5.8 0.6 7.50.6 2.9 0.6 5.7 0.6 6.6 0.6 5.8 0.65 7.5 0.65 2.9 0.65 5.6 0.65 6.6 0.655.8 0.7 7.5 0.7 2.9 0.7 5.4 0.7 6.5 0.7 5.7 0.75 7.3 0.75 2.9 0.75 5.20.75 6.3 0.75 5.5 0.8 7.0 0.8 2.7 0.8 4.9 0.8 6.0 0.8 5.2 0.85 6.4 0.852.5 0.85 4.4 0.85 5.5 0.85 4.8 0.9 5.4 0.9 2.2 0.9 3.6 0.9 4.7 0.9 4.00.95 3.7 0.95 1.8 0.95 2.6 0.95 3.3 0.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf Organics OrganicsOrganics Organics Organics 0.9 F1234yf + 0.033 0.033 F1234yf + 0.9 0.033F1234yf + 0.033 0.034 F1234yf + 0.033 0.25 F1234yf + 0.25 F1233zdE +0.033 F1233zdE + F1233zdE + F1233zdE + 0.033 F1233zdE + F1234zeZ + 0.033F1234zeZ + 0.9 F1234zeZ + F1234zeZ + 0.25 F1234zeZ + 0.034 F1243zf 0.034F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 0 6.4 01.7 0 2.1 0 5.6 0 4.1 0.05 7.4 0.05 2.9 0.05 3.2 0.05 6.6 0.05 5.2 0.17.4 0.1 2.9 0.1 3.2 0.1 6.6 0.1 5.2 0.15 7.4 0.15 2.9 0.15 3.2 0.15 6.60.15 5.2 0.2 7.4 0.2 2.9 0.2 3.2 0.2 6.6 0.2 5.2 0.25 7.4 0.25 2.8 0.253.2 0.25 6.6 0.25 5.2 0.3 7.4 0.3 2.8 0.3 3.2 0.3 6.6 0.3 5.2 0.35 7.40.35 2.8 0.35 3.2 0.35 6.6 0.35 5.1 0.4 7.4 0.4 2.8 0.4 3.2 0.4 6.6 0.45.1 0.45 7.4 0.45 2.8 0.45 3.2 0.45 6.6 0.45 5.1 0.5 7.4 0.5 2.8 0.5 3.20.5 6.6 0.5 5.1 0.55 7.4 0.55 2.8 0.55 3.2 0.55 6.6 0.55 5.1 0.6 7.4 0.62.8 0.6 3.2 0.6 6.5 0.6 5.1 0.65 7.4 0.65 2.8 0.65 3.2 0.65 6.5 0.65 5.10.7 7.4 0.7 2.8 0.7 3.2 0.7 6.4 0.7 5.1 0.75 7.2 0.75 2.8 0.75 3.2 0.756.2 0.75 5.0 0.8 6.9 0.8 2.7 0.8 3.0 0.8 5.9 0.8 4.7 0.85 6.3 0.85 2.50.85 2.8 0.85 5.5 0.85 4.3 0.9 5.3 0.9 2.2 0.9 2.5 0.9 4.6 0.9 3.7 0.953.7 0.95 1.8 0.95 2.0 0.95 3.3 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE Organics OrganicsOrganics Organics Organics 0.9 F1234yf + 0.033 0.033 F1234yf + 0.9 0.033F1234yf + 0.033 0.034 F1234yf + 0.033 0.25 F1234yf + 0.25 F1234zeE +F1234zeE + F1234zeE + F1234zeE + F1234zeE + 0.033 F245cb + 0.033F245cb + 0.9 F245cb + 0.033 F245cb + 0.25 F245cb + 0.034 F1233zdE 0.034F1233zdE 0.034 F1233zdE 0.9 F1233zdE 0.25 F1233zdE TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 06.5 0 4.8 0 4.6 0 1.8 0 4.5 0.05 7.5 0.05 5.8 0.05 5.8 0.05 2.9 0.05 5.60.1 7.5 0.1 5.8 0.1 5.8 0.1 2.9 0.1 5.6 0.15 7.5 0.15 5.8 0.15 5.8 0.152.9 0.15 5.6 0.2 7.5 0.2 5.8 0.2 5.8 0.2 2.9 0.2 5.6 0.25 7.5 0.25 5.80.25 5.8 0.25 2.9 0.25 5.6 0.3 7.5 0.3 5.8 0.3 5.8 0.3 2.9 0.3 5.6 0.357.5 0.35 5.8 0.35 5.8 0.35 2.9 0.35 5.6 0.4 7.5 0.4 5.8 0.4 5.8 0.4 2.90.4 5.6 0.45 7.5 0.45 5.8 0.45 5.8 0.45 2.9 0.45 5.6 0.5 7.5 0.5 5.8 0.55.8 0.5 2.9 0.5 5.6 0.55 7.5 0.55 5.7 0.55 5.8 0.55 2.9 0.55 5.6 0.6 7.50.6 5.7 0.6 5.8 0.6 2.9 0.6 5.6 0.65 7.5 0.65 5.6 0.65 5.8 0.65 2.9 0.655.6 0.7 7.5 0.7 5.4 0.7 5.8 0.7 2.9 0.7 5.6 0.75 7.3 0.75 5.2 0.75 5.80.75 2.9 0.75 5.5 0.8 7.0 0.8 4.9 0.8 5.8 0.8 2.7 0.8 5.2 0.85 6.4 0.854.4 0.85 5.7 0.85 2.5 0.85 4.8 0.9 5.4 0.9 3.6 0.9 4.9 0.9 2.2 0.9 4.10.95 3.7 0.95 2.6 0.95 3.5 0.95 1.8 0.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE Organics OrganicsOrganics Organics Organics 0.9 F1234yf + 0.033 0.033 F1234yf + 0.9 0.033F1234yf + 0.033 0.034 F1234yf + 0.033 0.25 F1234yf + 0.25 F1234zeZ +F1234zeZ + F1234zeZ + F1234zeZ − F1234zeZ + 0.033 F245cb + 0.033F245cb + 0.9 F245cb + 0.033 F245cb − 0.25 F245cb + 0.034 F1233zdE 0.034F1233zdE 0.034 F1233zdE 0.9 F1233zdE 0.25 F1233zdE TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 06.4 0 2.1 0 4.5 0 1.7 0 3.7 0.05 7.4 0.05 3.2 0.05 5.7 0.05 2.8 0.05 4.80.1 7.4 0.1 3.2 0.1 5.7 0.1 2.8 0.1 4.8 0.15 7.4 0.15 3.2 0.15 5.7 0.152.8 0.15 4.8 0.2 7.4 0.2 3.2 0.2 5.7 0.2 2.8 0.2 4.8 0.25 7.4 0.25 3.20.25 5.7 0.25 2.8 0.25 4.8 0.3 7.4 0.3 3.2 0.3 5.7 0.3 2.8 0.3 4.8 0.357.4 0.35 3.2 0.35 5.7 0.35 2.8 0.35 4.8 0.4 7.4 0.4 3.2 0.4 5.7 0.4 2.80.4 4.8 0.45 7.4 0.45 3.2 0.45 5.7 0.45 2.8 0.45 4.8 0.5 7.4 0.5 3.2 0.55.7 0.5 2.8 0.5 4.8 0.55 7.4 0.55 3.2 0.55 5.7 0.55 2.8 0.55 4.8 0.6 7.40.6 3.2 0.6 5.7 0.6 2.8 0.6 4.9 0.65 7.4 0.65 3.2 0.65 5.7 0.65 2.8 0.654.9 0.7 7.4 0.7 3.2 0.7 5.7 0.7 2.8 0.7 4.9 0.75 7.2 0.75 3.2 0.75 5.70.75 2.8 0.75 4.9 0.8 6.9 0.8 3.0 0.8 5.7 0.8 2.7 0.8 4.7 0.85 6.4 0.852.8 0.85 5.7 0.85 2.5 0.85 4.3 0.9 5.4 0.9 2.5 0.9 4.9 0.9 2.2 0.9 3.70.95 3.7 0.95 2.0 0.95 3.5 0.95 1.8 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf Organics OrganicsOrganics Organics Organics 0.9 F1234yf + 0.033 0.033 F1234yf + 0.9 0.033F1234yf + 0.033 0.034 F1234yf + 0.033 0.25 F1234yf + 0.25 F1233zdE +F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.033 F245cb + 0.033F245cb + 0.9 F245cb + 0.033 F245cb + 0.25 F245cb + 0.034 F1243zf 0.034F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 0 6.5 01.8 0 4.7 0 5.7 0 4.8 0.05 7.5 0.05 2.9 0.05 5.8 0.05 6.7 0.05 5.9 0.17.5 0.1 2.9 0.1 5.8 0.1 6.7 0.1 5.9 0.15 7.5 0.15 2.9 0.15 5.8 0.15 6.70.15 5.9 0.2 7.5 0.2 2.9 0.2 5.8 0.2 6.7 0.2 5.9 0.25 7.5 0.25 2.9 0.255.8 0.25 6.7 0.25 5.9 0.3 7.5 0.3 2.9 0.3 5.8 0.3 6.7 0.3 5.9 0.35 7.50.35 2.9 0.35 5.8 0.35 6.7 0.35 5.9 0.4 7.5 0.4 2.9 0.4 5.8 0.4 6.7 0.45.9 0.45 7.5 0.45 2.9 0.45 5.8 0.45 6.7 0.45 5.9 0.5 7.5 0.5 2.9 0.5 5.80.5 6.7 0.5 5.9 0.55 7.5 0.55 2.9 0.55 5.8 0.55 6.7 0.55 5.9 0.6 7.5 0.62.9 0.6 5.8 0.6 6.6 0.6 5.9 0.65 7.5 0.65 2.9 0.65 5.8 0.65 6.6 0.65 5.90.7 7.5 0.7 2.9 0.7 5.8 0.7 6.5 0.7 5.9 0.75 7.3 0.75 2.9 0.75 5.8 0.756.3 0.75 5.8 0.8 7.0 0.8 2.8 0.8 5.8 0.8 6.1 0.8 5.6 0.85 6.5 0.85 2.60.85 5.8 0.85 5.6 0.85 5.1 0.9 5.4 0.9 2.3 0.9 5.0 0.9 4.7 0.9 4.4 0.953.8 0.95 1.8 0.95 3.5 0.95 3.4 0.95 3.1 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234yf Organics OrganicsOrganics Organics Organics 0.9 F1233xf + 0.033 0.033 F1233xf + 0.9 0.033F1233xf + 0.033 0.034 F1233xf + 0.033 0.25 F1233xf + 0.25 F1233zdE +F1233zdE + F1233zdE + F1233zdE + F1233zdE + 0.033 F245cb + 0.033F245cb + 0.9 F245cb + 0.033 F245cb + 0.25 F245cb + 0.034 F1234yf 0.034F1234yf 0.034 F1234yf 0.9 F1234yf 0.25 F1234yf TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar 0 1.9 01.7 0 4.5 0 6.4 0 3.7 0.05 3.0 0.05 2.8 0.05 5.7 0.05 7.4 0.05 4.8 0.13.0 0.1 2.8 0.1 5.7 0.1 7.4 0.1 4.8 0.15 3.0 0.15 2.8 0.15 5.7 0.15 7.40.15 4.8 0.2 3.0 0.2 2.8 0.2 5.7 0.2 7.4 0.2 4.8 0.25 3.0 0.25 2.8 0.255.7 0.25 7.4 0.25 4.8 0.3 3.0 0.3 2.8 0.3 5.7 0.3 7.4 0.3 4.8 0.35 3.00.35 2.8 0.35 5.7 0.35 7.4 0.35 4.8 0.4 3.0 0.4 2.8 0.4 5.7 0.4 7.4 0.44.8 0.45 3.0 0.45 2.8 0.45 5.7 0.45 7.4 0.45 4.8 0.5 3.0 0.5 2.8 0.5 5.70.5 7.4 0.5 4.8 0.55 3.0 0.55 2.8 0.55 5.7 0.55 7.4 0.55 4.8 0.6 3.0 0.62.8 0.6 5.7 0.6 7.4 0.6 4.8 0.65 3.0 0.65 2.8 0.65 5.7 0.65 7.4 0.65 4.90.7 3.0 0.7 2.8 0.7 5.7 0.7 7.4 0.7 4.9 0.75 3.0 0.75 2.8 0.75 5.7 0.757.2 0.75 4.9 0.8 2.8 0.8 2.7 0.8 5.7 0.8 6.9 0.8 4.7 0.85 2.6 0.85 2.50.85 5.7 0.85 6.4 0.85 4.3 0.9 2.3 0.9 2.2 0.9 4.9 0.9 5.4 0.9 3.7 0.951.8 0.95 1.8 0.95 3.5 0.95 3.7 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 11 Temperature and Pressure Range of Penternary Mixtures

Boiling point range Temperature Pressure System with 5 compounds ° C.bar HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40 ~1.0 to ~8.9 1234zeE HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ 0 to 40 ~1.0to ~8.8  HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1243zf 0 to 40 ~1.0to ~10.0 HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1243zf 0 to 40 ~1.0to ~11.2 HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO- 0 to 40 ~0.9 to~8.6  1234zeZ HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO- 0 to 40 ~1.0to ~10.1 1243zf HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ-HFO- 0 to 40~1.0 to ~9.9  1243zf HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO- 0 to 40~1.0 to ~8.9  1234zeZ HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf 0to 40 ~1.1 to ~10.2 HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf 0to 40 ~1.0 to ~10.1 HF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO- 0 to 40~1.0 to ~10.1 1243zf HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234yf 0to 40 ~1.0 to ~11.2 HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HCFO- 0 to 40~1.0 to ~11.2 1233zdE HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO- 0 to40 ~1.0 to ~11.1 1233zdE HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO- 0to 40 ~1.0 to ~11.2 1233zdEHF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf 0 to 40 ~1.0 to ~11.4HF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf 0 to 40 ~1.1 to ~11.2HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE 0 to 40 ~1.1 to ~11.4HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE 0 to 40 ~1.0 to ~11.2HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf 0 to 40 ~1.1 to ~11.4

EXAMPLE 12 Decantation Range of Oenternary Mixtures

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermSystem with 5 compounds 0° C. 25° C. 40° C.HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO- 5-75 5-70 10-60 1234zeEHF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO- 5-80 5-75  5-70 1234zeZHF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO- 5-75 5-70  5-65 1243zfHF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE- 5-75 5-70  5-60 HFO-1234zeZHF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE- 5-75 5-65 15-45 HFO-1243zfHF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ- 5-75 5-70 10-60 HFO-1243zfHF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO- 5-75 5-70 10-60 1234zeZHF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO- 5-75 10-65  * 1243zfHF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO- 5-75 5-70 10-60 1243zfHF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ- 5-75 5-65 15-50 HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO- 5-75 5-75 10-65 1234yfHF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HCFO- 5-75 5-65 10-50 1233zdEHF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO- 5-75 5-70 10-60 1233zdEHF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO- 5-75 5-65 15-45 1243zfHF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO- 5-75 5-65 15-45 1233zdEHF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO- 5-70 10-60  * 1243zfHF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO- 5-75 10-65  15-45 1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO- 5-75 10-70  * 1233zdEHF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO- 5-75 5-75 10-65 1233zdEHF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO- 5-75 10-70 * 1243zf

EXAMPLE 13 System with Six Compounds, Isotherm at 25° C.

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F245cb + F245cb + 0.01 F1233zdE + F245cb + 0.01F1233zdE + F245cb + 0.96 F1233zdE + F245cb + 0.01 F1233zdE + F245cb +0.01 F1233zdE + 0.2 F1233zdE 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE +0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96F1234zeE + 0.2 F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 2.9 0 1.6 0 4.6 0 1.4 0 4.80 1.9 0.05 4.0 0.05 2.7 0.05 5.7 0.05 2.5 0.05 5.7 0.05 3.0 0.1 4.0 0.12.7 0.1 5.7 0.1 2.5 0.1 5.8 0.1 3.0 0.15 4.0 0.15 2.7 0.15 5.7 0.15 2.50.15 5.8 0.15 3.0 0.2 4.0 0.2 2.7 0.2 5.7 0.2 2.5 0.2 5.8 0.2 3.0 0.254.0 0.25 2.7 0.25 5.7 0.25 2.5 0.25 5.8 0.25 3.0 0.3 4.0 0.3 2.7 0.3 5.70.3 2.5 0.3 5.8 0.3 3.0 0.35 4.0 0.35 2.7 0.35 5.7 0.35 2.5 0.35 5.70.35 3.0 0.4 4.0 0.4 2.7 0.4 5.7 0.4 2.5 0.4 5.7 0.4 3.0 0.45 4.0 0.452.7 0.45 5.7 0.45 2.5 0.45 5.7 0.45 3.0 0.5 4.0 0.5 2.7 0.5 5.7 0.5 2.50.5 5.7 0.5 3.0 0.55 4.0 0.55 2.7 0.55 5.7 0.55 2.5 0.55 5.6 0.55 3.00.6 4.0 0.6 2.7 0.6 5.7 0.6 2.5 0.6 5.6 0.6 3.0 0.65 4.0 0.65 2.7 0.655.7 0.65 2.5 0.65 5.5 0.65 3.0 0.7 4.0 0.7 2.7 0.7 5.8 0.7 2.5 0.7 5.30.7 3.0 0.75 4.0 0.75 2.7 0.75 5.8 0.75 2.5 0.75 5.1 0.75 3.0 0.8 3.80.8 2.6 0.8 5.8 0.8 2.4 0.8 4.7 0.8 2.6 0.85 3.5 0.85 2.4 0.85 5.8 0.852.2 0.85 4.3 0.85 2.6 0.9 3.0 0.9 2.1 0.9 5.0 0.9 2.0 0.9 3.6 0.9 2.30.95 2.3 0.95 1.7 0.95 3.5 0.95 1.7 0.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F245cb + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + F245cb + 0.96 F1243zf + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + 0.2 F1243zf + 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.010.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96F1234zeE + 0.2 F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 3.8 0 1.7 0 4.6 0 5.8 0 4.80 1.5 0.05 4.9 0.05 2.8 0.05 5.8 0.05 6.7 0.05 5.8 0.05 2.6 0.1 4.9 0.12.8 0.1 5.8 0.1 6.7 0.1 5.8 0.1 2.6 0.15 4.9 0.15 2.8 0.15 5.8 0.15 6.70.15 5.8 0.15 2.6 0.2 4.9 0.2 2.8 0.2 5.8 0.2 6.7 0.2 5.8 0.2 2.6 0.254.9 0.25 2.8 0.25 5.8 0.25 6.7 0.25 5.8 0.25 2.6 0.3 4.9 0.3 2.8 0.3 5.80.3 6.7 0.3 5.8 0.3 2.6 0.35 4.9 0.35 2.8 0.35 5.8 0.35 6.7 0.35 5.80.35 2.6 0.4 4.9 0.4 2.8 0.4 5.8 0.4 6.7 0.4 5.8 0.4 2.6 0.45 4.9 0.452.8 0.45 5.8 0.45 6.7 0.45 5.8 0.45 2.6 0.5 4.9 0.5 2.8 0.5 5.8 0.5 6.70.5 5.7 0.5 2.6 0.55 4.9 0.55 2.8 0.55 5.8 0.55 6.7 0.55 5.7 0.55 2.60.6 4.9 0.6 2.8 0.6 5.8 0.6 6.6 0.6 5.6 0.6 2.6 0.65 4.9 0.65 2.8 0.655.8 0.65 6.6 0.65 5.5 0.65 2.5 0.7 4.9 0.7 2.8 0.7 5.8 0.7 6.5 0.7 5.40.7 2.5 0.75 4.7 0.75 2.8 0.75 5.8 0.75 6.3 0.75 5.1 0.75 2.5 0.8 4.50.8 2.6 0.8 5.8 0.8 6.0 0.8 4.8 0.8 2.4 0.85 4.1 0.85 2.4 0.85 5.8 0.855.6 0.85 4.3 0.85 2.3 0.9 3.5 0.9 2.2 0.9 5.0 0.9 4.7 0.9 3.6 0.9 2.00.95 2.6 0.95 1.7 0.95 3.5 0.95 3.3 0.95 2.6 0.95 1.7 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F245cb + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + F245cb + 0.96 F1243zf + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + 0.2 F1243zf + 0.2 0.01 F1234zeZ + 0.01 0.01 F1234zeZ + 0.010.01 F1234zeZ + 0.01 0.96 F1234zeZ + 0.01 0.01 F1234zeZ + 0.96F1234zeZ + 0.2 F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 3.2 0 1.6 0 4.6 0 5.7 0 1.90 1.4 0.05 4.3 0.05 2.7 0.05 5.7 0.05 6.7 0.05 3.0 0.05 2.5 0.1 4.3 0.12.7 0.1 5.7 0.1 6.7 0.1 3.0 0.1 2.5 0.15 4.3 0.15 2.7 0.15 5.7 0.15 6.70.15 3.0 0.15 2.5 0.2 4.3 0.2 2.7 0.2 5.7 0.2 6.7 0.2 3.0 0.2 2.5 0.254.3 0.25 2.7 0.25 5.7 0.25 6.7 0.25 3.0 0.25 2.5 0.3 4.3 0.3 2.7 0.3 5.70.3 6.7 0.3 3.0 0.3 2.5 0.35 4.3 0.35 2.7 0.35 5.7 0.35 6.7 0.35 3.00.35 2.5 0.4 4.3 0.4 2.7 0.4 5.8 0.4 6.7 0.4 3.0 0.4 2.5 0.45 4.3 0.452.7 0.45 5.8 0.45 6.7 0.45 3.0 0.45 2.5 0.5 4.3 0.5 2.7 0.5 5.8 0.5 6.70.5 3.0 0.5 2.5 0.55 4.3 0.55 2.7 0.55 5.8 0.55 6.7 0.55 3.0 0.55 2.50.6 4.3 0.6 2.7 0.6 5.8 0.6 6.6 0.6 3.0 0.6 2.5 0.65 4.3 0.65 2.7 0.655.8 0.65 6.6 0.65 3.0 0.65 2.5 0.7 4.3 0.7 2.7 0.7 5.8 0.7 6.5 0.7 3.00.7 2.5 0.75 4.3 0.75 2.7 0.75 5.8 0.75 6.3 0.75 3.0 0.75 2.5 0.8 4.10.8 2.6 0.8 5.8 0.8 6.0 0.8 2.9 0.8 2.4 0.85 3.8 0.85 2.4 0.85 5.8 0.855.5 0.85 2.7 0.85 2.3 0.9 3.3 0.9 2.1 0.9 5.0 0.9 4.7 0.9 2.3 0.9 2.00.95 2.4 0.95 1.7 0.95 3.5 0.95 3.3 0.95 1.9 0.95 1.7 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F1243zf + F1243zf + 0.01 F1233zdE + F1243zf +0.01 F1233zdE + F1243zf + 0.96 F1233zdE + F1243zf + 0.01 F1233zdE +F1243zf + 0.01 F1233zdE + 0.2 F1233zdE 0.2 0.01 F1234zeE + 0.01 0.01F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01F1234zeE + 0.96 F1234zeE + 0.2 F1234zeZ F1234zeZ F1234zeZ F1234zeZF1234zeZ F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar HF bar 0 3.2 0 1.60 5.7 0 1.4 0 4.8 0 1.9 0.05 4.3 0.05 2.7 0.05 6.7 0.05 2.5 0.05 5.70.05 3.0 0.1 4.3 0.1 2.7 0.1 6.7 0.1 2.5 0.1 5.8 0.1 3.0 0.15 4.3 0.152.7 0.15 6.7 0.15 2.5 0.15 5.8 0.15 3.0 0.2 4.3 0.2 2.7 0.2 6.7 0.2 2.50.2 5.8 0.2 3.0 0.25 4.3 0.25 2.7 0.25 6.7 0.25 2.5 0.25 5.8 0.25 3.00.3 4.3 0.3 2.7 0.3 6.7 0.3 2.5 0.3 5.8 0.3 3.0 0.35 4.3 0.35 2.7 0.356.7 0.35 2.5 0.35 5.8 0.35 3.0 0.4 4.3 0.4 2.7 0.4 6.7 0.4 2.5 0.4 5.80.4 3.0 0.45 4.3 0.45 2.7 0.45 6.7 0.45 2.5 0.45 5.7 0.45 3.0 0.5 4.30.5 2.7 0.5 6.7 0.5 2.5 0.5 5.7 0.5 3.0 0.55 4.2 0.55 2.7 0.55 6.6 0.552.5 0.55 5.7 0.55 3.0 0.6 4.2 0.6 2.7 0.6 6.6 0.6 2.5 0.6 5.6 0.6 3.00.65 4.2 0.65 2.7 0.65 6.6 0.65 2.5 0.65 5.5 0.65 3.0 0.7 4.2 0.7 2.70.7 6.5 0.7 2.5 0.7 5.3 0.7 3.0 0.75 4.0 0.75 2.7 0.75 6.3 0.75 2.5 0.755.1 0.75 3.0 0.8 3.8 0.8 2.6 0.8 6.0 0.8 2.4 0.8 4.7 0.8 2.8 0.85 3.50.85 2.4 0.85 5.5 0.85 2.2 0.85 4.3 0.85 2.6 0.9 3.0 0.9 2.1 0.9 4.7 0.92.0 0.9 3.6 0.9 2.3 0.95 2.2 0.95 1.7 0.95 3.3 0.95 1.7 0.95 2.6 0.951.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F245cb + 0.01 0.01F245cb + 0.96 0.01 F245cb + 0.01 0.01 F245cb + 0.01 0.01 F245cb + 0.010.2 F245cb + 0.2 F1243zf + F1243zf + 0.01 F1233zdE + F1243zf + 0.01F1233zdE + F1243zf + 0.96 F1233zdE + F1243zf + 0.01 F1233zdE + F1243zf +0.01 F1233zdE+ 0.2 F1233zdE 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE +0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96F1234zeE + 0.2 F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 3.8 0 4.6 0 5.8 0 1.5 0 4.80 1.9 0.05 4.9 0.05 5.8 0.05 6.7 0.05 2.6 0.05 5.8 0.05 3.0 0.1 4.9 0.15.8 0.1 6.7 0.1 2.6 0.1 5.8 0.1 3.0 0.15 4.9 0.15 5.8 0.15 6.7 0.15 2.60.15 5.8 0.15 3.0 0.2 4.9 0.2 5.8 0.2 6.7 0.2 2.6 0.2 5.8 0.2 3.0 0.254.9 0.25 5.8 0.25 6.7 0.25 2.6 0.25 5.8 0.25 3.0 0.3 4.9 0.3 5.8 0.3 6.70.3 2.6 0.3 5.8 0.3 3.0 0.35 4.9 0.35 5.8 0.35 6.7 0.35 2.6 0.35 5.80.35 3.0 0.4 4.9 0.4 5.8 0.4 6.7 0.4 2.6 0.4 5.8 0.4 3.0 0.45 4.9 0.455.8 0.45 6.7 0.45 2.6 0.45 5.8 0.45 3.0 0.5 4.9 0.5 5.8 0.5 6.7 0.5 2.60.5 5.7 0.5 3.0 0.55 4.9 0.55 5.8 0.55 6.7 0.55 2.6 0.55 5.7 0.55 3.00.6 4.9 0.6 5.8 0.6 6.6 0.6 2.6 0.6 5.6 0.6 3.0 0.65 4.9 0.65 5.8 0.656.6 0.65 2.6 0.65 5.5 0.65 3.0 0.7 4.9 0.7 5.8 0.7 6.5 0.7 2.6 0.7 5.40.7 3.0 0.75 4.8 0.75 5.8 0.75 6.3 0.75 2.5 0.75 5.1 0.75 3.0 0.8 4.50.8 5.8 0.8 6.0 0.8 2.4 0.8 4.8 0.8 2.9 0.85 4.2 0.85 5.8 0.85 5.6 0.852.3 0.85 4.3 0.85 2.7 0.9 3.5 0.9 5.0 0.9 4.7 0.9 2.0 0.9 3.6 0.9 2.40.95 2.6 0.95 3.5 0.95 3.4 0.95 1.7 0.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F1234yf + F1234yf + 0.01 F245cb + F1234yf + 0.01F245cb + F1234yf + 0.96 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.01F245cb + 0.2 F245cb 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.01F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96 F1234zeE + 0.2F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE TOTAL TOTAL TOTALTOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HFbar HF bar HF bar HF bar 0 3.9 0 1.7 0 6.7 0 4.6 0 4.8 0 1.5 0.05 5.00.05 2.8 0.05 7.6 0.05 5.8 0.05 5.8 0.05 2.6 0.1 5.0 0.1 2.8 0.1 7.6 0.15.8 0.1 5.8 0.1 2.6 0.15 5.0 0.15 2.8 0.15 7.6 0.15 5.8 0.15 5.8 0.152.6 0.2 5.0 0.2 2.8 0.2 7.6 0.2 5.8 0.2 5.8 0.2 2.6 0.25 5.0 0.25 2.80.25 7.6 0.25 5.8 0.25 5.8 0.25 2.6 0.3 5.0 0.3 2.8 0.3 7.6 0.3 5.8 0.35.8 0.3 2.6 0.35 5.0 0.35 2.8 0.35 7.6 0.35 5.8 0.35 5.8 0.35 2.6 0.45.0 0.4 2.8 0.4 7.6 0.4 5.8 0.4 5.8 0.4 2.6 0.45 5.0 0.45 2.8 0.45 7.60.45 5.8 0.45 5.8 0.45 2.6 0.5 5.0 0.5 2.8 0.5 7.6 0.5 5.8 0.5 5.7 0.52.6 0.55 5.0 0.55 2.8 0.55 7.6 0.55 5.8 0.55 5.7 0.55 2.6 0.6 5.0 0.62.8 0.6 7.6 0.6 5.8 0.6 5.6 0.6 2.6 0.65 5.0 0.65 2.8 0.65 7.6 0.65 5.80.65 5.5 0.65 2.6 0.7 5.1 0.7 2.8 0.7 7.6 0.7 5.8 0.7 5.4 0.7 2.6 0.755.0 0.75 2.8 0.75 7.5 0.75 5.8 0.75 5.1 0.75 2.6 0.8 4.7 0.8 2.6 0.8 7.10.8 5.8 0.8 4.8 0.8 2.4 0.85 4.3 0.85 2.5 0.85 6.5 0.85 5.8 0.85 4.30.85 2.3 0.9 3.7 0.9 2.2 0.9 5.5 0.9 5.0 0.9 3.6 0.9 2.0 0.95 2.7 0.951.8 0.95 3.8 0.95 3.5 0.95 2.6 0.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdEOrganics Organics Organics Organics Organics Organics 0.96 F1233xf +0.01 0.01 F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01F1233xf + 0.01 0.2 F1233xf + 0.2 F1234yf + F1234yf + 0.01 F245cb +F1234yf + 0.01 F245cb + F1234yf + 0.96 F245cb + F1234yf + 0.01 F245cb +F1234yf + 0.01 F245cb + 0.2 F245cb 0.2 0.01 F1234zeZ + 0.01 0.01F1234zeZ + 0.01 0.01 F1234zeZ + 0.01 0.96 F1234zeZ + 0.01 0.01F1234zeZ + 0.96 F1234zeZ + 0.2 F1233zdE F1233zdE F1233zdE F1233zdEF1233zdE F1233zdE TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar HF bar 0 3.3 0 1.60 6.6 0 4.6 0 1.9 0 1.4 0.05 4.4 0.05 2.8 0.05 7.6 0.05 5.8 0.05 3.00.05 2.5 0.1 4.4 0.1 2.8 0.1 7.6 0.1 5.8 0.1 3.0 0.1 2.5 0.15 4.4 0.152.8 0.15 7.6 0.15 5.8 0.15 3.0 0.15 2.5 0.2 4.4 0.2 2.8 0.2 7.6 0.2 5.80.2 3.0 0.2 2.5 0.25 4.4 0.25 2.8 0.25 7.6 0.25 5.8 0.25 3.0 0.25 2.50.3 4.4 0.3 2.8 0.3 7.6 0.3 5.8 0.3 3.0 0.3 2.5 0.35 4.4 0.35 2.8 0.357.6 0.35 5.8 0.35 3.0 0.35 2.5 0.4 4.4 0.4 2.8 0.4 7.6 0.4 5.8 0.4 3.00.4 2.5 0.45 4.4 0.45 2.8 0.45 7.6 0.45 5.8 0.45 3.0 0.45 2.5 0.5 4.40.5 2.8 0.5 7.6 0.5 5.8 0.5 3.0 0.5 2.5 0.55 4.4 0.55 2.8 0.55 7.6 0.555.8 0.55 3.0 0.55 2.5 0.6 4.4 0.6 2.8 0.6 7.6 0.6 5.8 0.6 3.0 0.6 2.50.65 4.5 0.65 2.8 0.65 7.6 0.65 5.8 0.65 3.0 0.65 2.5 0.7 4.5 0.7 2.80.7 7.6 0.7 5.8 0.7 3.0 0.7 2.5 0.75 4.5 0.75 2.8 0.75 7.4 0.75 5.8 0.753.0 0.75 2.5 0.8 4.3 0.8 2.6 0.8 7.1 0.8 5.8 0.8 2.9 0.8 2.4 0.85 4.00.85 2.4 0.85 6.5 0.85 5.8 0.85 2.7 0.85 2.3 0.9 3.4 0.9 2.2 0.9 5.5 0.95.0 0.9 2.3 0.9 2.0 0.95 2.5 0.95 1.7 0.95 3.8 0.95 3.5 0.95 1.9 0.951.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F1234yf + F1234yf + 0.01 F245cb + F1234yf + 0.01F245cb + F1234yf + 0.96 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.01F245cb + 0.2 F245cb 0.2 0.01 F1233zdE + 0.01 0.01 F1233zdE + 0.01 0.01F1233zdE + 0.01 0.96 F1233zdE + 0.01 0.01 F1233zdE + 0.96 F1233zdE + 0.2F1243zf F1243zf F1243zf F1243zf F1243zf F1243zf TOTAL TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HFbar HF bar HF bar HF bar 0 4.2 0 1.7 0 6.7 0 4.6 0 1.5 0 5.8 0.05 5.30.05 2.8 0.05 7.6 0.05 5.8 0.05 2.6 0.05 6.7 0.1 5.3 0.1 2.8 0.1 7.7 0.15.8 0.1 2.6 0.1 6.8 0.15 5.3 0.15 2.8 0.15 7.6 0.15 5.8 0.15 2.6 0.156.7 0.2 5.3 0.2 2.8 0.2 7.6 0.2 5.8 0.2 2.6 0.2 6.7 0.25 5.3 0.25 2.80.25 7.6 0.25 5.8 0.25 2.6 0.25 6.7 0.3 5.3 0.3 2.8 0.3 7.6 0.3 5.8 0.32.6 0.3 6.7 0.35 5.3 0.35 2.8 0.35 7.6 0.35 5.8 0.35 2.6 0.35 6.7 0.45.3 0.4 2.8 0.4 7.6 0.4 5.8 0.4 2.6 0.4 6.7 0.45 5.3 0.45 2.8 0.45 7.60.45 5.8 0.45 2.6 0.45 6.7 0.5 5.3 0.5 2.8 0.5 7.6 0.5 5.8 0.5 2.6 0.56.7 0.55 5.3 0.55 2.8 0.55 7.6 0.55 5.8 0.55 2.6 0.55 6.7 0.6 5.3 0.62.8 0.6 7.6 0.6 5.8 0.6 2.6 0.6 6.7 0.65 5.3 0.65 2.8 0.65 7.6 0.65 5.80.65 2.6 0.65 6.6 0.7 5.3 0.7 2.8 0.7 7.6 0.7 5.8 0.7 2.6 0.7 6.5 0.755.2 0.75 2.8 0.75 7.5 0.75 5.8 0.75 2.6 0.75 6.4 0.8 5.0 0.8 2.7 0.8 7.20.8 5.8 0.8 2.5 0.8 6.1 0.85 4.6 0.85 2.5 0.85 6.6 0.85 5.8 0.85 2.30.85 5.6 0.9 3.9 0.9 2.2 0.9 5.5 0.9 5.0 0.9 2.0 0.9 4.7 0.95 2.8 0.951.8 0.95 3.8 0.95 3.5 0.95 1.7 0.95 3.4 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 11.2 HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdEOrganics Organics Organics Organics Organics Organics 0.96 F1233xf +0.01 0.01 F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01F1233xf + 0.01 0.2 F1233xf + 0.2 F1234yf + F1234yf + 0.01 F1233zdE +F1234yf + 0.01 F1233zdE + F1234yf + 0.96 F1233zdE + F1234yf + 0.01F1233zdE + F1234yf + 0.01 F1333zdE + 0.2 F1233zdE 0.2 0.01 F1234zeE +0.01 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01F1234zeE + 0.96 F1234zeE + 0.2 F1234zeZ F1234zeZ F1234zeZ F1234zeZF1234zeZ F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar HF bar 0 3.4 0 1.60 6.6 0 1.4 0 4.8 0 1.9 0.05 4.4 0.05 2.8 0.05 7.6 0.05 2.5 0.05 5.80.05 3.0 0.1 4.4 0.1 2.8 0.1 7.6 0.1 2.5 0.1 5.8 0.1 3.0 0.15 4.4 0.152.8 0.15 7.6 0.15 2.5 0.15 5.8 0.15 3.0 0.2 4.4 0.2 2.8 0.2 7.6 0.2 2.50.2 5.8 0.2 3.0 0.25 4.4 0.25 2.8 0.25 7.6 0.25 2.5 0.25 5.8 0.25 3.00.3 4.4 0.3 2.8 0.3 7.6 0.3 2.5 0.3 5.8 0.3 3.0 0.35 4.4 0.35 2.8 0.357.6 0.35 2.5 0.35 5.8 0.35 3.0 0.4 4.4 0.4 2.8 0.4 7.6 0.4 2.5 0.4 5.80.4 3.0 0.45 4.4 0.45 2.7 0.45 7.6 0.45 2.5 0.45 5.7 0.45 3.0 0.5 4.40.5 2.7 0.5 7.6 0.5 2.5 0.5 5.7 0.5 3.0 0.55 4.4 0.55 2.7 0.55 7.6 0.552.5 0.55 5.7 0.55 3.0 0.6 4.4 0.6 2.7 0.6 7.6 0.6 2.5 0.6 5.6 0.6 3.00.65 4.4 0.65 2.7 0.65 7.6 0.65 2.5 0.65 5.5 0.65 3.0 0.7 4.4 0.7 2.70.7 7.6 0.7 2.5 0.7 5.3 0.7 3.0 0.75 4.2 0.75 2.7 0.75 7.4 0.75 2.5 0.755.1 0.75 3.0 0.8 4.0 0.8 2.6 0.8 7.1 0.8 2.4 0.8 4.8 0.8 2.8 0.85 3.60.85 2.4 0.85 6.5 0.85 2.2 0.85 4.3 0.85 2.6 0.9 3.1 0.9 2.1 0.9 5.5 0.92.0 0.9 3.6 0.9 2.3 0.95 2.3 0.95 1.7 0.95 3.8 0.95 1.7 0.95 2.6 0.951.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F1234yf + F1234yf + 0.01 F1243zf + F1234yf + 0.01F1243zf + F1234yf + 0.96 F1243zf + F1234yf + 0.01 F1243zf + F1234yf +0.01 F1243zf + 0.2 F1243zf + 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE +0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96F1234zeE + 0.2 F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 4.3 0 1.7 0 6.7 0 5.8 0 4.80 1.5 0.05 5.3 0.05 2.8 0.05 7.6 0.05 6.7 0.05 5.8 0.05 2.6 0.1 5.3 0.12.8 0.1 7.6 0.1 6.7 0.1 5.8 0.1 2.6 0.15 5.3 0.15 2.8 0.15 7.6 0.15 6.70.15 5.8 0.15 2.6 0.2 5.3 0.2 2.8 0.2 7.6 0.2 6.7 0.2 5.8 0.2 2.6 0.255.3 0.25 2.8 0.25 7.6 0.25 6.7 0.25 5.8 0.25 2.6 0.3 5.3 0.3 2.8 0.3 7.60.3 6.7 0.3 5.8 0.3 2.6 0.35 5.3 0.35 2.8 0.35 7.6 0.35 6.7 0.35 5.80.35 2.6 0.4 5.3 0.4 2.8 0.4 7.6 0.4 6.7 0.4 5.8 0.4 2.6 0.45 5.3 0.452.8 0.45 7.6 0.45 6.7 0.45 5.8 0.45 2.6 0.5 5.3 0.5 2.8 0.5 7.6 0.5 6.70.5 5.8 0.5 2.6 0.55 5.3 0.55 2.8 0.55 7.6 0.55 6.7 0.55 5.7 0.55 2.60.6 5.3 0.6 2.8 0.6 7.6 0.6 6.7 0.6 5.6 0.6 2.6 0.65 5.2 0.65 2.8 0.657.6 0.65 6.6 0.65 5.5 0.65 2.6 0.7 5.1 0.7 2.8 0.7 7.6 0.7 6.5 0.7 5.40.7 2.6 0.75 5.0 0.75 2.8 0.75 7.5 0.75 6.3 0.75 5.1 0.75 2.6 0.8 4.70.8 2.6 0.8 7.1 0.8 6.1 0.8 4.8 0.8 2.4 0.85 4.3 0.85 2.5 0.85 6.5 0.855.6 0.85 4.3 0.85 2.3 0.9 3.6 0.9 2.2 0.9 5.5 0.9 4.7 0.9 3.6 0.9 2.00.95 2.6 0.95 1.8 0.95 3.8 0.95 3.4 0.95 2.6 0.95 1.7 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1233xf + 0.01 0.01F1233xf + 0.96 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.2 F1233xf + 0.2 F1234yf + F1234yf + 0.01 F1243zf + F1234yf + 0.01F1243zf + F1234yf + 0.96 F1243zf + F1234yf + 0.01 F1243zf + F1234yf +0.01 F1243zf + 0.2 F1243zf + 0.2 0.01 F1234zeZ + 0.01 0.01 F1234zeZ +0.01 0.01 F1234zeZ + 0.01 0.96 F1234zeZ + 0.01 0.01 F1234zeZ + 0.96F1234zeZ + 0.2 F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 3.6 0 1.7 0 6.6 0 5.7 0 1.90 1.4 0.05 4.7 0.05 2.8 0.05 7.6 0.05 6.7 0.05 3.0 0.05 2.6 0.1 4.7 0.12.8 0.1 7.6 0.1 6.7 0.1 3.0 0.1 2.6 0.15 4.7 0.15 2.8 0.15 7.6 0.15 6.70.15 3.0 0.15 2.6 0.2 4.7 0.2 2.8 0.2 7.6 0.2 6.7 0.2 3.0 0.2 2.6 0.254.7 0.25 2.8 0.25 7.6 0.25 6.7 0.25 3.0 0.25 2.6 0.3 4.7 0.3 2.8 0.3 7.60.3 6.7 0.3 3.0 0.3 2.6 0.35 4.7 0.35 2.8 0.35 7.6 0.35 6.7 0.35 3.00.35 2.5 0.4 4.7 0.4 2.8 0.4 7.6 0.4 6.7 0.4 3.0 0.4 2.5 0.45 4.7 0.452.8 0.45 7.6 0.45 6.7 0.45 3.0 0.45 2.5 0.5 4.7 0.5 2.8 0.5 7.6 0.5 6.70.5 3.0 0.5 2.5 0.55 4.7 0.55 2.8 0.55 7.6 0.55 6.7 0.55 3.0 0.55 2.50.6 4.7 0.6 2.8 0.6 7.6 0.6 6.6 0.6 3.0 0.6 2.5 0.65 4.7 0.65 2.8 0.657.6 0.65 6.6 0.65 3.0 0.65 2.5 0.7 4.7 0.7 2.8 0.7 7.6 0.7 6.5 0.7 3.00.7 2.5 0.75 4.5 0.75 2.8 0.75 7.4 0.75 6.3 0.75 3.0 0.75 2.5 0.8 4.30.8 2.6 0.8 7.1 0.8 6.0 0.8 2.9 0.8 2.4 0.85 3.9 0.85 2.4 0.85 6.5 0.855.5 0.85 2.7 0.85 2.3 0.9 3.4 0.9 2.2 0.9 5.5 0.9 4.7 0.9 2.3 0.9 2.00.95 2.5 0.95 1.7 0.95 3.8 0.95 3.3 0.95 1.9 0.95 1.7 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE OrganicsOrganics Organics Organics Organics Organics 0.96 F1234yf + 0.01 0.01F1234yf + 0.96 0.01 F1234yf + 0.01 0.01 F1234yf + 0.01 0.01 F1234yf +0.01 0.2 F1234yf + 0.2 F245cb + F245cb + 0.01 F1233zdE + F245cb + 0.01F1233zdE + F245cb + 0.96 F1233zdE + F245cb + 0.01 F1233zdE + F245cb +0.01 F1233zdE + 0.2 F1233zdE + 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE +0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96F1234zeE + 0.2 F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 3.9 0 6.7 0 4.6 0 1.5 0 4.80 1.9 0.05 5.0 0.05 7.6 0.05 5.8 0.05 2.6 0.05 5.8 0.05 3.0 0.1 5.0 0.17.6 0.1 5.8 0.1 2.6 0.1 5.8 0.1 3.0 0.15 5.0 0.15 7.6 0.15 5.8 0.15 2.60.15 5.8 0.15 3.0 0.2 5.0 0.2 7.6 0.2 5.8 0.2 2.6 0.2 5.8 0.2 3.0 0.255.0 0.25 7.6 0.25 5.8 0.25 2.6 0.25 5.8 0.25 3.0 0.3 5.0 0.3 7.6 0.3 5.80.3 2.6 0.3 5.8 0.3 3.0 0.35 5.0 0.35 7.6 0.35 5.8 0.35 2.6 0.35 5.80.35 3.0 0.4 5.0 0.4 7.6 0.4 5.8 0.4 2.6 0.4 5.8 0.4 3.0 0.45 5.0 0.457.6 0.45 5.8 0.45 2.6 0.45 5.8 0.45 3.0 0.5 5.0 0.5 7.6 0.5 5.8 0.5 2.60.5 5.7 0.5 3.0 0.55 5.0 0.55 7.6 0.55 5.8 0.55 2.6 0.55 5.7 0.55 3.00.6 5.0 0.6 7.6 0.6 5.8 0.6 2.6 0.6 5.6 0.6 3.0 0.65 5.0 0.65 7.6 0.655.8 0.65 2.6 0.65 5.5 0.65 3.0 0.7 5.1 0.7 7.6 0.7 5.8 0.7 2.6 0.7 5.40.7 3.0 0.75 5.0 0.75 7.5 0.75 5.8 0.75 2.6 0.75 5.1 0.75 3.0 0.8 4.70.8 7.1 0.8 5.8 0.8 2.5 0.8 4.8 0.8 2.9 0.85 4.3 0.85 6.5 0.85 5.8 0.852.3 0.85 4.3 0.85 2.7 0.9 3.7 0.9 5.5 0.9 5.0 0.9 2.0 0.9 3.6 0.9 2.40.95 2.7 0.95 3.8 0.95 3.5 0.95 1.7 0.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1234yf + 0.01 0.01F1234yf + 0.96 0.01 F1234yf + 0.01 0.01 F1234yf + 0.01 0.01 F1234xf +0.01 0.2 F1234yf + 0.2 F245cb + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + F245cb + 0.96 F1243zf + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + 0.2 F1243zf + 0.2 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.010.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01 F1234zeE + 0.96F1234zeE + 0.2 F1233zdE F1233zdE F1233zdE F1234zdE F1233zdE F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 4.8 0 6.7 0 4.7 0 5.8 0 4.90 1.5 0.05 5.9 0.05 7.7 0.05 5.8 0.05 6.7 0.05 5.8 0.05 2.6 0.1 5.9 0.17.7 0.1 5.8 0.1 6.8 0.1 5.8 0.1 2.6 0.15 5.9 0.15 7.7 0.15 5.8 0.15 6.80.15 5.8 0.15 2.6 0.2 5.9 0.2 7.7 0.2 5.8 0.2 6.8 0.2 5.8 0.2 2.6 0.255.9 0.25 7.6 0.25 5.8 0.25 6.8 0.25 5.8 0.25 2.6 0.3 5.9 0.3 7.6 0.3 5.80.3 6.8 0.3 5.8 0.3 2.6 0.35 5.9 0.35 7.6 0.35 5.8 0.35 6.8 0.35 5.80.35 2.6 0.4 5.9 0.4 7.7 0.4 5.8 0.4 6.7 0.4 5.8 0.4 2.6 0.45 5.9 0.457.7 0.45 5.8 0.45 6.7 0.45 5.8 0.45 2.6 0.5 5.9 0.5 7.7 0.5 5.8 0.5 6.70.5 5.8 0.5 2.6 0.55 5.9 0.55 7.7 0.55 5.8 0.55 6.7 0.55 5.7 0.55 2.60.6 5.9 0.6 7.7 0.6 5.8 0.6 6.7 0.6 5.7 0.6 2.6 0.65 5.9 0.65 7.7 0.655.8 0.65 6.6 0.65 5.6 0.65 2.6 0.7 5.9 0.7 7.6 0.7 5.8 0.7 6.5 0.7 5.40.7 2.6 0.75 5.7 0.75 7.5 0.75 5.8 0.75 6.4 0.75 5.2 0.75 2.6 0.8 5.40.8 7.2 0.8 5.8 0.8 6.1 0.8 4.8 0.8 2.5 0.85 5.0 0.85 6.6 0.85 5.8 0.855.6 0.85 4.3 0.85 2.3 0.9 4.2 0.9 5.5 0.9 5.0 0.9 4.8 0.9 3.6 0.9 2.10.95 3.0 0.95 3.8 0.95 3.5 0.95 3.4 0.95 2.6 0.95 1.7 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1234yf + 0.01 0.01F1234yf + 0.96 0.01 F1234yf + 0.01 0.01 F1234yf + 0.01 0.01 F1234yf +0.01 0.2 F1234yf + 0.2 F245cb + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + F245cb + 0.96 F1243zf + F245cb + 0.01 F1243zf + F245cb + 0.01F1243zf + 0.2 F1243zf + 0.2 0.01 F1234zeZ + 0.01 0.01 F1234zeZ + 0.010.01 F1234zeZ + 0.01 0.96 F1234zeZ + 0.01 0.01 F1234zeZ + 0.96F1234zeZ + 0.2 F1233zdE F1233zdE F1233zdE F1233zdE F1233zdE F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREHF bar HF bar HF bar HF bar HF bar HF bar 0 4.2 0 6.7 0 4.6 0 5.8 0 1.90 1.5 0.05 5.3 0.05 7.6 0.05 5.8 0.05 6.7 0.05 3.0 0.05 2.6 0.1 5.3 0.17.6 0.1 5.8 0.1 6.7 0.1 3.0 0.1 2.6 0.15 5.3 0.15 7.6 0.15 5.8 0.15 6.70.15 3.0 0.15 2.6 0.2 5.3 0.2 7.6 0.2 5.8 0.2 6.7 0.2 3.0 0.2 2.6 0.255.3 0.25 7.6 0.25 5.8 0.25 6.7 0.25 3.0 0.25 2.6 0.3 5.3 0.3 7.6 0.3 5.80.3 6.7 0.3 3.0 0.3 2.6 0.35 5.3 0.35 7.6 0.35 5.8 0.35 6.7 0.35 3.00.35 2.6 0.4 5.3 0.4 7.6 0.4 5.8 0.4 6.7 0.4 3.0 0.4 2.6 0.45 5.3 0.457.6 0.45 5.8 0.45 6.7 0.45 3.0 0.45 2.6 0.5 5.3 0.5 7.6 0.5 5.8 0.5 6.70.5 3.0 0.5 2.6 0.55 5.3 0.55 7.6 0.55 5.8 0.55 6.7 0.55 3.0 0.55 2.60.6 5.3 0.6 7.6 0.6 5.8 0.6 6.7 0.6 3.0 0.6 2.6 0.65 5.3 0.65 7.6 0.655.8 0.65 6.6 0.65 3.0 0.65 2.6 0.7 5.3 0.7 7.6 0.7 5.8 0.7 6.5 0.7 3.00.7 2.6 0.75 5.2 0.75 7.5 0.75 5.8 0.75 6.4 0.75 3.0 0.75 2.6 0.8 5.00.8 7.2 0.8 5.8 0.8 6.1 0.8 2.9 0.8 2.5 0.85 4.6 0.85 6.6 0.85 5.8 0.855.6 0.85 2.7 0.85 2.3 0.9 3.9 0.9 5.5 0.9 5.0 0.9 4.7 0.9 2.4 0.9 2.00.95 2.9 0.95 3.8 0.95 3.5 0.95 3.4 0.95 1.9 0.95 1.7 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf OrganicsOrganics Organics Organics Organics Organics 0.96 F1234yf + 0.01 0.01F1234yf + 0.96 0.01 F1234yf + 0.01 0.01 F1234yf + 0.01 0.01 F1234yf +0.01 0.2 F1234yf + 0.2 F1243zf + F1243zf + 0.01 F1233zdE + F1243zf +0.01 F1233zdE + F1243zf + 0.96 F1233zdE + F1243zf + 0.01 F1233zdE +F1243xf + 0.01 F1233zdE + 0.2 F1233zdE 0.2 0.01 F1234zeE + 0.01 0.01F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.96 F1234zeE + 0.01 0.01F1234zeE + 0.96 F1234zeE + 0.2 F1234zeZ F1234zeZ F1234zeZ F1234zeZF1234zeZ F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.2 0 6.70 5.8 0 1.5 0 4.8 0 1.9 0.05 5.3 0.05 7.6 0.05 6.7 0.05 2.6 0.05 5.80.05 3.0 0.1 5.3 0.1 7.6 0.1 6.7 0.1 2.6 0.1 5.8 0.1 3.0 0.15 5.3 0.157.6 0.15 6.7 0.15 2.6 0.15 5.8 0.15 3.0 0.2 5.3 0.2 7.6 0.2 6.7 0.2 2.60.2 5.8 0.2 3.0 0.25 5.3 0.25 7.6 0.25 6.7 0.25 2.6 0.25 5.8 0.25 3.00.3 5.3 0.3 7.6 0.3 6.7 0.3 2.6 0.3 5.8 0.3 3.0 0.35 5.3 0.35 7.6 0.356.7 0.35 2.6 0.35 5.8 0.35 3.0 0.4 5.3 0.4 7.6 0.4 6.7 0.4 2.6 0.4 5.80.4 3.0 0.45 5.3 0.45 7.6 0.45 6.7 0.45 2.6 0.45 5.8 0.45 3.0 0.5 5.30.5 7.6 0.5 6.7 0.5 2.6 0.5 5.8 0.5 3.0 0.55 5.3 0.55 7.6 0.55 6.7 0.552.6 0.55 5.7 0.55 3.0 0.6 5.2 0.6 7.6 0.6 6.7 0.6 2.6 0.6 5.6 0.6 3.00.65 5.2 0.65 7.6 0.65 6.6 0.65 2.6 0.65 5.5 0.65 3.0 0.7 5.2 0.7 7.60.7 6.5 0.7 2.6 0.7 5.4 0.7 3.0 0.75 5.0 0.75 7.5 0.75 6.3 0.75 2.6 0.755.1 0.75 3.0 0.8 4.7 0.8 7.1 0.8 6.1 0.8 2.5 0.8 4.8 0.8 2.9 0.85 4.30.85 6.5 0.85 5.6 0.85 2.3 0.85 4.3 0.85 2.7 0.9 3.7 0.9 5.5 0.9 4.7 0.92.0 0.9 3.6 0.9 2.4 0.95 2.7 0.95 3.8 0.95 3.4 0.95 1.7 0.95 2.6 0.951.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 14 Temperature and Pressure Range of Systems with 6 Compounds

Boiling point range Temperature Pressure bar System with 6 compounds °C. abs HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE- 0 to 40 ~0.9 to ~9.0 HFO-1234zeZ-HCFO-1233zdE HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE- 0 to 40~0.9 to ~10.3 HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ- 0 to 40 ~1.0 to ~10.3HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ- 0 to 40~0.9 to ~10.3 HCFO-1233zdE-HFO-1243zfHF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ- 0 to 40 ~0.9 to ~10.3HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO- 0 to 40~0.9 to ~11.6 1234zeE-HCFO-1233zdEHF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO- 0 to 40 ~0.9 to ~11.51234zeZ-HCFO-1233zdE HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO- 0 to 40~0.9 to ~11.6 1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO- 0 to 40 ~0.9 to ~11.51234zeZ-HCFO-1233zdE HF-HFCO-1233xf-HFO-1234yf-HFO-1234zeE- 0 to 40 ~0.9to ~11.6 HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-0 to 40 ~0.9 to ~11.6 HCFO-1233zdE-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO- 0 to 40 ~0.9 to ~11.61234zeZ-HCFO-1233zdE HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO- 0 to 40~1.0 to ~11.7

HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO- 0 to 40 ~0.9 to ~11.61233zdE-HFO-1243zf HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO- 0 to 40~0.9 to ~11.6 1233zdE-HFO-1243zf

indicates data missing or illegible when filed

EXAMPLE 15 Decantation Range of Systems with 6 Compounds

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermSystem with 6 compounds

40° C. HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE- 5-75 5-70 10-65HFO-1234zeZ-HCFO-1233zdE HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE- 5-75 5-7015-50 HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ- 5-755-70 10-65 HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ- 5-75 5-65 10-55HCFO-1233zdE-HFO-1243zf HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ- 5-75 5-7015-50 HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-5-75 5-70 15-55 1234zeE-HCFO-1233zdEHF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO- 5-75 5-75 10-651234zeZ-HCFO-1233zdE HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO- 5-75 5-7015-55 1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO- 5-755-65 10-55 1234zeZ-HCFO-1233zdE HF-HFCO-1233xf-HFO-1234yf-HFO-1234zeE-5-70 10-75  * HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ- 5-75 5-70 10-55HCFO-1233zdE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO- 5-755-70 15-55 1234zeZ-HCFO-1233zdEHF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO- 5-75 10-65  *1233zdE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HCFO- 5-75 10-70 15-55 1233zdE-HFO-1243zf HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-5-70 10-65  *

indicates data missing or illegible when filed

EXAMPLE 16 Systems with Seven Compounds, Isotherm at 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1-243zfOrganics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.17 0.95 F1233xf + 0.01 0.01 F1233xf + 0.95 0.01 F1233xf +0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01F245cb + 0.17 F1233zdE + F245cb + 0.01 F1233zdE + F245cb + 0.01F1233zdE + F245cb + 0.95 F1233zdE + F245cb + 0.01 F1233zdE + F245cb +0.01 F1233zdE + F245cb + 0.01 F1233zdE + 0.17 F1234zeE + 0.17 0.01F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.95F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.95 F1234zeZ +0.17 F1243zf F1234zeZ + 0.01 F1243zf F1234zeZ + 0.01 F1243zf F1234zeZ +0.01 F1243zf F1234zeZ + 0.01 F1243zf F1234zeZ + 0.95 F1243zf F1234zeZ +0.01 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF barHF bar HF bar 0 3.5 0 1.7 0 4.6 0 1.5 0 4.8 0 5.7 0 1.9 0.05 4.6 0.052.8 0.05 5.7 0.05 2.6 0.05 5.7 0.05 6.7 0.05 3.0 0.1 4.6 0.1 2.8 0.1 5.70.1 2.6 0.1 5.8 0.1 6.7 0.1 3.0 0.15 4.6 0.15 2.8 0.15 5.7 0.15 2.6 0.155.8 0.15 6.7 0.15 3.0 0.2 4.6 0.2 2.8 0.2 5.7 0.2 2.6 0.2 5.8 0.2 6.70.2 3.0 0.25 4.6 0.25 2.8 0.25 5.8 0.25 2.6 0.25 5.8 0.25 6.7 0.25 3.00.3 4.6 0.3 2.8 0.3 5.8 0.3 2.6 0.3 5.8 0.3 6.7 0.3 3.0 0.35 4.6 0.352.8 0.35 5.8 0.35 2.6 0.35 5.8 0.35 6.7 0.35 3.0 0.4 4.6 0.4 2.8 0.4 5.80.4 2.6 0.4 5.8 0.4 6.7 0.4 3.0 0.45 4.6 0.45 2.8 0.45 5.8 0.45 2.6 0.455.7 0.45 6.7 0.45 3.0 0.5 4.6 0.5 2.8 0.5 5.8 0.5 2.6 0.5 5.7 0.5 6.70.5 3.0 0.55 4.6 0.55 2.8 0.55 5.8 0.55 2.6 0.55 5.7 0.55 6.6 0.55 3.00.6 4.6 0.6 2.8 0.6 5.8 0.6 2.6 0.6 5.6 0.6 6.6 0.6 3.0 0.65 4.6 0.652.8 0.65 5.8 0.65 2.6 0.65 5.5 0.65 6.6 0.65 3.0 0.7 4.6 0.7 2.8 0.7 5.80.7 2.6 0.7 5.3 0.7 6.5 0.7 3.0 0.75 4.5 0.75 2.8 0.75 5.8 0.75 2.6 0.755.1 0.75 6.3 0.75 3.0 0.8 4.2 0.8 2.6 0.8 5.8 0.8 2.4 0.8 4.8 0.8 6.00.8 2.9 0.85 3.9 0.85 2.4 0.85 5.8 0.85 2.3 0.85 4.3 0.85 5.5 0.85 2.70.9 3.3 0.9 2.2 0.9 4.9 0.9 2.0 0.9 3.6 0.9 4.7 0.9 2.4 0.95 2.5 0.951.8 0.95 3.5 0.95 1.7 0.95 2.6 0.95 3.3 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZOrganics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.17 0.01 F1233xf + 0.95 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.95 F1233xf + 0.01F1234yf + 0.17 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.95 F245cb +F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb +F1234yf + 0.01 F245cb + 0.17 F1233zdE + 0.17 0.01 F1233zdE + 0.01 0.01F1233zdE + 0.01 0.95 F1233zdE + 0.01 0.01 F1233zdE + 0.95 0.01F1233zdE + 0.01 0.01 F1233zdE + 0.01 F1234zeE + 0.17 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.95F1234zeE + 0.01 F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZF1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF barHF bar HF bar 0 3.6 0 6.6 0 4.6 0 1.5 0 4.8 0 1.9 0 1.7 0.05 4.7 0.057.6 0.05 5.8 0.05 2.6 0.05 5.8 0.05 3.0 0.05 2.8 0.1 4.7 0.1 7.6 0.1 5.80.1 2.6 0.1 5.8 0.1 3.0 0.1 2.8 0.15 4.7 0.15 7.6 0.15 5.8 0.15 2.6 0.155.8 0.15 3.0 0.15 2.8 0.2 4.7 0.2 7.6 0.2 5.8 0.2 2.6 0.2 5.8 0.2 3.00.2 2.8 0.25 4.7 0.25 7.6 0.25 5.8 0.25 2.6 0.25 5.8 0.25 3.0 0.25 2.80.3 4.7 0.3 7.6 0.3 5.8 0.3 2.6 0.3 5.8 0.3 3.0 0.3 2.8 0.35 4.7 0.357.6 0.35 5.8 0.35 2.6 0.35 5.8 0.35 3.0 0.35 2.8 0.4 4.7 0.4 7.6 0.4 5.80.4 2.6 0.4 5.8 0.4 3.0 0.4 2.8 0.45 4.7 0.45 7.6 0.45 5.8 0.45 2.6 0.455.7 0.45 3.0 0.45 2.8 0.5 4.7 0.5 7.6 0.5 5.8 0.5 2.6 0.5 5.7 0.5 3.00.5 2.8 0.55 4.7 0.55 7.6 0.55 5.8 0.55 2.6 0.55 5.7 0.55 3.0 0.55 2.80.6 4.7 0.6 7.6 0.6 5.8 0.6 2.6 0.6 5.6 0.6 3.0 0.6 2.8 0.65 4.7 0.657.6 0.65 5.8 0.65 2.6 0.65 5.5 0.65 3.0 0.65 2.8 0.7 4.7 0.7 7.6 0.7 5.80.7 2.6 0.7 5.3 0.7 3.0 0.7 2.8 0.75 4.6 0.75 7.4 0.75 5.8 0.75 2.6 0.755.1 0.75 3.0 0.75 2.8 0.8 4.4 0.8 7.1 0.8 5.8 0.8 2.5 0.8 4.8 0.8 2.90.8 2.6 0.85 4.1 0.85 6.5 0.85 5.8 0.85 2.3 0.85 4.3 0.85 2.7 0.85 2.50.9 3.5 0.9 5.5 0.9 5.0 0.9 2.0 0.9 3.6 0.9 2.4 0.9 2.2 0.95 2.5 0.953.8 0.95 3.5 0.95 1.7 0.95 2.6 0.95 1.9 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zfOrganics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.17 0.01 F1233xf + 0.95 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.95 F1233xf + 0.01F1234yf + 0.17 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.95 F245cb +F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb +F1234yf + 0.01 F245cb + 0.17 F1233zdE + 0.17 0.01 F1233zdE + 0.01 0.01F1233zdE + 0.01 0.95 F1233zdE + 0.01 0.01 F1233zdE + 0.95 0.01F1233zdE + 0.01 0.01 F1233zdE + 0.01 F1234zeE + 0.17 F1243zf F1234zeE +0.01 F1243zf F1234zeE + 0.01 F1243zf F1234zeE + 0.01 F1243zf F1234zeE +0.01 F1243zf F1234zeE + 0.95 F1243zf F1234zeE + 0.01 F1243zf TOTAL TOTALTOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar HF bar HF bar 0 4.40 6.6 0 4.6 0 1.5 0 4.8 0 5.8 0 1.7 0.05 5.4 0.05 7.6 0.05 5.8 0.05 2.60.05 5.8 0.05 6.7 0.05 2.8 0.1 5.4 0.1 7.6 0.1 5.8 0.1 2.6 0.1 5.8 0.16.7 0.1 2.8 0.15 5.4 0.15 7.6 0.15 5.8 0.15 2.6 0.15 5.8 0.15 6.7 0.152.8 0.2 5.4 0.2 7.6 0.2 5.8 0.2 2.6 0.2 5.8 0.2 6.7 0.2 2.8 0.25 5.40.25 7.6 0.25 5.8 0.25 2.6 0.25 5.8 0.25 6.7 0.25 2.8 0.3 5.4 0.3 7.60.3 5.8 0.3 2.6 0.3 5.8 0.3 6.7 0.3 2.8 0.35 5.4 0.35 7.6 0.35 5.8 0.352.6 0.35 5.8 0.35 6.7 0.35 2.8 0.4 5.4 0.4 7.6 0.4 5.8 0.4 2.6 0.4 5.80.4 6.7 0.4 2.8 0.45 5.4 0.45 7.6 0.45 5.8 0.45 2.6 0.45 5.8 0.45 6.70.45 2.8 0.5 5.4 0.5 7.6 0.5 5.8 0.5 2.6 0.5 5.8 0.5 6.7 0.5 2.8 0.555.4 0.55 7.6 0.55 5.8 0.55 2.6 0.55 5.7 0.55 6.7 0.55 2.8 0.6 5.4 0.67.6 0.6 5.8 0.6 2.6 0.6 5.6 0.6 6.7 0.6 2.8 0.65 5.4 0.65 7.6 0.65 5.80.65 2.6 0.65 5.5 0.65 6.6 0.65 2.8 0.7 5.4 0.7 7.6 0.7 5.8 0.7 2.6 0.75.4 0.7 6.5 0.7 2.8 0.75 5.3 0.75 7.4 0.75 5.8 0.75 2.6 0.75 5.1 0.756.3 0.75 2.8 0.8 5.0 0.8 7.1 0.8 5.8 0.8 2.5 0.8 4.8 0.8 6.1 0.8 2.70.85 4.6 0.85 6.5 0.85 5.8 0.85 2.3 0.85 4.3 0.85 5.6 0.85 2.5 0.9 3.90.9 5.5 0.9 5.0 0.9 2.1 0.9 3.6 0.9 4.7 0.9 2.2 0.95 2.8 0.95 3.8 0.953.5 0.95 1.7 0.95 2.6 0.95 3.4 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 11.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1234zfOrganics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.17 0.01 F1233xf + 0.95 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.95 F1233xf + 0.01F1234yf + 0.17 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.95 F245cb +F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb +F1234yf + 0.01 F245cb + 0.17 F1243zf + 0.17 0.01 F1243zf + 0.01 0.01F1243zf + 0.01 0.95 F1243zf + 0.01 0.01 F1243zf + 0.95 0.01 F1243zf +0.01 0.01 F1243zf + 0.01 F1233zdE + 0.17 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.95 F1233zdE + 0.01 F1234zeZF1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ TOTAL TOTAL TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRACPRESSURE HF bar HF bar HF bar HF bar HF bar HF bar HF bar 0 3.8 0 6.6 04.6 0 5.7 0 1.5 0 1.9 0 1.7 0.05 4.9 0.05 7.6 0.05 5.8 0.05 6.7 0.05 2.60.05 3.0 0.05 2.8 0.1 4.9 0.1 7.6 0.1 5.8 0.1 6.7 0.1 2.6 0.1 3.0 0.12.8 0.15 4.9 0.15 7.6 0.15 5.8 0.15 6.7 0.15 2.6 0.15 3.0 0.15 2.8 0.24.9 0.2 7.6 0.2 5.8 0.2 6.7 0.2 2.6 0.2 3.0 0.2 2.8 0.25 4.9 0.25 7.60.25 5.8 0.25 6.7 0.25 2.6 0.25 3.0 0.25 2.8 0.3 4.9 0.3 7.6 0.3 5.8 0.36.7 0.3 2.6 0.3 3.0 0.3 2.8 0.35 4.9 0.35 7.6 0.35 5.8 0.35 6.7 0.35 2.60.35 3.0 0.35 2.8 0.4 4.9 0.4 7.6 0.4 5.8 0.4 6.7 0.4 2.6 0.4 3.0 0.42.8 0.45 4.9 0.45 7.6 0.45 5.8 0.45 6.7 0.45 2.6 0.45 3.0 0.45 2.8 0.54.9 0.5 7.6 0.5 5.8 0.5 6.7 0.5 2.6 0.5 3.0 0.5 2.8 0.55 4.9 0.55 7.60.55 5.8 0.55 6.7 0.55 2.6 0.55 3.0 0.55 2.8 0.6 4.9 0.6 7.6 0.6 5.8 0.66.6 0.6 2.6 0.6 3.0 0.6 2.8 0.65 4.9 0.65 7.6 0.65 5.8 0.65 6.6 0.65 2.60.65 3.0 0.65 2.8 0.7 4.9 0.7 7.6 0.7 5.8 0.7 6.5 0.7 2.6 0.7 3.0 0.72.8 0.75 4.9 0.75 7.4 0.75 5.8 0.75 6.3 0.75 2.6 0.75 3.0 0.75 2.8 0.84.7 0.8 7.1 0.8 5.8 0.8 6.0 0.8 2.5 0.8 2.9 0.8 2.7 0.85 4.3 0.85 6.50.85 5.8 0.85 5.5 0.85 2.3 0.85 2.7 0.85 2.5 0.9 3.7 0.9 5.5 0.9 5.0 0.94.7 0.9 2.0 0.9 2.4 0.9 2.2 0.95 2.7 0.95 3.8 0.95 3.5 0.95 3.3 0.95 1.70.95 1.9 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zfOrganics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.17 0.01 F1233xf + 0.95 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.95 F1233xf + 0.01F1234yf + 0.17 F1233zdE + F1234yf + 0.01 F1233zdE + F1234yf + 0.95F1233zdE + F1234yf + 0.01 F1233zdE + F1234yf + 0.01 F1233zdE + F1234yf +0.01 F1233zdE + F1234yf + 0.01 F1233zdE + 0.17 F1243zf + 0.17 0.01F1243zf + 0.01 0.01 F1243zf + 0.01 0.95 F1243zf + 0.01 0.01 F1243zf +0.95 0.01 F1243zf + 0.01 0.01 F1243zf + 0.01 F1234zeE + 0.17 F1234zeE +0.01 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.95F1234zeE + 0.01 F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZ F1234zeZF1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF barHF bar HF bar 0 3.9 0 6.6 0 1.5 0 5.7 0 4.8 0 1.9 0 1.7 0.05 5.0 0.057.6 0.05 2.6 0.05 6.7 0.05 5.8 0.05 3.0 0.05 2.8 0.1 4.9 0.1 7.6 0.1 2.60.1 6.7 0.1 5.8 0.1 3.0 0.1 2.8 0.15 4.9 0.15 7.6 0.15 2.6 0.15 6.7 0.155.8 0.15 3.0 0.15 2.8 0.2 4.9 0.2 7.6 0.2 2.6 0.2 6.7 0.2 5.8 0.2 3.00.2 2.8 0.25 4.9 0.25 7.6 0.25 2.6 0.25 6.7 0.25 5.8 0.25 3.0 0.25 2.80.3 4.9 0.3 7.6 0.3 2.6 0.3 6.7 0.3 5.8 0.3 3.0 0.3 2.8 0.35 4.9 0.357.6 0.35 2.6 0.35 6.7 0.35 5.8 0.35 3.0 0.35 2.8 0.4 4.9 0.4 7.6 0.4 2.60.4 6.7 0.4 5.8 0.4 3.0 0.4 2.8 0.45 4.9 0.45 7.6 0.45 2.6 0.45 6.7 0.455.8 0.45 3.0 0.45 2.8 0.5 4.9 0.5 7.6 0.5 2.6 0.5 6.7 0.5 5.7 0.5 3.00.5 2.8 0.55 4.9 0.55 7.6 0.55 2.6 0.55 6.7 0.55 5.7 0.55 3.0 0.55 2.80.6 4.9 0.6 7.6 0.6 2.6 0.6 6.6 0.6 5.6 0.6 3.0 0.6 2.8 0.65 4.9 0.657.6 0.65 2.6 0.65 6.6 0.65 5.5 0.65 3.0 0.65 2.8 0.7 4.8 0.7 7.6 0.7 2.60.7 6.5 0.7 5.3 0.7 3.0 0.7 2.8 0.75 4.7 0.75 7.4 0.75 2.6 0.75 6.3 0.755.1 0.75 3.0 0.75 2.8 0.8 4.4 0.8 7.1 0.8 2.5 0.8 6.0 0.8 4.8 0.8 2.90.8 2.6 0.85 4.0 0.85 6.5 0.85 2.3 0.85 5.5 0.85 4.3 0.85 2.7 0.85 2.50.9 3.4 0.9 5.5 0.9 2.0 0.9 4.7 0.9 3.6 0.9 2.4 0.9 2.2 0.95 2.5 0.953.8 0.95 1.7 0.95 3.3 0.95 2.6 0.95 1.9 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zfOrganics Organics Organics Organics Organics Organics Organics 0.15F1234yf + 0.17 0.95 F1234yf + 0.01 0.01 F1234yf + 0.95 0.01 F1234yf +0.01 0.01 F1234yf + 0.01 0.01 F1234yf + 0.01 0.01 F1234yf + 0.01F245cb + 0.17 F1233zdE + F245cb + 0.01 F1233zdE + F245cb + 0.01F1233zdE + F245cb + 0.95 F1233zdE + F245cb + 0.01 F1233zdE + F245cb +0.01 F1233zdE + F245cb + 0.01 F1233zdE + 0.17 F1234zeE + 0.17 0.01F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.95F1234zeE + 0.01 0.01 F1234zeE + 0.01 0.01 F1234zeE + 0.95 F1234zeZ +0.17 F1243zf F1234zeZ + 0.01 F1243zf F1234zeZ + 0.01 F1243zf F1234zeZ +0.01 F1243zf F1234zeZ + 0.01 F1243zf F1234zeZ + 0.95 F1243zf F1234zeZ +0.01 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF barHF bar HF bar 0 4.3 0 6.6 0 4.6 0 1.5 0 4.8 0 5.8 0 2.0 0.05 5.3 0.057.6 0.05 5.8 0.05 2.6 0.05 5.8 0.05 6.7 0.05 3.1 0.1 5.3 0.1 7.6 0.1 5.80.1 2.6 0.1 5.8 0.1 6.7 0.1 3.1 0.15 5.3 0.15 7.6 0.15 5.8 0.15 2.6 0.155.8 0.15 6.7 0.15 3.1 0.2 5.3 0.2 7.6 0.2 5.8 0.2 2.6 0.2 5.8 0.2 6.70.2 3.1 0.25 5.3 0.25 7.6 0.25 5.8 0.25 2.6 0.25 5.8 0.25 6.7 0.25 3.10.3 5.3 0.3 7.6 0.3 5.8 0.3 2.6 0.3 5.8 0.3 6.7 0.3 3.1 0.35 5.3 0.357.6 0.35 5.8 0.35 2.6 0.35 5.8 0.35 6.7 0.35 3.1 0.4 5.3 0.4 7.6 0.4 5.80.4 2.6 0.4 5.8 0.4 6.7 0.4 3.1 0.45 5.3 0.45 7.6 0.45 5.8 0.45 2.6 0.455.8 0.45 6.7 0.45 3.1 0.5 5.3 0.5 7.6 0.5 5.8 0.5 2.6 0.5 5.8 0.5 6.70.5 3.1 0.55 5.3 0.55 7.6 0.55 5.8 0.55 2.6 0.55 5.7 0.55 6.7 0.55 3.10.6 5.3 0.6 7.6 0.6 5.8 0.6 2.6 0.6 5.6 0.6 6.7 0.6 3.1 0.65 5.3 0.657.6 0.65 5.8 0.65 2.6 0.65 5.5 0.65 6.6 0.65 3.1 0.7 5.3 0.7 7.6 0.7 5.80.7 2.6 0.7 5.4 0.7 6.5 0.7 3.1 0.75 5.2 0.75 7.4 0.75 5.8 0.75 2.6 0.755.1 0.75 6.3 0.75 3.1 0.8 4.9 0.8 7.1 0.8 5.8 0.8 2.5 0.8 4.8 0.8 6.10.8 2.9 0.85 4.5 0.85 6.5 0.85 5.8 0.85 2.3 0.85 4.3 0.85 5.6 0.85 2.70.9 3.9 0.9 5.5 0.9 5.0 0.9 2.1 0.9 3.6 0.9 4.7 0.9 2.4 0.95 2.8 0.953.8 0.95 3.5 0.95 1.7 0.95 2.6 0.95 3.4 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.21 1.2 1 1.2 1 1.2HF-HCFC-1233zdE-HCFC-244bb-HFC-245fa-Trifluoropropyne-HFO-1225yeZ-HFO-1225zcOrganics 0.15 Organics 0.95 Organics 0.01 Organics 0.01 Organics 0.01Organics 0.01 Organics F1233zdE + F1233zdE + F1233zdE + F1233zdE +F1233zdE + F1233zdE + 0.01F1233zdE + 0.17 F244bb + 0.01 F244bb + 0.95F244bb + 0.01 F244bb + 0.01 F244bb + 0.01 F244bb + 0.01 F244bb + 0.17F245fa + 0.01 F245fa + 0.01 F245fa + 0.95 F245fa + 0.01 F245fa + 0.01F245fa + 0.01 F245fa + 0.17TFP + 0.17 0.01 TFP + 0.01 0.01 TFP + 0.010.01 TFP + 0.01 0.95 TFP + 0.01 0.01 TFP + 0.95 0.01 TFP + 0.01F1225yeZ + F1225yeZ + F1225yeZ + F1225yeZ + F1225yeZ + F1225yeZ +F1225yeZ + 0.17 F1225zc 0.01 F1225zc 0.01 F1225zc 0.01 F1225zc 0.01F1225zc 0.01 F1225zc 0.95 F1225zc TOTAL TOTAL TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRES PRES PRES PRES PRES PRES PRES HF bar bar bar bar barbar bar 0 4.8 1.5 0.9 1.7 11.3 5.1 5.3 0.05 5.9 2.6 2.1 2.8 12.1 6.2 6.20.1 5.9 2.6 2.1 2.8 12.0 6.2 6.3 0.15 5.8 2.6 2.1 2.8 11.9 6.2 6.3 0.25.8 2.6 2.1 2.8 11.8 6.2 6.3 0.25 5.8 2.6 2.1 2.8 11.7 6.2 6.2 0.3 5.82.6 2.1 2.8 11.6 6.2 6.2 0.35 5.8 2.6 2.1 2.8 11.5 6.2 6.2 0.4 5.8 2.62.1 2.8 11.5 6.2 6.2 0.45 5.8 2.6 2.0 2.8 11.4 6.2 6.2 0.5 5.7 2.6 2.02.8 11.5 6.2 6.2 0.55 5.7 2.6 2.0 2.8 11.5 6.2 6.2 0.6 5.7 2.6 2.0 2.811.5 6.2 6.1 0.65 5.6 2.6 2.0 2.8 11.5 6.2 6.0 0.7 5.6 2.6 2.0 2.8 11.56.1 5.8 0.75 5.4 2.6 2.0 2.8 11.6 5.9 5.6 0.8 5.1 2.5 2.0 2.7 11.3 5.65.2 0.85 4.7 2.3 2.0 2.5 10.5 5.0 4.6 0.9 3.9 2.1 1.8 2.2 8.9 4.2 3.80.95 2.8 1.7 1.6 1.8 6.0 3.0 2.7 1 1.2 1.2 1.2 1.2 1.2 1.2 1.2

EXAMPLE 17 Temperature and Pressure Range of Systems with 7 Compounds

Boiling point range Temperature Pressure System with 7 compounds ° C.bar abs HC-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40 ~0.9 to ~10.31234zeE-HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-0 to 40 ~0.9 to ~11.5 1233zdE-HFO-1234zeE-HFO-1234zeZHF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO- 0 to 40 ~1.0 to ~11.61233zdE-HFO-1234zeE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-0 to 40 ~0.9 to ~11.5 1233zdE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO- 0 to 40 ~0.9 to ~11.51234zeE-HFO-1234zeZ-HFO-1243zfHF-HFO-1234yf-HFC-245b-HCFO-1233zdE-HFO-1234zeE- 0 to 40 ~1.0 to ~11.6HFO-1234zeZ-HFO-1243zf HF-HCFC-1233zdE-HCFC-244bb-HFC-245fa- 0 to 40~0.7 to ~17.5 Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

EXAMPLE 18 Decantation Range of Systems with 7 Compounds

Decantation ranges Mass percentage of HF Temperature System with 7compounds 0° C. 25° C. 40° C. HC-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-5-75 5-70 10-55 1234zeE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO- 5-75 5-70 10-601233zdE-HFO-1234zeE-HFO-1234zeZHF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO- 5-75 10-65  201233zdE-HFO-1234zeE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-5-70 5-70 10-60 1233zdE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO- 5-75 10-65  15-451234zeE-HFO-1234zeZ-HFO-1243zf HF-HFO-1234yf-HFC-245b-HCFO-1233zdE-HFO-5-75 10-65  * 1234zeE-HFO-1234zeZ-HFO-1243zfHF-HCFC-1233zdE-HCFC-244bb-HFC-245fa- 5-75 5-70 10-60Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

EXAMPLE 19 Systems with 8 Compounds

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf Organics Organics Organics Organics OrganicsOrganics Organics 0.01 F1233xf + 0.94 0.01 F1233xf + 0.01 0.01 F1233xf +0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.01 F1233xf + 0.01 0.16F1233xf + 0.14 F1234yf + 0.01 F245cb + F1234yf + 0.94 F245cb + F1234yf +0.01 F245cb + F1234yf + 0.01 F245cb + F1234yf + 0.01 F245cb + F1234yf +0.01 F245cb + F1234yf + 0.14 F245cb + 0.01 F1233zdE + 0.01 0.01F1233zdE + 0.01 0.94 F1334zdE + 0.01 0.01 F1233zdE + 0.94 0.01F1233zdE + 0.01 .01 F1233zdE + 0.01 0.14 F1233zdE + 0.14 F1234zeE +F1234zeE + F1234zeE + F1234zeE + F1234zeE + F1234zeE + F1234zeE + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01 0.94 0.01 F1234zeZ +0.14 F1234zeZ + 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf F1234zeZ + 0.01F1243zf F1234zeZ + 0.01 F1243zf 0.94 F1243zf 0.14 F1243zf TOTAL TOTALTOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSURE MASSFRAC PRESSUREMASSFRAC PRESSURE HF bar HF bar HF bar HF bar HF bar HF bar HF bar 0 6.60 4.6 0 1.5 0 4.8 0 2.0 0 5.7 0 3.9 0.05 7.6 0.05 5.8 0.05 2.6 0.05 5.80.05 3.1 0.05 6.7 0.05 5.0 0.1 7.6 0.1 5.8 0.1 2.6 0.1 5.8 0.1 3.1 0.16.7 0.1 5.0 0.15 7.6 0.15 5.8 0.15 2.6 0.15 5.8 0.15 3.1 0.15 6.7 0.155.0 0.2 7.6 0.2 5.8 0.2 2.6 0.2 5.8 0.2 3.1 0.2 6.7 0.2 5.0 0.25 7.60.25 5.8 0.25 2.6 0.25 5.8 0.25 3.1 0.25 6.7 0.25 5.0 0.3 7.6 0.3 5.80.3 2.6 0.3 5.8 0.3 3.1 0.3 6.7 0.3 5.0 0.35 7.6 0.35 5.8 0.35 2.6 0.355.8 0.35 3.1 0.35 6.7 0.35 5.0 0.4 7.6 0.4 5.8 0.4 2.6 0.4 5.8 0.4 3.10.4 6.7 0.4 5.0 0.45 7.6 0.45 5.8 0.45 2.6 0.45 5.8 0.45 3.1 0.45 6.70.45 5.0 0.5 7.6 0.5 5.8 0.5 2.6 0.5 5.7 0.5 3.1 0.5 6.7 0.5 5.0 0.557.6 0.55 5.8 0.55 2.6 0.55 5.7 0.55 3.1 0.55 6.7 0.55 5.0 0.6 7.6 0.65.8 0.6 2.6 0.6 5.6 0.6 3.1 0.6 6.6 0.6 5.0 0.65 7.6 0.65 5.8 0.65 2.60.65 5.5 0.65 3.1 0.65 6.6 0.65 5.0 0.7 7.5 0.7 5.8 0.7 2.6 0.7 5.4 0.73.1 0.7 6.5 0.7 5.0 0.75 7.4 0.75 5.8 0.75 2.6 0.75 5.1 0.75 3.1 0.756.3 0.75 4.9 0.8 7.1 0.8 5.8 0.8 2.5 0.8 4.8 0.8 2.9 0.8 6.0 0.8 4.60.85 6.5 0.85 5.8 0.85 2.3 0.85 4.3 0.85 2.7 0.85 5.5 0.85 4.2 0.9 5.50.9 5.0 0.9 2.1 0.9 3.6 0.9 2.4 0.9 4.7 0.9 3.6 0.95 3.8 0.95 3.5 0.951.7 0.95 2.6 0.95 1.9 0.95 3.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 11.2 1 1.2HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HCFC-244bb Organics Organics Organics Organics Organics OrganicsOrganics Organics 0.94 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.16 F1233xf +0.01 F1234yf + 0.94 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.14 F1234yf + 0.01 F245cb +0.01 F245cb + 0.94 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.14 F245cb + 0.01 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.94 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.14 F1233zdE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.94 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.14 F1234zeE + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.94 F1234zeZ + 0.01F1234zeZ + 0.14 F1234zeZ + 0.01 F244bb 0.01 F244bb 0.01 F244bb 0.01F244bb 0.01 F244bb 0.01 F244bb 0.94 F244bb 0.14 F244bb TOTAL TOTAL TOTALTOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE PRESSURE PRESSUREPRESSURE PRESSURE PRESSURE PRESSURE PRESSURE HF bar bar bar bar bar barbar bar 0 1.7 6.6 4.5 1.5 4.8 1.9 0.8 3.2 0.05 2.8 7.5 5.7 2.6 5.7 3.02.0 4.3 0.1 2.8 7.5 5.7 2.6 5.7 3.0 2.0 4.3 0.15 2.8 7.5 5.7 2.6 5.7 3.02.0 4.3 0.2 2.8 7.5 5.7 2.6 5.7 3.0 2.0 4.3 0.25 2.8 7.5 5.7 2.6 5.7 3.02.0 4.3 0.3 2.8 7.5 5.7 2.6 5.7 3.0 2.0 4.3 0.35 2.8 7.5 5.7 2.6 5.7 3.02.0 4.3 0.4 2.8 7.5 5.7 2.6 5.7 3.0 2.0 4.3 0.45 2.8 7.5 5.7 2.6 5.7 3.02.0 4.3 0.5 2.8 7.5 5.7 2.6 5.7 3.0 2.0 4.3 0.55 2.8 7.5 5.7 2.6 5.6 3.02.0 4.2 0.6 2.8 7.5 5.7 2.6 5.6 3.0 2.0 4.2 0.65 2.8 7.5 5.7 2.6 5.5 3.02.0 4.2 0.7 2.8 7.5 5.7 2.6 5.3 3.0 2.0 4.2 0.75 2.8 7.4 5.7 2.6 5.1 3.01.9 4.2 0.8 2.6 7.0 5.7 2.4 4.7 2.9 1.9 4.0 0.85 2.4 6.5 5.7 2.3 4.3 2.71.9 3.7 0.9 2.2 5.4 4.9 2.0 3.6 2.4 1.8 3.2 0.95 1.8 3.8 3.5 1.7 2.6 1.91.6 2.4 1 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-Trifluoropropyne Organics Organics Organics Organics OrganicsOrganics Organics Organics 0.16 F1234yf + 0.94 F1234yf + 0.01 F1234yf +0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.14 F245cb + 0.01 F245cb + 0.94 F245cb + 0.01 F245cb + 0.01F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.14 F1233xf + 0.01F1233xf + 0.01 F1233xf + 0.94 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.01 F1233xf + 0.14 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.94 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.14 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.94 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.14 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.94F1233zdE + 0.01 F1233zdE + 0.14 TPF 0.01 TPF 0.01 TPF 0.01 TPF 0.01 TPF0.01 TPF 0.01 TPF 0.94 TPF TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTALTOTAL MASSFRAC PRESSURE PRESSURE PRESSURE PRESSURE PRESSURE PRESSUREPRESSURE PRESSURE HF bar bar bar bar bar bar bar bar 0 5.0 6.7 4.7 1.84.9 2.0 1.6 11.2 0.05 6.0 7.6 5.8 2.9 5.8 3.1 2.7 12.0 0.1 6.0 7.6 5.82.9 5.9 3.1 2.7 11.9 0.15 6.0 7.6 5.8 2.9 5.9 3.1 2.7 11.8 0.2 6.0 7.65.8 2.9 5.9 3.1 2.7 11.7 0.25 6.0 7.6 5.8 2.9 5.8 3.1 2.7 11.6 0.3 6.07.6 5.8 2.9 5.8 3.1 2.7 11.5 0.35 6.0 7.6 5.8 2.9 5.8 3.1 2.7 11.5 0.46.0 7.6 5.8 2.9 5.8 3.1 2.7 11.4 0.45 6.0 7.6 5.8 2.9 5.8 3.1 2.7 11.40.5 6.0 7.6 5.8 2.9 5.8 3.1 2.7 11.4 0.55 6.0 7.6 5.8 2.9 5.8 3.1 2.711.5 0.6 6.0 7.6 5.8 2.9 5.7 3.1 2.7 11.5 0.65 6.0 7.6 5.8 2.9 5.6 3.12.7 11.5 0.7 6.0 7.6 5.8 2.9 5.4 3.1 2.7 11.5 0.75 5.9 7.5 5.8 2.9 5.23.1 2.7 11.5 0.8 5.6 7.1 5.8 2.8 4.9 3.0 2.6 11.2 0.85 5.1 6.6 5.8 2.64.4 2.8 2.4 10.4 0.9 4.3 5.5 5.0 2.2 3.6 2.4 2.1 8.8 0.95 3.1 3.8 3.51.8 2.6 1.9 1.7 5.9 1 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFC-245fa Organics Organics Organics Organics Organics OrganicsOrganics Organics 0.16 F1234yf + 0.94 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.14 F245cb + 0.01 F245cb + 0.94 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.14 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.94 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01F1233xf + 0.01 F1233xf + 0.14 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE +0.01 F1234zeE + 0.94 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.14 F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.94 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.14 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.94 F1233zdE + 0.01F1233zdE + 0.14 F245fa 0.01 F245fa 0.01 F245fa 0.01 F245fa 0.01 F245fa0.01 F245fa 0.01 F245fa 0.94 F245fa TOTAL TOTAL TOTAL TOTAL TOTAL TOTALTOTAL TOTAL MASSFRAC PRESSURE PRESSURE PRESSURE PRESSURE PRESSUREPRESSURE PRESSURE PRESSURE HF bar bar bar bar bar bar bar bar 0 3.4 6.64.5 1.7 4.8 1.9 1.5 1.6 0.05 4.5 7.5 5.7 2.8 5.7 3.0 2.6 2.8 0.1 4.5 7.55.7 2.8 5.7 3.0 2.6 2.8 0.15 4.5 7.5 5.7 2.8 5.7 3.0 2.6 2.8 0.2 4.5 7.55.7 2.8 5.7 3.0 2.6 2.8 0.25 4.5 7.5 5.7 2.8 5.7 3.0 2.6 2.8 0.3 4.5 7.55.7 2.8 5.7 3.0 2.6 2.8 0.35 4.5 7.5 5.7 2.8 5.7 3.0 2.6 2.8 0.4 4.5 7.55.7 2.8 5.7 3.0 2.6 2.8 0.45 4.5 7.5 5.7 2.8 5.7 3.0 2.6 2.8 0.5 4.5 7.55.7 2.8 5.7 3.0 2.6 2.8 0.55 4.5 7.5 5.7 2.8 5.6 3.0 2.6 2.8 0.6 4.5 7.55.7 2.8 5.6 3.0 2.6 2.8 0.65 4.5 7.5 5.7 2.8 5.5 3.0 2.6 2.8 0.7 4.5 7.55.7 2.8 5.3 3.0 2.6 2.8 0.75 4.4 7.4 5.7 2.8 5.1 3.0 2.6 2.8 0.8 4.2 7.15.8 2.6 4.7 2.9 2.5 2.7 0.85 3.9 6.5 5.7 2.5 4.3 2.7 2.3 2.5 0.9 3.3 5.44.9 2.2 3.6 2.4 2.0 2.2 0.95 2.4 3.8 3.5 1.8 2.6 1.9 1.7 1.8 1 1.2 1.21.2 1.2 1.2 1.2 1.2 1.2HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1225yeZ Organics Organics Organics Organics OrganicsOrganics Organics Organics 0.16 F1234yf + 0.94 F1234yf + 0.01 F1234yf +0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.14 F245cb + 0.01 F245cb + 0.94 F245cb + 0.01 F245cb + 0.01F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.14 F1233xf + 0.01F1233xf + 0.01 F1233xf + 0.94 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.01 F1233xf + 0.14 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.94 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.14 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.94 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.14 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.94F1233zdE + 0.01 F1233zdE + 0.14 F1225yeZ 0.01 F1225yeZ 0.01 F1225yeZ0.01 F1225yeZ 0.01 F1225yeZ 0.01 F1225yeZ 0.01 F1225yeZ 0.94 F1225yeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSUREPRESSURE PRESSURE PRESSURE PRESSURE PRESSURE PRESSURE PRESSURE HF barbar bar bar bar bar bar bar 0 3.8 6.6 4.6 1.7 4.8 1.9 1.5 5.1 0.05 4.97.6 5.8 2.8 5.8 3.0 2.6 6.1 0.1 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.1 0.15 4.97.6 5.8 2.8 5.8 3.0 2.6 6.1 0.2 4.9 7.5 5.8 2.8 5.8 3.0 2.6 6.1 0.25 4.97.6 5.8 2.8 5.8 3.0 2.6 6.1 0.3 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.1 0.35 4.97.6 5.8 2.8 5.8 3.0 2.6 6.1 0.4 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.1 0.45 4.97.6 5.8 2.8 5.8 3.0 2.6 6.1 0.5 4.9 7.6 5.8 2.8 5.7 3.0 2.6 6.1 0.55 4.97.6 5.8 2.8 5.7 3.0 2.6 6.1 0.6 4.9 7.6 5.8 2.8 5.6 3.0 2.6 6.1 0.65 4.97.6 5.8 2.8 5.5 3.0 2.6 6.1 0.7 5.0 7.5 5.8 2.8 5.3 3.0 2.6 6.0 0.75 4.87.4 5.8 2.8 5.1 3.0 2.6 5.8 0.8 4.6 7.1 5.8 2.7 4.8 2.9 2.5 5.5 0.85 4.26.5 5.8 2.5 4.3 2.7 2.3 5.0 0.9 3.6 5.5 4.9 2.2 3.6 2.4 2.1 4.2 0.95 2.63.8 3.5 1.8 2.6 1.9 1.7 2.9 1 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFC-1233zdE-HFO-1225zc Organics Organics Organics Organics Organics OrganicsOrganics Organics 0.16 F1234yf + 0.94 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.14 F245cb + 0.01 F245cb + 0.94 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.14 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.94 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01F1233xf + 0.01 F1233xf + 0.14 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE +0.01 F1234zeE + 0.94 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.14 F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.94 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.14 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.94 F1233zdE + 0.01F1233zdE + 0.14 F1225zc 0.01 F1225zc 0.01 F1225zc 0.01 F1225zc 0.01F1225zc 0.01 F1225zc 0.01 F1225zc 0.94 F1225zc TOTAL TOTAL TOTAL TOTALTOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE PRESSURE PRESSURE PRESSUREPRESSURE PRESSURE PRESSURE PRESSURE HF bar bar bar bar bar bar bar bar 03.9 6.6 4.6 1.7 4.8 1.9 1.5 5.2 0.05 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.14.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.15 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.24.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.25 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.34.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.35 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.44.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.45 4.9 7.6 5.8 2.8 5.8 3.0 2.6 6.2 0.54.9 7.6 5.8 2.8 5.7 3.0 2.6 6.1 0.55 4.9 7.6 5.8 2.8 5.7 3.0 2.6 6.1 0.64.9 7.6 5.8 2.8 5.6 3.0 2.6 6.0 0.65 4.9 7.6 5.8 2.8 5.5 3.0 2.6 5.9 0.74.9 7.5 5.8 2.8 5.3 3.0 2.6 5.8 0.75 4.8 7.4 5.8 2.8 5.1 3.0 2.6 5.5 0.84.6 7.1 5.8 2.7 4.8 2.9 2.5 5.1 0.85 4.2 6.5 5.8 2.5 4.3 2.7 2.3 4.6 0.93.5 5.5 4.9 2.2 3.6 2.4 2.1 3.8 0.95 2.6 3.8 3.5 1.8 2.6 1.9 1.7 2.7 11.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2

EXAMPLE 20 Temperature and Pressure Range of System with 8 Compounds

Boiling point range Temperature Pressure System with 8 compounds ° C.bar abs HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO- 0 to 40 ~1.0~11.51233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 0 to 40 ~0.7 to ~11.51234zeE-HFO-1234zeZ-HCFO-1233zdE-HCFC-244bbHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO- 0 to 40 ~1.0 to~17.4 1234zeZ-HCFO-1233zdE-TrifluoropropyneHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 0 to 40 ~0.9 to ~11.51234zeE-HFO-1234zeZ-HCFO-1233zdE-HFC-245faHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 0 to 40 ~1.0 to ~11.51234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1225yeZHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 0 to 40 ~1.0 to ~11.51234zeE-HFO-1234zeZ-HCFC-1233zdE-HFO-1225zc

EXAMPLE 21 Decantation Ranges of System with 8 Compounds

Decantation ranges Mass percentage of HF Temperature System with 8compounds 0° C. 25° C. 40° C. HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-   5-75%    5-70%    15-50% 1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 5-80 5-75  5-701234zeE-HFO-1234zeZ-HCFO-1233zdE-HCFC-244bbHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE- 5-75 10-65 *HFO-1234zeZ-HCFO-1233zdE-TrifluoropropyneHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 5-75 5-70 10-60 1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFC-245faHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 5-75 5-70 15-551234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO- 1225yeZHF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO- 5-75 5-65 15-501234zeE-HFO-1234zeZ-HCFC-1233zdE-HFO-1225zc

EXAMPLE 22 Systems with 13 Compounds

HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE- HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zcOrganics 0.087 Organics Organics Organics Organics F1234yf + 0.083 0.89F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + F245cb + 0.0830.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + F1233xf + 0.0830.01 F1233xf + 0.89 F1233xf + 0.01 F1233xf + 0.01 F1233xf + F1233zdE +0.083 0.01 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.89 F1233zdE +F1234zeE + 0.083 0.01 F1234zeE + 0.01 F1234zeE + 0.89 F1234zeE + 0.01F1234zeE + F1234zeZ + 0.083 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + F1243zf + 0.083 0.01 F1243zf + 0.01 F1243zf +0.01 F1243zf + 0.01 F1243zf + F244bb + 0.083 0.01 F244bb + 0.01 F244bb +0.01 F244bb + 0.01 F244bb + F245fa + 0.083 0.01 F245fa + 0.01 F245fa +0.01 F245fa + 0.01 F245fa + TFP + 0.083 0.01 TFP + 0.01 0.01 TFP + 0.010.01 TFP + 0.01 0.01 TFP + 0.01 F1225yeZ + 0.83 F1225yeZ + 0.1F1225yeZ + 0.1 F1225yeZ + 0.1 F1225yeZ + 0.1 F1225zc F1225zc F1225zcF1225zc F1225zc TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE PRESSUREPRESSURE PRESSURE PRESSURE HF bar bar bar bar bar 0 4.5 6.5 1.9 4.8 1.70.05 5.6 7.5 3.0 5.8 2.9 0.1 5.6 7.5 3.0 5.8 2.8 0.15 5.6 7.5 3.0 5.82.8 0.2 5.6 7.5 3.0 5.8 2.8 0.25 5.6 7.5 3.0 5.8 2.8 0.3 5.6 7.5 3.0 5.02.8 0.35 5.6 7.5 3.0 5.8 2.8 0.4 5.6 7.5 3.0 5.8 2.8 0.45 5.5 7.5 3.05.8 2.8 0.5 5.5 7.5 3.0 5.8 2.8 0.55 5.5 7.5 3.0 5.7 2.8 0.6 5.5 7.5 3.05.6 2.8 0.65 5.5 7.5 3.0 5.5 2.8 0.7 5.4 7.5 3.0 5.4 2.8 0.75 5.3 7.33.0 5.2 2.8 0.8 5.1 7.0 2.8 4.8 2.7 0.85 4.6 6.4 2.6 4.3 2.5 0.9 3.9 5.42.3 3.6 2.2 0.95 2.8 3.7 1.8 2.6 1.6 1 1.2 1.2 1.2 1.2 1.2

EXAMPLE 23 Temperature and Pressure Range of System with 13 Compounds

Boiling point range Temperature Pressure System with 13 compounds ° C.bar abs HF-HFO-1234yf-HFC-245cb-HCFO-1233xf- 0 to 40 ~0.7 ~18.0HCFO-1233zdE-HFO-1234zeE-HFO- 1234zeZ-HFC-1243zf-HCFC-244bb-TFP-

indicates data missing or illegible when filed

EXAMPLE 24 Decantation Ranges of System with 13 Compounds

Decantation ranges Mass percentage of HF Temperature System with 13compounds 0° C. 25° C. 40° C. HF-HFO-1234yf-HFC-245cb-HCFO-1233xf- 5-75%10-70% 15-60% HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP- HFC-245fa-HFO-1225yeZ-HFO-1225zc

1-14. (canceled)
 15. An azeotropic or quasi-azeotropic compositionconsisting essentially of hydrogen fluoride andE-3,3,3-trifluoro-1-chloropropene.
 16. The composition as claimed inclaim 15, wherein the composition is azeotropic.
 17. The composition asclaimed in claim 15, wherein the composition is quasi-azeotropic,wherein the pressure difference between the pressure at the dew pointand the pressure at the bubble formation point is less than or equal to5%, on the basis of the pressure at the bubble formation point.
 18. Thecomposition as claimed in claim 15, wherein the composition has from 5%to 70% by weight of hydrogen fluoride and from 95% to 30% by weight ofE-3,3,3-trifluoro-1-chloropropene, the boiling point of this compositionis between 0 and 40° C. at a pressure of between 0.9 and 4 bar absolute.19. The composition as claimed in claim 15, wherein the composition hasfrom 10% to 65% by weight of hydrogen fluoride and from 90% to 35% byweight of E-3,3,3-trifluoro-1-chloropropene, the boiling point of thiscomposition is between 0 and 40° C. at a pressure of between 0.9 and 4bar absolute.
 20. The composition as claimed in claim 15, wherein thecomposition consists of hydrogen fluoride andE-3,3,3-trifluoro-1-chloropropene.
 21. The composition as claimed inclaim 20, wherein the composition is azeotropic.
 22. The composition asclaimed in claim 20, wherein the composition is quasi-azeotropic,wherein the pressure difference between the pressure at the dew pointand the pressure at the bubble formation point is less than or equal to5%, on the basis of the pressure at the bubble formation point.
 23. Thecomposition as claimed in claim 20, wherein the composition has from 5%to 70% by weight of hydrogen fluoride and from 95% to 30% by weight ofE-3,3,3-trifluoro-1-chloropropene, the boiling point of this compositionis between 0 and 40° C. at a pressure of between 0.9 and 4 bar absolute.24. The composition as claimed in claim 20, wherein the composition hasfrom 10% to 65% by weight of hydrogen fluoride and from 90% to 35% byweight of E-3,3,3-trifluoro-1-chloropropene, the boiling point of thiscomposition is between 0 and 40° C. at a pressure of between 0.9 and 4bar absolute.